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1.发明授权Method for coating electrically conductive particles by grafting a polymer layer 失效通过接枝聚合物层涂覆导电颗粒的方法公开(公告)号：US06375821B1
公开(公告)日：2002-04-23
申请号：US09529643
申请日：2000-06-19
IPC分类号： C25D902
CPC分类号： C09D5/4476
摘要： The invention concerns a method for forming a coating on conductive particles by grafting a polymer and/or a copolymer of the particles from a bath containing at least a monomer from which the polymer and/or copolymer is formed. The method consists of producing the grafting by electrochemical reduction of the monomer in an electrolytic solution, where at least a cathode and an anode are provided, and containing an aprotic solvent, a support electrolyte and the monomer(s) required for polymerizing or copolymerizing the coating, by suspending the particles and moving the solution so as to produce an intermittent contact between the particles and the cathode, and to form, by polymerization or copolymerization, the coating on the particles by applying an electric potential.
摘要翻译： 本发明涉及一种通过从至少含有形成聚合物和/或共聚物的单体的浴接枝颗粒的聚合物和/或共聚物而在导电颗粒上形成涂层的方法。 该方法包括通过在电解液中电化学还原单体进行接枝，其中至少提供阴极和阳极，并且含有非质子溶剂，载体电解质和聚合或共聚所需的单体 通过使颗粒悬浮并移动溶液以在颗粒和阴极之间产生间歇接触，并通过施加电势而在颗粒上聚合或共聚而形成涂层。
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2.发明授权
公开(公告)号：US5578188A
公开(公告)日：1996-11-26
申请号：US221378
申请日：1994-03-31
CPC分类号： C08F2/58 , C09D5/4476 , H01B1/122
摘要： A film of a composite material is deposited by electropolymerization onto electrically conductive surface. A mixture comprising a monomer, a substance forming a dopant, a supporting electrolyte and a solvent is subjected to electrolysis in which the conductive surface to be coated is used as either cathode or anode. The cathode or anode is polarized to a potential between the electron transfer between the electrically conductive surface and the monomer. Prior to electrolysis, a solution is made from the mixture containing the substance forming a dopant either as anion, cation, molecule, and/or as undissociated complex.
摘要翻译： 通过电聚合将复合材料的膜沉积到导电表面上。 将包含单体，形成掺杂剂的物质，支持电解质和溶剂的混合物进行电解，其中待涂覆的导电表面用作阴极或阳极。 阴极或阳极被极化到导电表面和单体之间的电子转移之间的电位。 在电解之前，由含有形成掺杂剂的物质的混合物作为阴离子，阳离子，分子和/或作为未解离的络合物制成溶液。
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3.发明授权
公开(公告)号：US5567297A
公开(公告)日：1996-10-22
申请号：US374431
申请日：1995-01-19
CPC分类号： C09D5/4476 , C09D4/00
摘要： A process for depositing by electropolymerization an organic film onto an electrically conductive surface, wherein use is made of a mixture comprising (a) at least one monomer suited for forming a polymer onto said surface, (b) at least one material which can be linked to said polymer, (c) a supporting electrolyte and (d) a solvent, said process comprising the use, as material to be linked to said polymer, of a reactive substance which can react chemically with the growing polymeric chains formed starting from the monomer.
摘要翻译： 一种通过电聚合将有机膜沉积在导电表面上的方法，其中使用由以下混合物组成的混合物：（a）至少一种适用于在所述表面上形成聚合物的单体，（b）可连接的至少一种材料 所述聚合物，（c）支持电解质和（d）溶剂，所述方法包括将作为与所述聚合物连接的材料用作反应性物质，所述活性物质可以与从单体开始形成的生长的聚合物链发生化学反应 。
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公开(公告)号：US06325911B1
公开(公告)日：2001-12-04
申请号：US09462297
申请日：2000-04-03
申请人： Marc Mertens , Lucien Martinot , Robert Jerome
发明人： Marc Mertens , Lucien Martinot , Robert Jerome
IPC分类号： C25D554
摘要： A method for making composites uses electrochemical polymer or copolymer coating of a carbon-based support by using a reaction system including (a) at least a monomer capable of forming a polymer on said support, (b) an aprotic solvent and (c) an electrolyte providing the resulting organic medium with an electrical conductivity for conducting therein electrolysis. The carbon support permanently forms the cathode, by applying either a potential or an electric current bringing the reaction system into the passivation zone corresponding to the first inhibition peak. The method forms a polymer grafted on the support.
摘要翻译： 一种制备复合材料的方法是使用包含（a）至少一种能够在所述载体上形成聚合物的单体的反应体系，使用电化学聚合物或共聚物涂覆碳基载体，（b）非质子溶剂和（c） 为所得有机介质提供电导率以在其中进行电解的电解质。 碳载体通过施加使反应体系进入对应于第一抑制峰的钝化区的电位或电流而永久地形成阴极。 该方法形成接枝在载体上的聚合物。
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5.发明授权Process for controlled radical polymerization or copolymerization of (meth)acrylic and vinyl monomers and (co)polymers obtained 失效获得的（甲基）丙烯酸和乙烯基单体和（共）聚合物的受控自由基聚合或共聚方法
公开(公告)号：US5767210A
公开(公告)日：1998-06-16
申请号：US827386
申请日：1997-03-27
IPC分类号： C08F2/24 , C08F2/02 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/26 , C08F4/28 , C08F4/72 , C08F4/80 , C08F20/00 , C08F20/14 , C08F2/00 , C08F20/06
摘要： This process is characterized by the fact that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature that can be as low as 0.degree. C., in the presence of an initiation system including: at least one compound generating radicals, other than bromofluorene, and at least one catalyst consisting of a complex of palladium in the 0 oxidation state, denoted by the following formula (I): Pd(0)L.sup.1 L.sup.2 L.sup.3 L.sup.4 in which each of L.sup.1, L.sup.2, L.sup.3 and L.sup.4, which are identical or different, denotes a ligand which may be a chiral ligand, which is chosen from PRR'R", P(OR)(OR')(OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", where each of R, R' and R" independently denotes a C.sub.1 -C.sub.14 alkyl group, optionally substituted, or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined to one another by one or more divalent radicals.
摘要翻译： 该方法的特征在于，在起始系统存在下，至少一种所述单体在本体，溶液，乳液或悬浮液中在可低至0℃的温度下聚合或共聚，包括 ：除了溴芴之外，至少一种产生自由基的化合物和至少一种由O型氧化态的钯络合物组成的催化剂，由下式（I）表示：Pd（0）L1L2L3L4，其中L1，L2 表示可以是手性配体的配体，其选自PRR'R“，P（OR）（OR'）（OR”）（OR“），NRR'R” ，ORR'，SRR'，SeRR'，AsRR'R“，SbRR'R”，其中R，R'和R“各自独立地表示任选取代的C 1 -C 14烷基或任选取代的芳族 这些配体中的至少两个可能通过一个或多个二价基团彼此连接。
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6.发明授权Process for the controlled radical (CO) polymerization of (Meth) acrylic vinyl vinylidene and diene monomers in the presence of an Rh Co OR Ir 失效（甲基）丙烯酸乙烯基亚乙烯基和二烯单体在Rh Co OR Ir存在下的受控自由基（CO）聚合方法
公开(公告)号：US5811500A
公开(公告)日：1998-09-22
申请号：US884219
申请日：1997-06-27
IPC分类号： C08F2/24 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/60 , C08F4/72 , C08F4/80 , C08F12/08 , C08F14/00 , C08F18/08 , C08F20/10 , C08F20/14 , C08F297/06 , C08F4/06
CPC分类号： C08F4/00
摘要： This process is characterized in that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0.degree. C., in the presence of an initiator system comprising at least one non-peroxy radical-generator compound and at least one catalyst consisting of a metal complex represented by formula Ma.sub.a (L).sub.n in which M represents Rh, Co or Ir; A represents, a halogen or a pseudohalogen; the groups L, which may be identical or different, each represent a ligand which may be a chiral ligand, which is chosen from cyclooctadiene, PRR'R", P(OR) (OR') (OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", each radical R, R' and R" independently representing an optionally substituted C.sub.1 -C.sub.14 alkyl group or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined together by one or more divalent radicals; a is an integer such that 1.ltoreq.a.ltoreq.3 ; n is an integer such that 1.ltoreq.n.ltoreq.5, and in the absence of activator.
摘要翻译： 该方法的特征在于，至少一种所述单体在本体，溶液，乳液或悬浮液中，在可能低至0℃的温度下，在至少包含至少 一种非过氧自由基产生剂化合物和至少一种由式Ma（L）n表示的金属配合物组成的催化剂，其中M表示Rh，Co或Ir; A表示卤素或假卤素; 可以相同或不同的基团L各自表示可以是手性配体的配体，其选自环辛二烯，PRR'R“，P（OR）（OR'）（OR”），NRR' R“，ORR'，SRR'，SeRR'，AsRR'R”，SbRR'R“，每个基团R，R'和R”独立地表示任选取代的C 1 -C 14烷基或任选取代的芳族 这些配体中的至少两个可能通过一个或多个二价基团连接在一起; a是整数，使得1
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7.发明授权公开(公告)号：US06348564B1
公开(公告)日：2002-02-19
申请号：US09595030
申请日：2000-06-16
IPC分类号： C08G6308
CPC分类号： C07D313/04 , C08G6/02 , C08G63/08
摘要： Unsubstituted oxepane-diones useful as monomers for the production of polymers, process for the synthesis thereof by oxidation of unsubstituted cyclohexanediones, process for the preparation of polyesterketone polymers by polymerization of cyclic esterketones and polyesterketone polymers so obtained.
摘要翻译： 可用作生产聚合物的单体的未取代的氧杂环庚烷二酮，通过未取代的环己二酮的氧化合成的方法，通过如此获得的环状酯酮和聚酯酮聚合物的聚合制备聚酯酮聚合物的方法。
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8.发明授权
公开(公告)号：US6166169A
公开(公告)日：2000-12-26
申请号：US232144
申请日：1999-01-15
CPC分类号： C08K5/13 , C08G63/78 , C08G63/823 , C08K5/524 , C08L67/00
摘要： An aliphatic polyester and/or copolyester, obtained from a polyreaction of at least one monomer from the group comprising lactides, lactones, cyclic carbonates and cyclic anhydrides. To be able to prepare the aliphatic polyester and/or copolyester a reaction mixture is used which contains at least one catalyst of the general formula (M) (X.sub.1, X.sub.2 . . . X), M being a metal selected from the group 3 to 12 of the periodic system (X.sub.1, X.sub.2 . . . X.sub.m) being a substituent selected from one of the families of alkyls, aryls, oxides, carboxylates, halogenides, alkoxides and compounds with elements from group 15 and/or 16 of the periodic system, m being an integer in the range of from 1 to 6, and n being an integer in the range of from 0 to 6, and which also contains a co-catalyst of the general formula (Y) (R.sub.1, R.sub.2 . . . R.sub.q).sub.p, Y being an element selected from the group 15 or 16 of the periodic system. (R.sub.1, R.sub.2 . . . R.sub.q) being a substituent selected from one of the families of the alkyls, aryls, oxides, halogenides, oxyalkyls, aminoalkyls, thiolkyls, phenoxides, aminioaryls, thioaryls, and q and p corresponding to the values for m and n.
摘要翻译： 由至少一种包含丙交酯，内酯，环状碳酸酯和环状酸酐的单体的多元反应获得的脂族聚酯和/或共聚酯。 为了能够制备脂肪族聚酯和/或共聚酯，使用含有至少一种通式（M）的催化剂（X1，X2 ... X）的反应混合物，M是选自组3 周期性系统（X1，X2 ... Xm）的12位是选自烷基，芳基，氧化物，羧酸盐，卤化物，醇盐和具有周期系统的第15和/或16族元素的化合物之一的取代基 m为1〜6的整数，n为0〜6的整数，并且还含有通式（Y）（R1，R2，...）的助催化剂。 R q）p，Y是选自周期系统的组15或16的元素。 （R1，R2 ... Rq）是选自烷基，芳基，氧化物，卤化物，烷氧基，氨基烷基，硫代烷基，苯氧基，氨基芳基，硫代芳基中的一个族的取代基，对应于m的值的q和p 和n。
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9.发明授权
公开(公告)号：US4897267A
公开(公告)日：1990-01-30
申请号：US225395
申请日：1988-07-28
申请人： Jose Bontemps , Philippe Pirson , Jean-Bernard Falmagne , Robert Jerome , Philippe Teyssie , Luc Delattre , Brigitte Evrard
发明人： Jose Bontemps , Philippe Pirson , Jean-Bernard Falmagne , Robert Jerome , Philippe Teyssie , Luc Delattre , Brigitte Evrard
CPC分类号： A61K47/48038 , A61K31/47 , A61K9/1647
摘要： The present invention relates to microparticles containing an active principle against malaria, such as primaquine, one of its amino acid derivatives, or their conjugates with a hepatotropic vector or their pharmaceutically acceptable salts, and a biocompatible and biodegradable polymer controlling the kinetics of release of the active principle, like (DL)polylactide. The invention also relates to pharmaceutical compositions comprising microcapsules according to the invention. Lastly, the invention relates to processes for the preparation of microparticles as mentioned above, the processes comprising: dissolving the polymer in a volatile solvent, adding to this solution the active principle and possibly a substance regulating the size of the microparticles, and at the end of evaporation, recovering the microparticles by centrifugation and filtration.
摘要翻译： 本发明涉及含有针对疟疾的活性成分的微粒，例如伯氨喹，其氨基酸衍生物之一或其与嗜肝性载体或其药学上可接受的盐的缀合物，以及控制释放动力学的生物相容性和可生物降解的聚合物 活性成分，如（DL）聚丙交酯。 本发明还涉及包含根据本发明的微胶囊的药物组合物。 最后，本发明涉及如上所述的制备微粒的方法，其方法包括：将聚合物溶解在挥发性溶剂中，向该溶液中加入活性成分和可能的调节微粒尺寸的物质，并在最后加入 的蒸发，通过离心和过滤回收微粒。
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10.发明授权Initiation system and process for anionic (co) polymerization of (Meth) acrylic, vinylaromatic and/or diene monomers 失效（甲基）丙烯酸，乙烯基芳族和/或二烯单体的阴离子（共）聚合的引发体系和方法公开(公告)号：US06489262B2
公开(公告)日：2002-12-03
申请号：US09058504
申请日：1998-04-10
IPC分类号： B01J3100
CPC分类号： C08F4/58 , C08F4/48 , C08F20/12 , C08F297/02 , C08F297/026
摘要： The present invention relates to an initiation system composed of the reaction product of at least one cyclic siloxane and at least one organometalic compound of sufficient reactivity to open the siloxane ring. Application of the present invention is to the preparation of homopolymers of (meth)acrylic, vinylaromatic or diene monomers, random or block copolymers of these monomers and, in particular, application to poly(methylmethacrylate) with a high content of isotactic triads.
摘要翻译： 本发明涉及由至少一种环状硅氧烷与至少一种具有足够反应性的有机金属化合物的反应产物组成的引发体系，以开启硅氧烷环。本发明的应用是制备（甲基）丙烯酸的均聚物 ，乙烯基芳族或二烯单体，这些单体的无规或嵌段共聚物，特别是应用于具有高含量的全同立构三单元组的聚（甲基丙烯酸甲酯）。
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