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公开(公告)号：US4528384A
公开(公告)日：1985-07-09
申请号：US164744
申请日：1980-06-30
IPC分类号： C08F2/28 , C08F12/32 , C07D333/16 , B05D1/36
摘要： Novel polymers having high activity as cationic surface-active agents are prepared by the addition polymerization of ethylenically unsaturated aromatic sulfonium salts, e.g., ##STR1## When such polymers are heated and/or dried, they are irreversibly converted to inert, nonionic residues without the elimination of odorous by-products.The novel sulfonium salt polymers having relatively low molecular weight and low charge density are particularly useful as surfactants or emulsifiers in the emulsion polymerization of ethylenically unsaturated monomers such as styrene, butadiene, alkyl acrylates and the like. The polymers having high molecular weight and high charge density are useful as thickeners and flocculants.
摘要翻译： 通过烯键式不饱和芳族锍盐的加成聚合制备具有高活性的阳离子表面活性剂的新型聚合物，例如，当加热和/或干燥这些聚合物时，它们不可逆地转化为惰性的非离子残余物， 消除恶臭副产品。 具有相对低分子量和低电荷密度的新型锍盐聚合物在烯属不饱和单体如苯乙烯，丁二烯，丙烯酸烷基酯等的乳液聚合中特别可用作表面活性剂或乳化剂。 具有高分子量和高电荷密度的聚合物可用作增稠剂和絮凝剂。
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公开(公告)号：US4214096A
公开(公告)日：1980-07-22
申请号：US48954
申请日：1979-06-15
IPC分类号： B01F17/00 , C07C335/32 , C09D5/44 , C07C157/02 , C07C157/05 , C07C161/00
CPC分类号： C07C335/32 , B01F17/0057 , C09D5/448
摘要： Novel isothiouronium salts are herein described which correspond to the formula ##STR1## wherein R and R' are each independently hydrocarbyl or inertly-substituted hydrocarbyl of at least 4 carbon atoms; R.sub.1 -R.sub.4 are each independently alkyl or hydroxyalkyl of 1 to 4 carbon atoms, or R.sub.1 and R.sub.3 are joined to form a 5- or 6-membered heterocyclic ring; n is 0 or 1; and A.sup..crclbar. is an inert neutralizing anion. The isothiouronium salts are surprisingly effective dispersing agents and are used in forming electrodepositable latexes.
摘要翻译： 本文描述了新的异硫脲鎓盐，其对应于下式：其中R和R'各自独立地为至少4个碳原子的烃基或惰性取代的烃基; R 1 -R 4各自独立地为具有1至4个碳原子的烷基或羟烷基，或者R 1和R 3连接形成5-或6-元杂环; n为0或1; 而A（ - ）是惰性中和阴离子。 异硫脲盐是惊人的有效的分散剂，并用于形成可电沉积胶乳。
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3.发明授权Aqueous compositions containing organic polymers curable at low temperatures in the wet state 失效包含在湿态低温下可固化的有机聚合物的含水组合物
公开(公告)号：US4431768A
公开(公告)日：1984-02-14
申请号：US374828
申请日：1982-05-04
CPC分类号： D21H17/38 , C04B24/24 , C08F236/04 , C08J9/30
摘要： Aqueous acidic compositions which contain a combination of an organic polymer having a bound latent source of thiolate ions, such as isothiouronium groups and an organic polymer having bound cationic onium groups, such as sulfonium groups, or a polymer containing both kinds of groups can be cured in the wet state by raising the pH to above about 9 at a temperature from about 0.degree. C. to about 100.degree. C.
摘要翻译： 含有具有结合的硫醇盐离子潜在来源的有机聚合物如异硫脲基团和具有结合阳离子鎓基团的有机聚合物如锍基团或含有两种基团的聚合物的组合的水性酸性组合物可以被固化 在潮湿状态下，通过在约0℃至约100℃的温度下将pH升高至约9以上。
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公开(公告)号：US4477640A
公开(公告)日：1984-10-16
申请号：US422775
申请日：1982-09-24
IPC分类号： C08F2/28 , C08F12/32 , C08F228/00 , C08F220/38
摘要： Novel polymers having high activity as cationic surface-active agents are prepared by the addition polymerization of ethylenically unsaturated aromatic sulfonium salts, e.g., ##STR1## When such polymers are heated and/or dried, they are irreversibly converted to inert, nonionic residues without the elimination of odorous by-products. The novel sulfonium salt polymers having relatively low molecular weight and low charge density are particularly useful as surfactants or emulsifiers in the emulsion polymerization of ethylenically unsaturated monomers such as styrene, butadiene, alkyl acrylates and the like. The polymers having high molecular weight and high charge density are useful as thickeners and flocculants.
摘要翻译： 通过烯键式不饱和芳族锍盐的加成聚合制备具有高活性的阳离子表面活性剂的新型聚合物，例如，当加热和/或干燥这些聚合物时，它们不可逆地转化为惰性的非离子残余物， 消除恶臭副产品。 具有相对低分子量和低电荷密度的新型锍盐聚合物在烯属不饱和单体如苯乙烯，丁二烯，丙烯酸烷基酯等的乳液聚合中特别可用作表面活性剂或乳化剂。 具有高分子量和高电荷密度的聚合物可用作增稠剂和絮凝剂。
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公开(公告)号：US4002586A
公开(公告)日：1977-01-11
申请号：US569720
申请日：1975-04-21
IPC分类号： C08F8/34 , C08F236/06 , C08G59/40 , C08L63/00
CPC分类号： C08G59/4064 , C08F236/06 , C08F8/44 , C08F2800/20
摘要： Modified cationic latexes are prepared from nonionic or cationic latexes having particles containing chemically bound epoxide groups at or near the particle surface by reacting the latex with a nucleophile such as dimethyl sulfide and an acid such as acetic acid to form a latex having stabilizing onium ions chemically bound to the particle at or near the particle surface.
摘要翻译： 改性阳离子胶乳由非离子或阳离子胶乳制备，其通过使胶乳与亲核试剂例如二甲基硫醚和酸如乙酸反应形成具有化学键合环氧化物基团的化学结合的环氧基团，从而形成具有稳定的离子化学 与颗粒表面处或附近的颗粒结合。
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6.发明申请公开(公告)号：US20080188725A1
公开(公告)日：2008-08-07
申请号：US12027158
申请日：2008-02-06
IPC分类号： A61B5/1455
CPC分类号： A61B5/14532 , A61B5/0071 , A61B5/14552 , A61B5/1459 , A61B5/7203 , G01N21/6428 , G01N21/645
摘要： Novel optical devices, methods and systems relating to the detection of glucose, and more particularly to real-time glucose monitoring, are disclosed herein. More particularly, various hardware and methodological means are disclosed for ratiometric correction of optical glucose measurements for artifacts of optical systems.
摘要翻译： 本文公开了与葡萄糖检测有关的新型光学器件，方法和系统，更具体地涉及实时葡萄糖监测。 更具体地，公开了用于光学系统的伪像的光学葡萄糖测量的比例校正的各种硬件和方法手段。
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7.发明授权Gas separations utilizing glassy polymer membranes at sub-ambient temperatures 失效在低于环境温度下使用玻璃状聚合物膜的气体分离
公开(公告)号：US5837032A
公开(公告)日：1998-11-17
申请号：US382032
申请日：1995-02-10
申请人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Thomas O. Jeanes , Henry N. Beck , Stephen E. Bales , Bethanne L. Smith
发明人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Thomas O. Jeanes , Henry N. Beck , Stephen E. Bales , Bethanne L. Smith
IPC分类号： B01D53/22 , B01D53/26 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/02 , C01B21/04 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12
CPC分类号： C01B13/0251 , B01D53/22 , B01D53/228 , B01D53/268 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B21/0444 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12 , C01B2210/0046 , C01B2210/0062
摘要： This invention relates to a method of an apparatus and method for separating component gases in a gas mixture employing a glassy polymer membrane at temperatures at or slightly above the freezing point of any liquid present so as to achieve superior separator of gas components. The composition of certain monomers and polymers are claimed.
摘要翻译： PCT No.PCT / US93 / 07696 Sec。 371日期1995年2月10日 102（e）1995年2月10日PCT PCT 1993年8月13日PCT公布。 出版物WO94 / 04250 日本特开1994年3月3日本发明涉及一种使用玻璃状聚合物膜在气体混合物中分离组分气体的装置和方法的方法，所述气体混合物在存在的任何液体的冰点处或稍高于所存在的任何液体的冰点处，以便获得优异的气体分离器 组件。 要求某些单体和聚合物的组成。
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公开(公告)号：US5405661A
公开(公告)日：1995-04-11
申请号：US930971
申请日：1992-08-14
IPC分类号： C09D179/04 , B32B27/02 , C08G18/60
CPC分类号： C09D179/04 , Y10S428/92 , Y10T428/1086 , Y10T428/131 , Y10T428/1314 , Y10T428/24942 , Y10T428/30 , Y10T428/31504 , Y10T442/2033 , Y10T442/2721 , Y10T442/674
摘要： A structural panel for a vehicle or building contains a substrate and a layer of flame resistant polybenzazole polymer. If the substrate is heat resistant, the panel can serve as a fire barrier. If the substrate is not heat resistant, the polybenzazole layer can still serve to delay ignition and contain any volatile gases and molten polymer that forms when the panel is subjected to heat.
摘要翻译： 用于车辆或建筑物的结构板包含基底和一层阻燃的聚吲哚聚合物。 如果基板是耐热的，则该面板可以用作防火屏障。 如果基材不耐热，则聚苯并恶唑层仍可用于延迟点燃并含有当面板受热时形成的挥发性气体和熔融聚合物。
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9.发明授权Process of making microporous hollow fiber or film membrane of poly(phenylene sulfide) (PPS) 失效制造聚苯硫醚（PPS）的微孔中空纤维或膜膜的方法
公开(公告)号：US5246647A
公开(公告)日：1993-09-21
申请号：US746756
申请日：1991-08-19
申请人： Henry N. Beck , Robert D. Mahoney , Hawk S. Wan , Chieh-Chun Chau , Timothy M. Finney , Ritchie A. Wessling , Jiro Kawamoto , Mark F. Sonnenschein
发明人： Henry N. Beck , Robert D. Mahoney , Hawk S. Wan , Chieh-Chun Chau , Timothy M. Finney , Ritchie A. Wessling , Jiro Kawamoto , Mark F. Sonnenschein
CPC分类号： B01D53/228 , B01D67/0018 , B01D67/0027 , B01D67/003 , B01D71/66 , C08J3/091 , C08J9/26 , C08J9/28 , D01F6/765 , B01D2323/22 , C08J2201/046 , C08J2201/052 , C08J2381/02
摘要： The present invention relates to a process for preparing a microporous permselective membrane from a poly(phenylene sulfide) (PPS) polymer, an organic compound which substantially solubilizes the PPS below its melting point to form a homogenous mixture, heating the resulting mixture, extruding or casting the mixture into a membrane (fiber or film), quenching or coagulating the membrane, and leaching the membrane, while optionally drawing the membrane before, during, after leaching, or a combination thereof. In one embodiment, the solvent optionally includes an organic non-solvent to assist in obtaining the desired microporsity. The permselective polymers are useful to separate gaseous or liquid components from a mixture of components.
摘要翻译： 本发明涉及一种由聚（苯硫醚）（PPS）聚合物制备微孔渗透选择膜的方法，该有机化合物基本上将PPS溶解在其熔点以下以形成均匀混合物，加热得到的混合物，挤出或 将混合物浇注到膜（纤维或膜）中，淬火或凝结膜并浸出膜，同时任选地在浸出之前，浸出期间，浸出后或其组合时拉伸膜。 在一个实施方案中，溶剂任选地包括有机非溶剂以帮助获得所需的微孔性。 选择性聚合物可用于从组分混合物中分离气态或液体组分。
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10.发明授权
公开(公告)号：US5089259A
公开(公告)日：1992-02-18
申请号：US400418
申请日：1989-08-30
摘要： Stable, aqueous emulsion formulations of water-insoluble organic pesticides are formed from a mixture of (1) a water-insoluble organic pesticide, (2) a water based structured particle latex containing nonionic particles to which is bound a layer containing stabilizing pH independent ionic groups chemically bound at or near the surface of the polymer particles, and optionally a cosolvent and/or cosurfactant for the pesticide. The resulting product is much more stable to coalescence than emulsions made with conventional surfactants.
摘要翻译： 稳定的水不溶性有机农药的水性乳液制剂由（1）水不溶性有机农药，（2）含有非离子颗粒的水基结构化颗粒胶乳的混合物形成，其结合含有稳定的pH独立离子的层 在聚合物颗粒表面或其附近化学结合的基团，以及任选的农药的共溶剂和/或辅助表面活性剂。 与用常规表面活性剂制成的乳液相比，所得产物的聚结更加稳定。
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