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    Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation
    2.
    发明授权
    Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation 失效
    具有增强的表面耐久性的聚烯烃材料和通过暴露于辐射使其形成的方法

    公开(公告)号：US06790874B2

    公开(公告)日：2004-09-14

    申请号：US10208053

    申请日：2002-07-31

    申请人： Edmund K. Lau ,  Satchit Srinivasan ,  Peter J. Perron ,  Peter S. Solera ,  Anthony DeBellis ,  Chia-Hu Chang ,  Gerald Capocci ,  Joseph Puglisi ,  Douglas Horsey

    发明人： Edmund K. Lau ,  Satchit Srinivasan ,  Peter J. Perron ,  Peter S. Solera ,  Anthony DeBellis ,  Chia-Hu Chang ,  Gerald Capocci ,  Joseph Puglisi ,  Douglas Horsey

    IPC分类号： C08F246

    CPC分类号： C08J3/28 ,  C08J2323/02 ,  C08L9/00 ,  C08L21/00 ,  C08L23/02 ,  C08L23/0815 ,  C08L23/10 ,  C08L2205/03 ,  C08L2312/06 ,  C08L2666/04

    摘要： The invention relates to thermoplastic polyolefin compositions having enhanced surface durability and products thereof which include a thermoplastic polyolefin base component at least one radiation-crosslinkable component present in an amount sufficient to enhance the surface durability of the thermoplastic polyolefin component when radiation-cured and at least one photoinitiator present in an amount sufficient to initiate crosslinking of the radiation-crosslinkable component upon exposure of the thermoplastic polyolefin composition to radiation. The invention further relates to methods of providing a cured thermoplastic polyolefin composition having enhanced surface durability by preparing a mixture having a thermoplastic polyolefin base component, at least one radiation-crosslinkable component in an amount sufficient to enhance the surface durability of the polyolefin when radiation cured, and at least one photoinitiator each in an amount sufficient to facilitate crosslinking of the radiation-crosslinkable component when a surface of the thermoplastic polyolefin composition is exposed to radiation, and then exposing the thermoplastic polyolefin composition to radiation in an amount sufficient to crosslink the radiation-crosslinkable component thereby providing a thermoplastic polyolefin composition having enhanced surface durability.

    摘要翻译： 本发明涉及具有增强的表面耐久性的热塑性聚烯烃组合物及其产品，其包括热塑性聚烯烃基础组分至少一种可辐射交联组分，其量足以增强热辐射固化时的热塑性聚烯烃组分的表面耐久性，并且至少 一种光引发剂以足以在将热塑性聚烯烃组合物暴露于辐射时引发辐射可交联组分的交联的量存在。 本发明还涉及提供具有增强的表面耐久性的固化的热塑性聚烯烃组合物的方法，该组合物通过制备具有热塑性聚烯烃基础组分的混合物，至少一种可辐射交联组分，其量足以增强当辐射固化时聚烯烃的表面耐久性 和至少一种光引发剂，其量足以在热塑性聚烯烃组合物的表面暴露于辐射时促进辐射可交联组分的交联，然后将热塑性聚烯烃组合物暴露于足以交联辐射的量的辐射 - 可交联组分，从而提供具有增强的表面耐久性的热塑性聚烯烃组合物。

    TPO blends containing multimodal elastomers
    4.
    发明授权
    TPO blends containing multimodal elastomers 失效
    含有多峰弹性体的TPO共混物

    公开(公告)号：US06451894B1

    公开(公告)日：2002-09-17

    申请号：US09373787

    申请日：1999-08-13

    申请人： Satchit Srinivasan ,  Edward Szczepaniak ,  Jhy-Yuan Her ,  Michael K Laughner ,  Teresa Plumley Karjala

    发明人： Satchit Srinivasan ,  Edward Szczepaniak ,  Jhy-Yuan Her ,  Michael K Laughner ,  Teresa Plumley Karjala

    IPC分类号： C08L2300

    CPC分类号： C08L23/06 ,  C08L23/12 ,  C08L23/16 ,  C08L53/00 ,  C08L53/02 ,  Y10T428/31551 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

    摘要： Molded articles of thermoplastic polyolefin blends having improved resistance to fluids such as petroleum fuels after being painted with flexible coatings such as polyurethane paints and the like are disclosed. These blends include a crystalline or semi-crystalline polyolefin such as polyethylene, polypropylene, or a copolymer of ethylene and a C3 to C10 olefin, and a multimodal elastomer of sequentially polymerized ethylene-&agr;-olefin monomers. The substantially crystalline polyolefin is present in an amount of 30 to 98 weight percent, while the multimodal elastomer, which is substantially amorphous, is present in an amount of about 2 to 70 weight percent. The blends may contain additional polymeric components, fillers and the like. In addition to increased paint adherence, higher weld line strength, low temperature ductility, and processability can be achieved.

    摘要翻译： 公开了在涂覆有柔性涂层如聚氨酯涂料等之后，具有改进的耐流体性（例如石油燃料）的热塑性聚烯烃共混物的模塑制品。 这些共混物包括结晶或半结晶聚烯烃，例如聚乙烯，聚丙烯或乙烯与C 3 -C 10烯烃的共聚物，以及顺序聚合的乙烯-α-烯烃单体的多峰弹性体。 基本上结晶的聚烯烃以30至98重量％的量存在，而基本上无定形的多峰弹性体以约2-70重量％的量存在。 共混物可以含有另外的聚合物组分，填料等。 除了增加涂料粘附性，还可以实现更高的焊接线强度，低温延展性和加工性。

    Polyolefin materials having enhanced surface durability
    9.
    发明授权
    Polyolefin materials having enhanced surface durability 有权
    具有增强的表面耐久性的聚烯烃材料

    公开(公告)号：US06541568B1

    公开(公告)日：2003-04-01

    申请号：US09575660

    申请日：2000-06-01

    申请人： Ruidong Ding ,  Satchit Srinivasan ,  Edmund K. Lau

    发明人： Ruidong Ding ,  Satchit Srinivasan ,  Edmund K. Lau

    IPC分类号： C08L4700

    CPC分类号： C08L23/10 ,  C08L23/06 ,  C08L23/16 ,  C08L53/00 ,  C08L2666/04 ,  C08L2666/24

    摘要： Thermoplastic polymer blends and formed articles made thereof which exhibit superior physical properties such as a combination of excellent scratch resistance, rigidity and impact toughness. The thermoplastic polyolefin blend includes from about 40 percent to about 80 percent of a base component of propylene-containing polymer; from about 5 percent to about 30 percent of a toughening component; and from about 3 percent to about 40 percent of a thermoplastic elastomer, preferably of a high styrene containing block or random copolymer. A preferred thermoplastic polyolefin blend includes between about 50 percent to about 70 percent of the base component; between about 10 percent to about 20 percent of the toughening component; and between about 5 percent to about 20 percent of the styrene block copolymer. Advantageously, the thermoplastic elastomer has greater than 50 percent by weight styrene monomer.

    摘要翻译： 其制造的热塑性聚合物共混物和成型制品具有优异的物理性能，例如优异的耐擦伤性，刚性和冲击韧性的组合。 热塑性聚烯烃共混物包括约40％至约80％的含丙烯聚合物的基础组分; 约5％至约30％的增韧组分; 和约3％至约40％的热塑性弹性体，优选高含苯乙烯嵌段或无规共聚物。 优选的热塑性聚烯烃共混物包括约50％至约70％的基础组分; 约10％至约20％的增韧组分; 和约5％至约20％的苯乙烯嵌段共聚物。 有利地，热塑性弹性体具有大于50重量％的苯乙烯单体。

    Engineered polyolefin materials with enhanced surface durability
    10.
    发明授权
    Engineered polyolefin materials with enhanced surface durability 失效
    具有增强表面耐久性的工程聚烯烃材料

    公开(公告)号：US06403721B1

    公开(公告)日：2002-06-11

    申请号：US09672063

    申请日：2000-09-29

    申请人： Ruidong Ding ,  Satchit Srinivasan ,  Edmund K. Lau

    发明人： Ruidong Ding ,  Satchit Srinivasan ,  Edmund K. Lau

    IPC分类号： C08L900

    CPC分类号： C08L23/10 ,  C08L23/0815 ,  C08L23/0869 ,  C08L23/0876 ,  C08L51/06 ,  C08L53/00 ,  C08L2205/02 ,  C08L2666/04

    摘要： A polyolefin blend is presented that includes a base component of a propylene-containing-polymer, such as polypropylene, a propylene-based polyolefin-metal salt, and an ethylene-based polyolefin-metal salt. Optionally, the blend includes a copolymer of ethylene and an alpha-olefin; a terpolymer of ethylene, alpha-olefin, and a diene; a thermoplastic elastomer, such as an olefinic copolymer with styrene; and/or a copolymer of ethylene, at least one alpha-olefin, and a monomer with a hydrophilic moiety. Methods of preparing such blends, as well as resultant articles including such blends, are also part of the invention.

    摘要翻译： 提出了一种聚烯烃共混物，其包括含丙烯聚合物的基础组分，例如聚丙烯，丙烯类聚烯烃 - 金属盐和乙烯类聚烯烃 - 金属盐。 任选地，共混物包括乙烯和α-烯烃的共聚物; 乙烯，α-烯烃和二烯的三元共聚物; 热塑性弹性体，例如与苯乙烯的烯烃共聚物; 和/或乙烯，至少一种α-烯烃和具有亲水部分的单体的共聚物。 制备这种共混物的方法以及包括这种共混物的所得制品也是本发明的一部分。