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公开(公告)号:US20190329521A1
公开(公告)日:2019-10-31
申请号:US16475420
申请日:2018-01-11
发明人: Yasuhiro SHIBAI , Ken ATSUMO , Kenichiro NAKAMATSU
摘要: The present invention provides an antifouling film that is excellent in antifouling properties, adhesion, rubbing resistance, and reliability, and reduces fingerprint emergence at high humidity. The antifouling film includes a substrate; and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light, the polymer layer being a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active components, 20 to 90 wt % of a polyfunctional acrylate containing an ethylene oxide group, 5 to 25 wt % of a monofunctional amide monomer, and 0.5 to 10 wt % of a fluorine-based release agent, the polymerizable composition containing, in terms of active components, a total of 40 to 65 wt % of the ethylene oxide group in the polyfunctional acrylate and the monofunctional amide monomer.
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公开(公告)号:US20210363482A1
公开(公告)日:2021-11-25
申请号:US17051461
申请日:2019-08-09
IPC分类号: C12N5/00
摘要: A three-dimensional culture method includes: providing a cell suspension, the cell suspension containing a cell (12C) and a culture medium (14M); providing a solid surface (10S), the solid surface having a plurality of raised portions (10Sp) whose height is not less than 10 nm and not more than 1 mm; attaching a liquid drop (16D) of the cell suspension to the solid surface (10S); and culturing the cell (12C) in the liquid drop (16D) under such conditions that a direction of gravity exerted on the liquid drop (16D) is toward the solid surface (10S).
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公开(公告)号:US20190300666A1
公开(公告)日:2019-10-03
申请号:US16317159
申请日:2017-07-03
发明人: Hidekazu HAYASHI , Tokio TAGUCHI , Kenichiro NAKAMATSU , Yasuhiro SHIBAI , Ken ATSUMO , Tsuneo YAMASHITA , Eiji SAKAMOTO , Saya NII , Takayuki ARAKI
摘要: The present invention provides a method for producing an antifouling film capable of long-term continuous production of an antifouling film having excellent antifouling properties. The method for producing an antifouling film of the present invention includes Process (1) of applying a resin to a surface of a substrate; Process (2) of applying a second release agent to a surface of a die coated with a first release agent; Process (3) of pushing the substrate to the surface of the die coated with the second release agent with the resin in between to form an uneven structure on a surface of the resin; and Process (4) of curing the resin including the uneven structure on the surface thereof to form a polymer layer. The resin contains an antifouling agent that contains a predetermined compound. The first release agent contains a predetermined compound. The second release agent contains a predetermined compound.
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公开(公告)号:US20170066207A1
公开(公告)日:2017-03-09
申请号:US15118536
申请日:2016-02-10
发明人: Hidekazu HAYASHI , Tokio TAGUCHI , Nobuaki YAMADA , Yasuhiro SHIBAI , Atsushi NIINOH , Kenichiro NAKAMATSU
IPC分类号: B29D11/00 , C09D175/16 , C09D133/08 , G02B1/14 , C09D5/16 , C09D5/00 , G02B1/118 , G02B1/18 , B29C33/62 , C09D133/24
CPC分类号: B29D11/00788 , B29C33/62 , B29C35/0805 , B29C59/026 , B29C2035/0827 , B29C2059/023 , B29D11/0073 , B29D11/00865 , B29K2033/04 , B29K2105/0002 , B29K2105/0005 , B29K2995/0087 , B29K2995/0097 , B32B3/30 , B32B27/08 , B32B27/30 , B32B37/15 , B32B38/06 , B32B2551/00 , C08F290/067 , C08L75/16 , C09D5/006 , C09D5/1662 , C09D5/1681 , C09D5/1693 , C09D133/08 , C09D133/24 , C09D175/16 , G02B1/118 , G02B1/14 , G02B1/18 , C08F222/1006
摘要: A method for producing an optical film includes: (1) applying a lower layer resin and an upper layer resin; (2) forming a resin layer having the uneven structure on a surface thereof by pressing a mold against the lower layer resin and the upper layer resin from the upper layer resin side in the state where the applied lower layer resin and upper layer resin are stacked; and (3) curing the resin layer, the lower layer resin containing at least one kind of first monomer that contains no fluorine atoms, the upper layer resin containing a fluorine-containing monomer and at least one kind of second monomer that contains no fluorine atoms, at least one of the first monomer and the second monomer containing a compatible monomer that is compatible with the fluorine-containing monomer and being dissolved in the lower layer resin and the upper layer resin.
摘要翻译: 制造光学膜的方法包括:(1)施加下层树脂和上层树脂; (2)在施加的下层树脂和上层树脂堆叠的状态下,通过从上层树脂侧将模具压靠在下层树脂和上层树脂上而在其表面上形成具有凹凸结构的树脂层 ; 和(3)固化树脂层,含有至少一种不含氟原子的第一种单体的下层树脂,含有含氟单体的上层树脂和不含氟原子的至少一种第二单体 第一单体和第二单体中的至少一种含有与含氟单体相容并溶解在下层树脂和上层树脂中的相容单体。
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公开(公告)号:US20220126542A1
公开(公告)日:2022-04-28
申请号:US17569623
申请日:2022-01-06
IPC分类号: B29D11/00 , B32B3/30 , G02B1/118 , G02B1/18 , B29C59/02 , C09D5/16 , C08F290/06 , C08L75/16 , B32B27/08 , G02B1/14 , B29C33/62 , C09D5/00 , C09D133/08 , C09D133/24 , C09D175/16 , B32B27/30 , B32B37/15
摘要: The present invention provides a method for producing an optical film excellent in anti-fouling properties and scratch resistance as well as anti-reflection properties. The method includes the steps of: (1) applying a lower layer resin and an upper layer resin; (2) forming a resin layer having the uneven structure on a surface thereof by pressing a mold against the lower layer resin and the upper layer resin from the upper layer resin side in the state where the applied lower layer resin and upper layer resin are stacked; and (3) curing the resin layer, the lower layer resin containing at least one kind of first monomer that contains no fluorine atoms, the upper layer resin containing a fluorine-containing monomer and at least one kind of second monomer that contains no fluorine atoms, at least one of the first monomer and the second monomer containing a compatible monomer that is compatible with the fluorine-containing monomer and being dissolved in the lower layer resin and the upper layer resin.
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公开(公告)号:US20190284355A1
公开(公告)日:2019-09-19
申请号:US16352993
申请日:2019-03-14
发明人: Yasuhiro SHIBAI , Miho YAMADA
IPC分类号: C08J5/18 , C08K5/00 , C08K5/092 , C08K5/07 , C08K5/3417 , C08F265/06 , C08F2/48 , B32B27/30 , B32B3/30 , B32B27/36 , B32B23/08
摘要: A synthetic polymer film has a surface which has a plurality of raised or recessed portions, wherein the synthetic polymer film has a cross-linked structure, and the synthetic polymer film contains an antimicrobial additive which is permitted by law for addition to food and which has an antimicrobial effect.
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公开(公告)号:US20190233656A1
公开(公告)日:2019-08-01
申请号:US16317161
申请日:2017-07-03
发明人: Hidekazu HAYASHI , Tokio TAGUCHI , Kenichiro NAKAMATSU , Yasuhiro SHIBAI , Ken ATSUMO , Tsuneo YAMASHITA , Saya NII , Eiji SAKAMOTO , Kakeru HANABUSA , Hisashi MITSUHASHI , Takayuki ARAKI
CPC分类号: C09D5/00 , B29C37/0067 , B29C59/026 , B29C59/046 , B29C2035/0827 , B29C2059/023 , B32B27/16 , B32B27/18 , B32B27/30 , B32B38/06 , C08G18/48 , C08G18/67 , C08G18/6755 , C08G18/72 , C08G18/79 , C09D175/14 , G02B1/18 , G03F7/0002
摘要: The present invention provides a method for producing an antifouling film having excellent antifouling properties and rubbing resistance. The method for producing an antifouling film of the present invention includes Process (1) of applying a resin to a surface of a substrate; Process (2) of pushing the substrate to a die with the resin in between to form an uneven structure on a surface of the resin; and Process (3) of curing the resin including the uneven structure on the surface thereof to form a polymer layer. The resin contains an antifouling agent that contains a compound containing a perfluoro(poly)ether group. The die includes a surface having undergone release treatment using a release agent containing a compound that contains a perfluoro(poly)ether group, a hydrolyzable group, and a Si atom.
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公开(公告)号:US20200298539A1
公开(公告)日:2020-09-24
申请号:US16820901
申请日:2020-03-17
发明人: Yasuhiro SHIBAI , Yu YAMANE , Tokio TAGUCHI
摘要: A plastic product includes: a plastic base having a surface, the surface being made of a cycloolefin polymer; and a synthetic polymer film formed on the surface of the plastic base. The synthetic polymer film is formed from a photocurable resin containing an oxime ester-based photopolymerization initiator in an amount of not less than 0.1 mass % and not more than 5 mass % on the basis of the entire photocurable resin.
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公开(公告)号:US20200071560A1
公开(公告)日:2020-03-05
申请号:US16495462
申请日:2018-03-14
发明人: Yasuhiro SHIBAI , Ken ATSUMO , Kenichiro NAKAMATSU
IPC分类号: C09D135/02 , C09D5/00 , C09D7/65
摘要: The An antifouling film includes: a substrate; and a polymer layer including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light. The polymer layer is a cured product of a polymerizable composition. The polymerizable composition contains, in terms of active components, 75 to 98 wt % of a polyfunctional acrylate, 0.5 to 10 wt % of a fluorine-based release agent, and 1 to 14 wt % of a monofunctional amide monomer. The polymer layer has a bottom temperature at which a storage modulus E′ of the polymer layer is minimum of 90° C. to 150° C. and a minimum storage modulus E′ of 0.9×108 to 4.5×108 Pa in a dynamic viscoelasticity measurement within a measurement temperature range of −50° C. to 250° C. and at a temperature increasing rate of 5° C./min and a frequency of 10 Hz.
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公开(公告)号:US20200002488A1
公开(公告)日:2020-01-02
申请号:US16488257
申请日:2017-10-13
发明人: Yasuhiro SHIBAI , Ken ATSUMO , Tokio TAGUCHI
摘要: A decorative film includes: a substrate; and a polymer layer including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light. The substrate contains a polycarbonate at least in its surface close to the polymer layer. The polymer layer is a cured product of a polymerizable composition. The polymerizable composition contains a release agent, a polyfunctional acrylate containing one or both of an ethylene oxide group and a propylene oxide group, and 2-(2-vinyloxyethoxy)ethyl acrylate. The polymerizable composition contains, in terms of active components, given proportions of the release agent and the 2-(2-vinyloxyethoxy)ethyl acrylate. The polymerizable composition contains, in terms of active components, a given total amount of the ethylene oxide group and the propylene oxide group in the polyfunctional acrylate and the 2-(2-vinyloxyethoxy)ethyl acrylate.
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