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公开(公告)号：US4213944A
公开(公告)日：1980-07-22
申请号：US859176
申请日：1977-12-09
申请人： Shigeru Azuhata , Hidetoshi Akimoto , Hideo Kikuchi , Yukio Hishinuma , Ryoichiro Oshima , Yoshijiro Arikawa
发明人： Shigeru Azuhata , Hidetoshi Akimoto , Hideo Kikuchi , Yukio Hishinuma , Ryoichiro Oshima , Yoshijiro Arikawa
CPC分类号： B01D53/56
摘要： A hot gas containing nitrogen oxides is admixed with ammonia and hydrogen peroxide to reduce the nitrogen oxides to nitrogen and water. Reduction reaction of the nitrogen oxides by ammonia is considerably promoted in a temperature range of 400.degree. to 800.degree. C. by the addition of hydrogen peroxide, and also ammonia present in excess of the nitrogen oxides is decomposed thereby, eliminating an unreacted ammonia effluent.
摘要翻译： 含有氮氧化物的热气体与氨和过氧化氢混合以将氮氧化物还原成氮和水。 通过加入过氧化氢，在400〜800℃的温度范围内，氨的还原反应得到显着的促进，而且存在于过氧化氮中的氨也被分解，从而消除了未反应的氨流出物。
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2.发明授权
公开(公告)号：US4119702A
公开(公告)日：1978-10-10
申请号：US817745
申请日：1977-07-21
CPC分类号： B01D53/56
摘要： Nitrogen oxides in a combustion flue gas are removed by reduction in a gaseous phase at a low temperature in the absence of any catalyst by adding urea and an oxidizing agent for decomposition of urea, such as ozone, nitric acid, hydrogen peroxide, chlorine, chlorine dioxide, or oxy acids of chlorine or their salts. NO.sub.x removal can be carried out in a very simplified manner with high percent NO.sub.x removal.
摘要翻译： 在没有任何催化剂的情况下，通过添加尿素和用于尿素分解的氧化剂如臭氧，硝酸，过氧化氢，氯，氯等，在低温下通过还原气相来除去燃烧烟道气中的氮氧化物 二氧化物或氯的氧酸或其盐。 可以以非常简单的方式进行NOx去除，同时除去高的NOx。
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公开(公告)号：US4031185A
公开(公告)日：1977-06-21
申请号：US653949
申请日：1976-01-30
CPC分类号： B01D53/8628
摘要： The present invention relates to a process for removing nitrogen oxides contained in a gaseous mixture such as combustion flue gas, etc. by reduction of the nitrogen oxides with ammonia, and a cuprous or cupric halide is used as a catalyst to carry out the reduction in a low temperature range. As a result, nitrogen oxides can be satisfactorily removed by the reduction even at about 150.degree. C.
摘要翻译： 本发明涉及通过用氨还原氮氧化物除去诸如燃烧烟气等的气体混合物中所含的氮氧化物的方法，并且使用亚铜或二卤化铜作为催化剂进行还原 低温范围。 结果，即使在约150℃下也可以通过还原令人满意地除去氮氧化物。
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公开(公告)号：US4081509A
公开(公告)日：1978-03-28
申请号：US668432
申请日：1976-03-19
CPC分类号： B01D53/56
摘要： Nitrogen oxides are removed from a flue gas by wet process, where the flue gas is contacted with a solution of transition metal complex compounds capable of reacting with oxygen in the presence of oxygen, thereby forming oxygen complexes, and the nitrogen oxides are oxidized and absorbed by the oxygen complexes.
摘要翻译： 通过湿法从烟道气中除去氮氧化物，其中烟气与能够在氧气存在下与氧反应的过渡金属络合物溶液接触，从而形成氧络合物，氮氧化物被氧化和吸收 由氧配合物。
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公开(公告)号：US4605776A
公开(公告)日：1986-08-12
申请号：US694099
申请日：1985-01-23
申请人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
CPC分类号： C07F15/0066 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/35
摘要： A process for producing acetone selectively and with a high yield by oxidizing propylene by means of the combined oxygen in an oxygen complex under milder conditions and at a single stage is provided wherein a composite catalyst comprising as catalyst components, a transition metal complex with the metal ion of which oxygen molecule can coordinate to form an oxygen complex, and another kind transition metal complex with the metal ion of which propylene can coordinate to form a propylene complex is employed, and propylene activated by the complex formation is oxidized by the combined oxygen activated by the complex formation to thereby obtain acetone.
摘要翻译： 提供了一种通过在较温和的条件和单一阶段通过在氧络合物中的组合氧氧化丙烯而选择性且高产率的方法，其中复合催化剂包含作为催化剂组分的过渡金属络合物与金属 氧分子可以配位以形成氧络合物的离子，以及与丙烯可以配位以形成丙烯络合物的金属离子的另一种过渡金属络合物，并且通过复合氧化活化的丙烯被氧化 通过络合物形成从而获得丙酮。
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6.发明授权Method of preventing scale from being deposited in case of producing fresh water from sea water 失效在海水生产淡水的情况下防止水垢沉积的方法
公开(公告)号：US3932224A
公开(公告)日：1976-01-13
申请号：US532814
申请日：1974-12-16
CPC分类号： C02F5/02 , C02F1/042 , Y10S159/13 , Y10S159/38 , Y10S203/18
摘要： A method of preventing scale from being deposited in case of producing fresh water from sea water by heating the sea water in a vapour pressure type evaporator and multiple stage flush evaporator and by condensing water vapour evolved to obtain the fresh water comprising adding to the sea water small amount of seed crystal selected from the group consisting of calcium carbonate and magnesium hydroxide together with a surface active agent selected from the group consisting of a nonionic active agent and cation surface active agent.
摘要翻译： 一种在蒸气压式蒸发器和多级冲洗蒸发器中加热海水并通过冷凝放出的水蒸气以获得淡水的方法，在通过海水生产淡水的情况下防止水垢沉积，包括向海水中添加 少量选自碳酸钙和氢氧化镁的晶种以及选自非离子活性剂和阳离子表面活性剂的表面活性剂。
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公开(公告)号：US4691053A
公开(公告)日：1987-09-01
申请号：US617187
申请日：1984-06-04
申请人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
发明人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
IPC分类号： B01J31/18 , C07C45/38 , C07C45/34 , C07C45/39 , C07C51/235 , C07C51/255 , C07D307/34 , C07D307/89
CPC分类号： B01J31/1845 , B01J2231/70 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： A novel process for producing oxygen-containing organic compounds with high selectivity and good yield by oxidizing organic compounds under mild conditions is provided, which process comprises using as a catalyst for the oxidation, a complex (M.sub.m X.sub.n.L.sub.l) consisting of a transition metal compound (M.sub.m X.sub.n) and an organic phosphorous compound (L) as a ligand, wherein M represents a transition metal belonging to group I, group IV.about.VII or iron group in group VIII of the periodic table; X represents an anion such as a halogen; ligand L represents an organic phosphorous compound; and m and n mean a number of the atomic valence of said transition metal (ion) M and said anion X, respectively, and l means a number of said ligand.
摘要翻译： 提供了一种通过在温和条件下氧化有机化合物来生产具有高选择性和良好产率的含氧有机化合物的新方法，该方法包括使用由过渡金属化合物组成的络合物（MmXn.Ll） （MmXn）和作为配体的有机磷化合物（L），其中M表示属于元素周期表第I族，第IV族Ⅶ族或第Ⅷ族铁族的过渡金属; X表示阴离子，例如卤素; 配体L表示有机磷化合物; m和n分别表示所述过渡金属（离子）M和所述阴离子X的原子价数，l表示所述配体的数目。
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公开(公告)号：US4277452A
公开(公告)日：1981-07-07
申请号：US110558
申请日：1980-01-08
CPC分类号： B01D53/62
摘要： The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride.Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.
摘要翻译： 本发明涉及含有亚硝酸根离子，盐酸和三氯化钛的一氧化碳吸收液。 三氯化钛有效提高一氧化碳吸收量。 此外，三氯化钛显着增加了耐氧化性。 因此，这种吸收液体可以连续使用长时间使用。
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9.发明授权Interface for use in a combined liquid chromatography - mass spectrometry system 失效用于组合液相色谱 - 质谱系统的界面
公开(公告)号：US4112297A
公开(公告)日：1978-09-05
申请号：US811720
申请日：1977-06-30
CPC分类号： H01J49/0468 , G01N30/7246 , G01N30/728 , H01J49/0445 , G01N1/22
摘要： A new interface is interposed between a liquid chromatograph and a mass spectrometer, and it consists of a nebulizer, an evaporator and a cooler. An effluent from the liquid chromatograph is nebulized by the nebulizer. The nebulized effluent is heated by the evaporator, and has only its solvent evaporated. A mixed fluid which consists of the evaporated solvent and the nebulized sample is guided to the cooler, and is cooled therein. At this time, the evaporated solvent is condensed again and is separated from the nebulized sample as a liquid. The nebulized sample left behind is guided to an ion source of the mass spectrometer.
摘要翻译： 在液相色谱仪和质谱仪之间插入一个新的界面，它由雾化器，蒸发器和冷却器组成。 来自液相色谱仪的流出液被喷雾器雾化。 雾化的流出物通过蒸发器加热，仅溶剂蒸发。 由蒸发的溶剂和雾化样品组成的混合流体被引导到冷却器中并在其中冷却。 此时，蒸发的溶剂再次冷凝，并作为液体与雾化样品分离。 留下的雾化样品被引导到质谱仪的离子源。
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10.发明授权
公开(公告)号：US4806692A
公开(公告)日：1989-02-21
申请号：US820004
申请日：1986-01-21
申请人： Mutsuo Yamada , Taiji Kamiguchi , Hirotoshi Tanimoto , Yoshijiro Arikawa , Hiroyuki Kaku , Shigehito Takamoto
发明人： Mutsuo Yamada , Taiji Kamiguchi , Hirotoshi Tanimoto , Yoshijiro Arikawa , Hiroyuki Kaku , Shigehito Takamoto
摘要： A process for producing an oxygen-containing organic compound by oxidizing olefins under milder conditions is provided, which process comprises oxidizing an olefin activated by its complex formation, in the presence of a platinum group metal complex capable of forming an olefin complex through coordination of the platinum group metal with said olefin, and also in the presence of water, and further oxidizing and regenerating the resulting reduced platinum group metal complex with oxygen coordinated with a transition metal and activated thereby.
摘要翻译： 提供了一种通过在较温和的条件下氧化烯烃来生产含氧有机化合物的方法，该方法包括在能够形成烯烃络合物的铂族金属配合物的存在下氧化由其络合物形成活化的烯烃， 铂族金属与所述烯烃反应，并且还在水的存在下进一步氧化和再生所得到的还原的铂族金属络合物与过渡金属配位的氧并被活化。
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