Abstract:
A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
Abstract:
The present method describes the absorbing and desorbing of a gaseous reactant on a solid reactant. The solid reactant is an ammonia salt selected from the group consisting of alkali ammonium salts, alkali ammonium earth salts or a combination thereof.
Abstract:
Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein a buffered ionic liquid is mixed with an organometallic complex of the formula: where X is a halogen, n=2 or 3, M=Ti, V, Cr, Mn, Fe, Co and Ni and R1, R2, R3 and R4 are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkynyl, alkyloxy, substituted aryl, and X are provided. A method for dimerizing alpha-olefins utilizing the immobilized buffered catalysts and a co-catalyst is also provided.
Abstract:
The present invention relates generally to buffered ionic liquids that are very useful for dimerization of olefins, such as isopropene, wherein the buffer is a phosphine or a bismuthine or an arsine or an amine.
Abstract:
An upper part (1) of an assembled piston is disclosed, comprising a radially directed inner contact surface (2) arranged on the underside of an annular rib (15) and a radially directed outer contact surface (3) arranged on the underside of an annular wall (25), the outer (3) and the inner contact surface (2) each having a grooved profile in the form of concentric grooves with an average depth between Rz 10 and Rz 30. The wear on the contacting surfaces of the upper piece and the lower piece of the assembled piston is thus reduced.
Abstract:
Described herein is a cost effective means for selenium recovery and refining relying on an impregnated substrate. The substrate is impregnated with selenium and provides a system and method for the environmentally safe discharge of previous selenium-contaminated solutions and an environmentally safe discharge of industrial waste water.
Abstract:
Methods and apparatus relate to treating fluid to at least reduce selenium content within the fluid, which may be an aqueous liquid and form a feed stream. The treating removes selenium that may be present in compounds, such as selenocyanate, from the feed stream based on adsorption from contact of the fluid with a sorbent. Flowing a gaseous hydrogen sulfide and sulfur dioxide containing stream over a support, such as activated carbon, may provide the sorbent impregnated with sulfur and utilized in the treating of the fluid.
Abstract:
A brake actuating device has an actuator functionally connected between a piston and a brake pedal lever. The actuator is capable of varying the path length of a force-conducting connection between the brake pedal lever and the piston of the brake cylinder via a displaceable element. A spring element acts on the brake pedal lever. The spring force varies during the variation of the path length such that a sum of the spring force and a force acting on the brake pedal lever from the brake cylinder remains essentially unchanged. The spring element is fastened with one end to the displaceable element and with the other end to the brake pedal lever with the interposition of a tensioning mechanism, which is guided by a cam track provided on the brake pedal lever. The cam track and the spring element are designed such that a displacement of the displaceable element into any possible position of the brake pedal lever does not generate a change in the pedal force at the brake pedal lever that is perceptible to the driver.
Abstract:
A series of new bis(imino)pyridine vanadium(III) complexes was synthesized according to formula: They were tested for the homogeneous catalytic dimerization of propylene after activation with MAO and showed excellent selectivity for dimerization. The catalysts can be used with or without PPh3 as an additive to produce ≧80% dimerized alkenes.
Abstract:
A process is disclosed for removing heavy metals from a hydrocarbon gas stream by contacting the hydrocarbon gas stream, which contains a heavy metal and less than 10 ppm oxidizing compounds, with a composition containing a molecular sieve and sulfur resulting in a treated stream containing less heavy metal than the hydrocarbon gas stream; wherein the molecular sieve contains alumina, silica, and iron, and optionally copper and zinc. Optionally, the hydrocarbon gas stream can also contain a sulfur compound.