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    Process and a composition for coating a metallic substrate with a polymeric film
    1.
    发明授权
    Process and a composition for coating a metallic substrate with a polymeric film 失效
    方法和用聚合物膜涂覆金属基材的组合物

    公开(公告)号：US4524092A

    公开(公告)日：1985-06-18

    申请号：US530002

    申请日：1983-09-07

    申请人： Sebastiano Cesca ,  Aldo Priola ,  Fiorenzo Renzi

    发明人： Sebastiano Cesca ,  Aldo Priola ,  Fiorenzo Renzi

    IPC分类号： B05D3/02 ,  B05D7/14 ,  C09D4/00

    CPC分类号： B05D7/142 ,  B05D3/0272 ,  C09D4/00

    摘要： There is disclosed the coating of a metallic substrate with a cross-linked polymeric film by contacting the substrate with an aqueous composition containing:at least an acrylic or metacrylic compound which can be defined by the general formula: ##STR1## wherein: R is a straight-line or branched aliphatic hydrocarbon radical, either saturated or unsaturated containing from 2 to 10 carbon atoms, or a cycloaliphatic or an aromatic group;R.sub.1 and R.sub.2, equal to or different from one another, are straight-line or branched alkyl groups, either saturated or unsaturated and containing from 1 to 8 carbon atoms, or cycloaliphatic or aromatic groups;at least one unsaturated organic acid capable of being copolymerized with the compound (I), in an amount of from 5 to 40 parts by weight per 100 parts of the compound (I) or an organic or a mineral acid which cannot be copolymerized with the compound (I) in an amount of from 1 to 10 parts by weight per 100 parts of the compound (I), anda polymerization catalyst preferably selected from among the persulphates, the hydroperoxides, the peracids H.sub.2 O.sub.2 and the peroxides.A metallic substrate coated by the composition of polymeric nature as described above is then heated to a temperature equal to, or lower than 180.degree. C. approximately and for the time which is necessary to originate a polymeric film cross-linked upon said substrate.A film so deposited exhibits optimum properties as to adherence, resistance to bending and shocks and resistance to the saline mist.

    摘要翻译： 公开了具有交联聚合物膜的金属基材的涂层，其通过使基底与水性组合物接触，所述水性组合物含有至少一种丙烯酸或甲基丙烯酸酯化合物，其可以由以下通式定义：其中： R是含有2至10个碳原子的饱和或不饱和的直链或支链脂族烃基，或脂环族或芳族基团; R1和R2彼此相同或不同，是饱和或不饱和且含有1至8个碳原子的直链或支链烷基，或脂环族或芳族基团; 能够与化合物（I）共聚的至少一种不饱和有机酸，相对于每100份化合物（I）为5〜40重量份，或不与上述化合物（I）不共聚的有机或无机酸） 化合物（I）的量为每100份化合物（I）为1-10重量份，优选选自过硫酸盐，氢过氧化物，过酸H 2 O 2和过氧化物的聚合催化剂。 然后将如上所述的由聚合物性质的组合物涂覆的金属基材加热到大约等于或低于180℃的温度，并且在所需的时间内产生在所述基材上交联的聚合物膜。 如此沉积的薄膜表现出粘附性，抗弯曲性和抗冲击性以及耐盐雾性的最佳性能。

    Procedure for the production of polymers and copolymers of isobutylene
    3.
    发明授权
    Procedure for the production of polymers and copolymers of isobutylene 失效
    制备异丁烯的聚合物和共聚物的方法

    公开(公告)号：US3965078A

    公开(公告)日：1976-06-22

    申请号：US503599

    申请日：1974-09-06

    申请人： Aldo Priola ,  Sebastiano Cesca ,  Giuseppe Ferraris

    发明人： Aldo Priola ,  Sebastiano Cesca ,  Giuseppe Ferraris

    IPC分类号： C08F10/00 ,  C08F210/12 ,  C08F4/52

    CPC分类号： C08F10/00 ,  C08F210/12

    摘要： A method is described for the polymerization of isobutylene and, in particular, the copolymerization of isobutylene and isoprene to produce butyl rubber, by contacting the monomers with a catalyst prepared from: (a) an organoaluminum compound (e.g. Al(C.sub.2 H.sub.5).sub.2 Cl) and (b) a compound represented by the formula X'.sub.n M.sub.e Y.sub.m in which X' is a halogen atom; Y is oxygen, sulphur or a functional group selected from the alkoxies, esters, amides, simple or substituted alkyls, cycloalkyls, aromatics, arenes, phosphines, acetylacetones and oximes; Me is an element selected from Ti, Sn, Zn, B, Al, Hg, Pb, W, Sb, Ge, V, Zr, As, Bi and Mo; n and m are whole numbers whose sum equals the valence of Me except where Y is oxygen or sulphur, when the valency equals 2m + n, (e.g. Ti(O nC.sub.4 H.sub.9)Cl.sub.3), in a liquid reaction medium constituted by an aliphatic, aromatic, cycloaliphatic or halogenated hydrocarbon such as methyl chloride, and at a temperature in the range from -100.degree. to 30.degree.C.

    摘要翻译： 描述了用于异丁烯聚合的方法，特别是异丁烯和异戊二烯的共聚以制备丁基橡胶，方法是使单体与由（a）有机铝化合物（例如Al（C 2 H 5）2 Cl）和 （b）由式X'n Me Ym表示的化合物，其中X'为卤素原子; Y是氧，硫或选自烷氧基，酯，酰胺，简单或取代的烷基，环烷基，芳族化合物，芳烃，膦，乙酰丙酮和肟的官能团; Me是选自Ti，Sn，Zn，B，Al，Hg，Pb，W，Sb，Ge，V，Zr，As，Bi和Mo中的一种元素; n和m是总和等于Me的化合价的整数，除非是Y是氧或硫，当化合价等于2m + n时，例如Ti（O nC 4 H 9）Cl 3） 芳香族，脂环族或卤代烃如甲基氯，并且在-100至30℃的温度下。

    Process for the production of polymers and copolymers of isobutylene
    5.
    发明授权
    Process for the production of polymers and copolymers of isobutylene 失效
    用于生产异丁烯的聚合物和共聚物的方法

    公开(公告)号：US4107417A

    公开(公告)日：1978-08-15

    申请号：US503600

    申请日：1974-09-06

    申请人： Aldo Priola ,  Sebastiano Cesca ,  Giuseppe Ferraris

    发明人： Aldo Priola ,  Sebastiano Cesca ,  Giuseppe Ferraris

    IPC分类号： C08F10/10 ,  C08F4/64 ,  C08F4/60 ,  C08F210/12 ,  C08F236/04

    CPC分类号： C08F10/10

    摘要： A process is described whereby homopolymers and copolymers of isobutylene are prepared by effecting the polymerization at a temperature in the range of -100.degree. to 30.degree. C in the presence of a catalyst system including:(a) a compound selected from the group consisting of: AlCl.sub.3, AlBr.sub.3, AlEtCl.sub.2, TiCl.sub.4, SnCl.sub.4, SiCl.sub.4, VCl.sub.4, BF.sub.3, Al.sub.2 Et.sub.3 Cl.sub.3, SbCl.sub.5, SbF.sub.5, FeCl.sub.3, VOCl.sub.3, ZrCl.sub.4, AlI.sub.3, GaCl.sub.3 ; and(b) a compound adapted to react with the compounds of group (a) and selected from the group consisting of: SnR.sub.4, SnRX.sub.3, SrR.sub.4, TiX.sub.2 (OR).sub.2, Ti(OR).sub.4, PbR.sub.4, Ti(OR)X.sub.3, VO(OR).sub.3, Ti(OR).sub.3 X, (C.sub.5 H.sub.5).sub.2 Ti(C.sub.6 H.sub.5).sub.2, (C.sub.5 H.sub.5).sub.2 Ti(CH.sub.3).sub.2, Ti(Acac).sub.4, SnCl.sub.2 (acetate).sub.2 in which R is a hydrocarbon radical with from 1 to 10 carbon atoms and X is a halogen atom.The process is of particular value in the production of butyl rubber through the copolymerization of isobutylene and isoprene.

    摘要翻译： 描述了一种方法，其中通过在-100至30℃范围内的温度下，在催化剂体系存在下进行聚合制备异丁烯的均聚物和共聚物，所述催化剂体系包括：

    High molecular weight soluble polymers starting from polycyclic polyenes having two conjugated double bonds and process for preparing same
    7.
    发明授权
    High molecular weight soluble polymers starting from polycyclic polyenes having two conjugated double bonds and process for preparing same 失效
    从具有两个共轭双键的多环多烯烃开始的高分子量可溶性聚合物及其制备方法

    公开(公告)号：US4029871A

    公开(公告)日：1977-06-14

    申请号：US590574

    申请日：1975-06-26

    申请人： Aldo Priola ,  Arnaldo Roggero ,  Sebastiano Cesca

    发明人： Aldo Priola ,  Arnaldo Roggero ,  Sebastiano Cesca

    IPC分类号： C08F12/32

    CPC分类号： C08F12/32

    摘要： A class of soluble polymers of high molecular weight is disclosed whose members are: copolymers of polycyclic polyenes containing two conjugated double bonds which are members of the group consisting of a) polycyclic polyenes having an endomethylenic system orthocondensed with another hydrocarbon ring wherein the two common carbon atoms form a part of a conjugated diene system whose double bonds are located inside the non-endomethylenic ring, b) polyenes presenting an alkylidene group conjugated with a double bond of a ring which forms a part of an endocyclic system, and c) orthocondensed polycyclic polyenes substituted with an alkylidene type ring whose double bond is conjugated with a double bond of one of the cycles; and homopolymers of at least one of said polycyclic polyenes with at least one other conjugated diene. They may be prepared by reacting the selected monomers in the presence of a cationic catalyst selected from the halides of metals of the second to eighth groups of the periodic system and the alkyl derivatives thereof, which may be complexed with water, alcohols, acids, ethers or alkylhalides.

    摘要翻译： 公开了一类高分子量的可溶性聚合物，其成员为：含有两个共轭双键的多环多烯共聚物，其为由以下组成的组的组成：a）具有与另一个烃环稠合的内部亚甲基系统的多环多烯，其中两个共同碳 原子形成共轭二烯系统的一部分，其双键位于非内甲基环内，b）呈现与形成环内系统的一部分的环的双键共轭的亚烷基的多烯，以及c）缩合多环 被双键与一个循环的双键共轭的亚烷基型环取代的多烯; 和至少一种所述多环多烯与至少一种其它共轭二烯的均聚物。 它们可以通过选择的单体在阳离子催化剂的存在下反应制备，该阳离子催化剂选自周期系统的第二至第八组的金属的卤化物及其烷基衍生物，其可与水，醇，酸，醚络合 或烷基卤化物。

    Expandable Bladder
    9.
    发明申请
    Expandable Bladder 审中-公开
    可扩展膀胱

    公开(公告)号：US20090212467A1

    公开(公告)日：2009-08-27

    申请号：US11883128

    申请日：2005-01-26

    申请人： Nanni Marco Nahmias ,  Massimo Loprevite ,  Roberta Bongiovanni ,  Anna Di Gianni ,  Aldo Priola

    发明人： Nanni Marco Nahmias ,  Massimo Loprevite ,  Roberta Bongiovanni ,  Anna Di Gianni ,  Aldo Priola

    IPC分类号： B29C33/50 ,  B29D30/06 ,  C08L21/00

    CPC分类号： C08L51/04 ,  B29D30/0654 ,  B29D2030/0655 ,  C08F255/10 ,  C08L51/06 ,  C08L2666/02

    摘要： An expandable bladder for manufacturing pneumatic tyres is used in combination with a vulcanisation apparatus including, for example, a mould having a plurality of sidewall plates and tread sectors that, when the mould is closed, delimit a moulding cavity suitable for housing the green pneumatic tyre to be cured. The expandable bladder includes an elastomeric material obtained by curing an elastomeric composition which includes at least one butyl rubber and at least one compound having at least one double bond and an at least partially fluorinated alkyl or polyoxyalkylene chain.

    摘要翻译： 用于制造充气轮胎的可膨胀囊与硫化装置组合使用，硫化装置包括例如具有多个侧壁板和胎面部分的模具，当模具关闭时，模具限定适于容纳绿色充气轮胎的模制腔 待痊愈 可膨胀囊包括通过固化包含至少一种丁基橡胶和至少一种具有至少一个双键和至少部分氟化的烷基或聚氧化烯链的化合物的弹性体组合物而获得的弹性体材料。