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    Isocyanate-terminated prepolymers, a process of producing polyurethane/polyurea elastomers therefrom, and the resultant elastomers
    1.
    发明授权
    Isocyanate-terminated prepolymers, a process of producing polyurethane/polyurea elastomers therefrom, and the resultant elastomers 失效
    异氰酸酯封端的预聚物，由其生产聚氨酯/聚脲弹性体的方法和所得的弹性体

    公开(公告)号：US5646230A

    公开(公告)日：1997-07-08

    申请号：US575979

    申请日：1995-12-21

    申请人： Richard S. Pantone ,  James W. Rosthauser ,  Karl W. Haider

    发明人： Richard S. Pantone ,  James W. Rosthauser ,  Karl W. Haider

    IPC分类号： C08G18/10 ,  C08G18/48 ,  C08G18/72 ,  C08G18/75

    CPC分类号： C08G18/724 ,  C08G18/10 ,  C08G18/48

    摘要： This invention relates to isocyanate-terminated prepolymers, a process for the preparation of these isocyanate-terminated prepolymers, a process for the production of polyurethane.backslash.polyurea elastomers prepared from a diisocyanate comprising these prepolymers, and the elastomers produced by this process. These isocyanate-terminated prepolymers have a viscosity less than about 6000 mPa.cndot.s at 80.degree. C. and an NCO content of about 3 to 10%. These isocyanate-terminated prepolymers are the reaction product ofa) an aromatic diisocyanate,b) a polyether polyol having an OH number of about 25 to 125 and containing from about 1.8 to 2.5 hydroxyl groups, andc) an aliphatic diisocyanate.The equivalent ratio of the polyether polyol to the aromatic diisocyanate is from about 1.0:0.7 to 1.0:1.1.

    摘要翻译： 本发明涉及异氰酸酯封端的预聚物，制备这些异氰酸酯封端的预聚物的方法，制备由包含这些预聚物的二异氰酸酯制备的聚氨酯+ 544聚脲弹性体的方法以及通过该方法生产的弹性体。 这些异氰酸酯封端的预聚物在80℃下的粘度小于约6000mPa.s，NCO含量约为3至10％。 这些异氰酸酯封端的预聚物是a）芳香族二异氰酸酯，b）OH值约为25〜125，含有约1.8〜2.5个羟基的聚醚多元醇的反应产物，和c）脂肪族二异氰酸酯。 聚醚多元醇与芳族二异氰酸酯的当量比为约1.0:0.7至1.0:1.1。

    Photochromic polyurethanes
    5.
    发明授权
    Photochromic polyurethanes 有权
    光致变色聚氨酯

    公开(公告)号：US6107395A

    公开(公告)日：2000-08-22

    申请号：US212789

    申请日：1998-12-16

    申请人： James W. Rosthauser ,  Karl W. Haider ,  Sivaram Krishnan ,  James N. Rieck

    发明人： James W. Rosthauser ,  Karl W. Haider ,  Sivaram Krishnan ,  James N. Rieck

    IPC分类号： C08G18/10 ,  C08J3/00 ,  C08K3/20 ,  C08K5/00 ,  C08K5/34 ,  C08K5/35 ,  C08L75/00 ,  C09B69/10 ,  G03C1/685 ,  G03C1/73 ,  C08G18/00

    CPC分类号： G03C1/733 ,  C08G18/10 ,  C08K5/0041 ,  C09B69/10 ,  G03C1/685

    摘要： The present invention relates to a novel photochromic polyurethane consisting essentially of an isocyanate reactive mixture consisting essentially of: i) from about 40 to about 85% by weight of one or more polyols having a nominal functionality of from 2 to 4 and molecular weights of from 500 to 6000 g/mole; ii) from about 15 to about 60% by weight of one or more diols or triols or mixtures thereof having a functionality of from 2 to 3 and molecular weights of from 62 to 499; b) an aliphatic polyisocyanate having a functionality ranging from about 2 to about 3; and c) a photochromic compound selected from a group consisting of spirooxazines, fulgides, fulgimides, and naphthopyrans, wherein the photochromic compound is present in an amount of 0.01 to 5 parts per hundred parts by weight of the isocyanate reactive mixture.

    摘要翻译： 本发明涉及一种基本上由异氰酸酯反应性混合物组成的新型光致变色聚氨酯，其基本上由以下组成：i）约40至约85重量％的一种或多种标称官能度为2-4的多元醇，分子量为 500〜6000g / mol; ii）约15至约60重量％的一种或多种二醇或三醇或其混合物，其官能度为2至3，分子量为62至499; b）官能度为约2至约3的脂族多异氰酸酯; 和c）选自由螺恶嗪，富锗，富酰嘧啶和萘并吡喃组成的组的光致变色化合物，其中光致变色化合物的存在量为每100重量份异氰酸酯反应性混合物0.01至5重量份。

    Light stable elastomers having good dynamic properties
    6.
    发明授权
    Light stable elastomers having good dynamic properties 失效
    光稳定的弹性体具有良好的动态性能

    公开(公告)号：US5714562A

    公开(公告)日：1998-02-03

    申请号：US662402

    申请日：1996-06-12

    申请人： James W. Rosthauser ,  Karl W. Haider ,  Carl Serman

    发明人： James W. Rosthauser ,  Karl W. Haider ,  Carl Serman

    IPC分类号： C08G18/10 ,  C08G18/22 ,  C08G18/24 ,  C08G18/32 ,  C08G18/75

    CPC分类号： C08G18/758 ,  C08G18/10 ,  C08G18/227 ,  C08G18/242

    摘要： This invention relates to novel light stable elastomers which exhibit good dynamic properties, and a process for their preparation. These elastomers comprise the reaction product of an isocyanate propolymer, a chain extender, and a catalyst selected from i) solid delayed action catalysts having a melting point of greater than about 60.degree. C., ii) alkyl substituted organotin catalysts containing alkylmercaptide ligands, and which are liquid at room temperature, and iii) alkyl substituted organotin catalysts containing sulfur bridging groups, and which are liquid at room temperature.

    摘要翻译： 本发明涉及具有良好动力学特性的新型轻质稳定弹性体及其制备方法。 这些弹性体包括异氰酸酯共聚物，扩链剂和选自以下的催化剂的反应产物：i）熔点大于约60℃的固体延迟作用催化剂，ii）含烷基巯基配体的烷基取代的有机锡催化剂和 其在室温下为液体，以及iii）含有硫桥连基团的烷基取代的有机锡催化剂，并且在室温下为液体。

    Process for castable polyurea elastomers
    7.
    发明授权
    Process for castable polyurea elastomers 失效
    浇注聚脲弹性体的工艺

    公开(公告)号：US5510445A

    公开(公告)日：1996-04-23

    申请号：US343402

    申请日：1994-11-22

    申请人： Karl W. Haider ,  William E. Slack ,  Rick L. Adkins ,  James W. Rosthauser ,  Peter H. Markusch

    发明人： Karl W. Haider ,  William E. Slack ,  Rick L. Adkins ,  James W. Rosthauser ,  Peter H. Markusch

    IPC分类号： C08G18/50 ,  C08G18/65 ,  C08G18/66 ,  C08G18/75 ,  C08G18/32

    CPC分类号： C08G18/6529 ,  C08G18/5024 ,  C08G18/5027 ,  C08G18/6685 ,  C08G18/758 ,  C08G2120/00 ,  Y10S264/77

    摘要： This invention relates to a one-step process for preparing polyurea elastomers comprising reaction at an isocyanate index of from 90 to 200 of(a) one or more aliphatic and/or cycloaliphatic diisocyanates;(b) 25 to 70 equivalent percent, relative to the total of components (b) and (c), of one or more liquid amine-terminated polymers containing at least two aromatically bound isocyanate-reactive primary or secondary amino groups and/or aliphatically bound isocyanate-reactive secondary amino groups and having a molecular weight of from 400 to 6000; and(c) 75 to 30 equivalent percent, relative to the total of components (b) and (c), of one or more aromatic diamine chain extenders having a molecular weight of from 108 to 399, optionally in admixture with one or more crosslinkers.

    摘要翻译： 本发明涉及制备聚脲弹性体的一步法，该方法包括（a）一种或多种脂族和/或脂环族二异氰酸酯的异氰酸酯指数为90至200的反应; （b）相对于组分（b）和（c）的总量为25至70当量的一种或多种含有至少两个芳族结合的异氰酸酯反应性伯或仲氨基的液体胺封端的聚合物和/或脂族 结合的异氰酸酯反应性仲氨基并且分子量为400至6000; 和（c）相对于组分（b）和（c）的总量为75至30当量的一种或多种分子量为108至399的芳族二胺增链剂，任选地与一种或多种交联剂 。

    Process for the production of medium density decorative molded foams having good fire retardant properties with reduced mold times, fire retardant compositions and foams produced by this process
    9.
    发明授权
    Process for the production of medium density decorative molded foams having good fire retardant properties with reduced mold times, fire retardant compositions and foams produced by this process 有权
    具有良好的阻燃性能，减少模具时间的中等密度装饰模制泡沫的生产方法，阻燃组合物和通过该方法生产的泡沫

    公开(公告)号：US08097658B2

    公开(公告)日：2012-01-17

    申请号：US12620827

    申请日：2009-11-18

    申请人： James W. Rosthauser

    发明人： James W. Rosthauser

    IPC分类号： C08G18/06

    CPC分类号： C09K21/12 ,  C08K3/38 ,  C08K9/08

    摘要： Fire-resistant, medium density molded polyurethane foams which may be removed from a mold in substantially shorter times than previously possible are produced by the process of the present invention. These reduced de-mold times are achieved by including a solid flame retardant composition in the polyurethane foam forming composition. This solid flame retardant composition includes a melamine coated ammonium polyphosphate and zinc borate.

    摘要翻译： 通过本发明的方法产生耐火，中等密度的模塑聚氨酯泡沫，其可以以比之前可能的更短的时间从模具中除去。 这些减少的脱模时间通过在聚氨酯泡沫形成组合物中包含固体阻燃组合物来实现。 该固体阻燃剂组合物包括三聚氰胺涂覆的多磷酸铵和硼酸锌。