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1.发明授权Method for the liquid phase hydrotreatment of heavy hydrocarbons in the presence of a dispersed catalyst 失效在分散的催化剂存在下液相加氢处理重质烃的方法
公开(公告)号：US4756821A
公开(公告)日：1988-07-12
申请号：US13083
申请日：1987-02-10
IPC分类号： B01D61/14 , B01D69/02 , B01D71/02 , B01J31/04 , C10G31/09 , C10G31/11 , C10G49/12 , C10G49/22 , C10G67/02 , C10G45/16
摘要： A hydrotreatment method, for example, hydroviscoreduction or hydrodesulfurization in which the charge of hydrocarbons is reacted with hydrogen in contact with a catalyst finely dispersed in the liquid phase. To separate the product from the catalyst, the effluent freed from its accompanying free gas is passed along, and in contact with the upstream wall of a porous inorganic membrane. The oil that has not been filtered contains a concentrate of catalyst and is recycled to the hydrotreatment reactor. The filtered oil constitutes the product of the method.
摘要翻译： 加氢处理方法，例如，水合物引燃或加氢脱硫，其中烃的加料与氢气与微细分散在液相中的催化剂接触。 为了将产物与催化剂分离，从其伴随的游离气体中除去的流出物通过多孔无机膜的上游壁并与其接触。 未过滤的油包含催化剂的浓缩物，并再循环至加氢处理反应器。 过滤油构成该方法的产物。
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2.发明授权Process for and apparatus for catalytic cracking in two successive reaction zones 失效两个连续反应区的催化裂化方法和装置
公开(公告)号：US5498326A
公开(公告)日：1996-03-12
申请号：US57795
申请日：1993-05-07
CPC分类号： C10G51/026 , C10G11/18
摘要： The invention relates to a process for catalytic cracking and the associated apparatus in which the cracking reaction takes place in two substantially vertical and successive reaction zones, the loads being introduced into the first zone where it circulates from the top downwards, then at least a part of the product obtained is introduced into a second reaction zone in which it circulates in an ascending fashion. A supplementary hydrocarbonated phase is advantageously introduced into the product entering the second zone. The invention applies particularly to heavy loads, with a U-shaped apparatus.
摘要翻译： 本发明涉及一种催化裂化方法及其相关设备，其中裂化反应发生在两个基本垂直和连续的反应区域中，负载被引入第一区域，其中它从顶部向下循环，然后至少一部分 将所得产物引入第二反应区，其中它以升序方式循环。 补充的烃化相有利地被引入到进入第二区的产物中。 本发明尤其适用于具有U形装置的重载荷。
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3.发明授权Process for removing sulfur oxides from a gas by means of an absorption mass regenerable by reaction with elemental sulfur 失效通过与元素硫反应可再生的吸收物质从气体中除去硫氧化物的方法
公开(公告)号：US4855117A
公开(公告)日：1989-08-08
申请号：US160973
申请日：1988-02-26
IPC分类号： B01D53/50
CPC分类号： B01D53/508
摘要： The invention relates to a process for removing sulfur oxides, particularly sulfur dioxide, contained in gases such as industrial fumes, characterized in that the gas is contacted with a solid absorbent containing magnesium oxide, in such conditions that sulfur oxides are fixed mainly as magnesium sulfate and then the used solid absorbent is contacted with a gas stream containing elemental sulfur in such conditions that magnesium oxide is regenerated with the production of an effluent of sulfur dioxide containing gas.
摘要翻译： 本发明涉及一种除去气体如工业烟气中所含的硫氧化物，特别是二氧化硫的方法，其特征在于，气体与含氧化镁的固体吸收剂接触，硫氧化物主要以硫酸镁的形式固定 然后将所使用的固体吸收剂与含有元素硫的气流接触，使得氧化镁在产生含二氧化硫气体的流出物的条件下再生。
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4.发明授权Reaction chamber comprising a calender reactor and means for bedding the flow of a heat-carrying fluid 失效包含加热反应器的反应室和用于加热加热流体的流动的装置
公开(公告)号：US5186909A
公开(公告)日：1993-02-16
申请号：US642585
申请日：1991-01-17
申请人： Quang Dang Vu , Sigismond Franckowiak , Alain Grehier , Philippe Vacher , Jean-Pierre Burzynski
发明人： Quang Dang Vu , Sigismond Franckowiak , Alain Grehier , Philippe Vacher , Jean-Pierre Burzynski
IPC分类号： B01J8/02 , B01J8/06 , B01J8/08 , B01J19/00 , B01J23/656 , B01J27/13 , C10G35/04 , C10G35/12 , C10G47/02
CPC分类号： C10G35/12 , B01J8/087 , B01J2208/00088 , B01J2208/00221 , B01J2208/00504 , B01J2208/0053
摘要： A reaction chamber (E) comprises a calender reactor (5) comprising a device (4) for introducing a feedstock; a device (6) for carrying off the treated feedstock; at least two elementary reaction cells (52), not contiguous to one another, each one consisting of an individual feedstock distributor, an individual collector of the treated feedstock, and a catalytic bed, the cells being separated from one another by a channel (51); at least one device (V) for circulating a heat-carrying fluid in each channel (51); at least n partitions (S) for separating the flow of the heat-carrying fluid, n being an integer greater than or equal to 1; and at least n+1 means (T) for heating the heat-carrying fluid. The chamber can be used for performing the catalytic reforming of naphtha under low pressure.
摘要翻译： 反应室（E）包括砑光反应器（5），其包括用于引入原料的装置（4）; 用于运送经处理的原料的装置（6）; 至少两个元素反应池（52），彼此不邻接，每个由单独的原料分配器，经处理的原料的单个收集器和催化床组成，所述单元通过通道（51 ）; 至少一个用于使每个通道（51）中的载热流体循环的装置（V）; 用于分离所述载热流体的流动的至少n个分区（S），n是大于或等于1的整数; 并且至少n + 1表示用于加热承载流体的（T）。 该室可用于在低压下进行石脑油的催化重整。
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5.发明授权Process for purifying a gas containing hydrogen sulfide and carbon dioxide and apparatus therefor 失效用于净化含有硫化氢和二氧化碳的气体的方法及其设备
公开(公告)号：US4421725A
公开(公告)日：1983-12-20
申请号：US281798
申请日：1981-07-09
CPC分类号： B01D53/18
摘要： Process for separating H.sub.2 S from CO.sub.2, both contained in a treated gas, wherein said gas is contacted with a solution which selectively absorbs H.sub.2 S, wherefrom H.sub.2 S is separated in a regeneration zone, CO.sub.2 being released, said contact step being effected in a contact apparatus comprising 1 to 10 stages each formed of parallel vertical tubes whose bottom portion is provided with injection means of the cyclonic type imparting to the supplied gas and liquid a swirling ascending motion.
摘要翻译： 二氧化碳的分离方法，二者都包含在处理气体中，其中所述气体与选择性吸收H 2 S的溶液接触，其中H 2 S在再生区域中被分离，CO 2被释放，所述接触步骤在接触装置中进行，包括 1至10级，每个级别由平行的垂直管形成，其底部设置有向所供应气体和液体赋予旋转上升运动的旋风式喷射装置。
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6.发明授权Process for converting ammonium imidodisulfate, ammonium sulfamate and ammonium dithionate to sulfur dioxide and ammonia 失效将亚氨二硫酸铵，氨基磺酸铵和连二硫酸铵转化为二氧化硫和氨的方法
公开(公告)号：US4220634A
公开(公告)日：1980-09-02
申请号：US002273
申请日：1979-01-10
CPC分类号： C01B17/90 , C01B17/501 , C01C1/028 , Y02P20/52
摘要： Ammonium imidodisulfate and ammonium sulfamate may be converted to sulfur dioxide and ammonia by heating them with a reducing agent or a catalyst in a bath of molten ammonium sulfate and ammonium bisulfate. The reducing agent is sulfur or a sulfur compound and the catalyst is selected from Mo, W, Cu, Fe, Co, Cr, Mn and Ni.
摘要翻译： 亚胺二硫酸铵和氨基磺酸铵可以通过在熔融硫酸铵和硫酸氢铵浴中用还原剂或催化剂加热而转化为二氧化硫和氨。 还原剂是硫或硫化合物，催化剂选自Mo，W，Cu，Fe，Co，Cr，Mn和Ni。
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7.发明授权Process for purifying a sulfur dioxide containing gas by washing with an ammonia aqueous solution 失效通过用氨水洗涤来净化含二氧化硫的气体的方法
公开(公告)号：US4180550A
公开(公告)日：1979-12-25
申请号：US835085
申请日：1977-09-20
CPC分类号： C01B17/60 , B01D53/501
摘要： Process for purifying a sulfur dioxide containing gas, by washing with an ammonia aqueous solution, comprising the following steps:(a) contacting a sulfur dioxide containing gas with ammonia and/or ammonium sulfite in the presence of water, to form a solution containing ammonium bisulfite and/or sulfite;(b) reacting at least a portion of the solution obtained in step (a) with ammonium bisulfate, so as to decompose the ammonium bisulfite and sulfite and to obtain ammonium sulfate as an aqueous solution and gaseous sulfur dioxide;(c) recovering the sulfur dioxide;(d) heating the aqueous solution obtained in step (b) for vaporizing at least a portion of the water;(e) heating the product from step (d) to convert the ammonium sulfate to ammonium bisulfate and gaseous ammonia;(f) separating the gaseous ammonia obtained in step (e) and feeding it to step (a) either as such or as ammonium sulfite and,(g) feeding to step (b) the ammonium bisulfate obtained in step (e) either as such or after dissolution in water, wherein, in order to avoid an accumulation of ammonium sulfate and/or bisulfate, due the undesirable formation of ammonium sulfate, at least a portion of the ammonium sulfate and/or bisulfate from step (e) is heated with a molybdenum and/or tungsten compound for converting a portion of said ammonium sulfate and/or bisulfate to sulfur dioxide and ammonia, which are fed back to step (a).
摘要翻译： 通过用氨水洗涤来净化含二氧化硫气体的方法，包括以下步骤：（a）在水存在下使含二氧化硫的气体与氨和/或亚硫酸铵接触，形成含有铵的溶液 亚硫酸氢盐和/或亚硫酸盐; （b）使步骤（a）中获得的溶液的至少一部分与硫酸氢铵反应，以分解亚硫酸氢铵和亚硫酸盐，得到作为水溶液和气态二氧化硫的硫酸铵; （c）回收二氧化硫; （d）加热步骤（b）中获得的水溶液以使至少一部分水蒸发; （e）加热来自步骤（d）的产物以将硫酸铵转化为硫酸氢铵和气态氨; （f）分离步骤（e）中获得的气态氨，并将其进料到步骤（a）中，或者以亚硫酸铵形式进料到步骤（a），和（g）将步骤（b）中得到的硫酸氢铵 这样或之后溶解在水中，其中为了避免硫酸铵和/或硫酸氢盐的积聚，由于不期望的形成硫酸铵，将来自步骤（e）的至少一部分硫酸铵和/或硫酸氢盐加热 与用于将一部分所述硫酸铵和/或硫酸氢盐转化成二氧化硫和氨的钼和/或钨化合物反馈到步骤（a）。
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8.发明授权Process for converting heavy petroleum residues to hydrogen and gaseous distillable hydrocarbons 失效将重质石油残渣转化为氢气和气态可馏分烃的方法
公开(公告)号：US4609456A
公开(公告)日：1986-09-02
申请号：US699540
申请日：1985-02-08
IPC分类号： C10G47/02 , B01J23/00 , B01J23/02 , B01J23/22 , B01J23/78 , B01J27/00 , B01J27/232 , C10G11/12 , C10G47/04 , C10G47/26 , B01J23/90 , C10J3/46
摘要： The invention concerns a process for converting heavy petroleum residues to hydrogen and to gaseous and distillable hydrocarbons, comprising the association of a step of hydropyrolysis (inside tube 3) with a step of catalytic steam-gasification of the formed coke (outside tube 3), characterized in that the hydropyrolysis step is performed in the presence of a solid supporting a carbon gasification catalyst circulating between the hydropyrolysis zone and the coke steam-gasification zone, said steam-gasification being performed in the absence of oxygen.The petroleum residue, hydrogen and steam are introduced respectively through lines 5, 6 and 7.The products are withdrawn through line 10. Heat may be supplied by the radiating tube 4.
摘要翻译： 本发明涉及将重质石油残余物转化为氢气和气态和可馏出烃的方法，其包括加氢热解步骤（管3内）与成形焦炭（外管3）的催化蒸汽气化步骤的关联， 其特征在于，所述加氢热解步骤在支持在所述加氢热解区和所述焦炭蒸汽 - 气化区之间循环的碳气化催化剂的固体存在下进行，所述蒸汽气化在不存在氧的情况下进行。 石油渣，氢气和蒸汽分别通过管线5,6和7引入。产物通过管线10排出。热量可以由辐射管4供应。
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9.发明授权Process for purifying a gas containing hydrogen sulfide and contact masses usable therefor 失效用于净化含有硫化氢的气体和可用的接触块的方法
公开(公告)号：US4088736A
公开(公告)日：1978-05-09
申请号：US641352
申请日：1975-12-16
CPC分类号： B01D53/52 , C01B3/56 , C01B2203/042 , C01B2203/0485
摘要： A process for purifying a hydrogen sulfide containing gas, which comprises absorbing said hydrogen sulfide onto a mass comprising zinc oxide, alumina and a group II A metal oxide, a large proportion of the group II A metal oxide being in the form of aluminate or silicoaluminate; then regenerating the mass by passing an oxygen containing gas therethrough.
摘要翻译： 一种用于纯化含硫化氢的气体的方法，其包括将硫化氢吸收到包含氧化锌，氧化铝和IIA族金属氧化物的物质上，大部分为铝酸盐或硅铝酸盐形式的IIA族金属氧化物 ; 然后通过使含氧气体通过其再生。
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公开(公告)号：US4044114A
公开(公告)日：1977-08-23
申请号：US641223
申请日：1975-12-16
CPC分类号： C01B17/05 , B01D53/8615 , C01B17/0408 , C01B17/0456
摘要： Process for purifying a gas containing hydrogen sulfide and sulfur dioxide, comprising substantially removing sulfur dioxide, absorbing hydrogen sulfide on a solid contact mass, intermittently regenerating said mass by means of an oxygen-containing gas, so as to produce a gas containing sulfur dioxide, and reacting the latter gas with hydrogen sulfide to produce sulfur.
摘要翻译： 用于纯化含有硫化氢和二氧化硫的气体的方法，包括基本上除去二氧化硫，在固体接触物质上吸收硫化氢，通过含氧气体间歇地再生所述物质，以产生含有二氧化硫的气体， 并使后者的气体与硫化氢反应产生硫。
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