摘要:
It is suppressed that nanoparticles generated in an internal combustion engine are discharged into the atmosphere. In a cylinder or an exhaust system of the internal combustion engine, microparticles having a particle diameter larger than that of the nanoparticles are generated, and the nanoparticles generated in the internal combustion engine are adsorbed by the microparticles, thereby increasing the diameter of the nanoparticles. The microparticles can be generated in the cylinder as the soot, for example. Additionally, by providing a carbon microparticle generation device in the exhaust system, the microparticles can be generated, too. By making the nanoparticles adsorbed by the microparticles and increasing the diameter of the nanoparticles, discharging of the nanoparticles can be suppressed.
摘要:
An exhaust gas purifying catalyst that exhibits purifying performance even at high temperatures. The catalyst carries an alkali metal and a noble metal on a crystalline zirconium composite oxide, wherein the zirconium composite oxide is one in which zirconium is partly substituted with at least one kind of element selected from the group consisting of an alkaline earth metal, a rare earth metal and an element of the group IIIB, and the elongation of the crystal lattice due to the substitution with the element assumes a nearly theoretical value.
摘要:
There is provided a particulate matter combustion catalyst which allows easy combustion of particulate matter collected on the particulate matter filter of a diesel vehicle, at a much lower temperature than by the prior art. The particulate matter combustion catalyst has a construction characterized by an NO oxidation catalyst wherein the catalyst component is carried on an acidic first carrier, and an NO2 decomposition catalyst wherein the catalyst component is carried on a second carrier. Preferably, the NO oxidation catalyst has a precious metal such as platinum carried on an acidic first carrier such as tungstic acid/zirconia, and the NO2 decomposition catalyst has a catalyst component selected from the transition metals carried on a second carrier such as titania, or alternatively, the NO2 decomposition catalyst has at least one metal selected from among alkali metals and alkaline earth metals and a precious metal such as platinum carried on a second carrier such as titania.
摘要:
An exhaust gas purifying catalyst capable of exerting excellent NOx purifying capability even at high exhaust gas temperatures, exceeding 500° C., is provided.The catalyst is an absorption reduction-type NOx purifying catalyst comprising an NOx absorbent obtained by loading at least one alkali metal or alkaline earth metal on a crystalline ZrO2 composite oxide having added thereto at least one trivalent rare earth metal or divalent alkaline earth metal. Preferably, aluminum is further supported on the ZrO2 composite oxide. The NOx absorbent is considered to have an NOx absorption mechanism that an electron released from the alkali metal or the like enters into an oxygen vacancy part of the crystalline ZrO2 and this oxygen vacancy part functions as a strong base site for donating an electron to an electrophilic component such as NOx.
摘要翻译:提供即使在超过500℃的高废气温度下也能够发挥出优异的NO x X净化能力的废气净化催化剂。 催化剂是通过将至少一种碱金属或碱土金属负载在结晶ZrO 2上而获得的吸收还原型NO x x N 2净化催化剂,其包含NO x 2N复合氧化物中加入至少一种三价稀土金属或二价碱土金属。 优选地,铝进一步负载在ZrO 2复合氧化物上。 认为NO x吸收剂具有从碱金属等释放的电子进入结晶ZrO 2 <! - SIPO - >这个氧空位部分用作向诸如NO x的亲电组分提供电子的强碱基位点。
摘要:
An automotive exhaust catalyst includes an alumina support having pores, an NO.sub.x, storage member loaded in the pores having a pore diameter of from 10 to 30.ANG. at least, and a noble metal element loaded on the alumina support. The automotive exhaust catalyst can store NO.sub.x, in a large amount in fuel-lean or oxygen-rich atmosphere, and inhibit the alumina support from sintering, because the NO.sub.x storage member is loaded in a highly dispersed manner.
摘要:
An exhaust gas purifying catalyst in which catalytic activation particles 3 composed of a catalytic element or its compound are carried on a carrier 1. The catalytic activation particles 3, as carried on the carrier 1 and exposed to the outside of the carrier 1, are coated with the carrier 1 by 20 to 90% of their whole surface area. Also disclosed is a process for producing the exhaust gas purifying catalyst.
摘要:
A catalyst able to overcome defects of an absorption reduction-type NOx purifying catalyst, such as poor NOx purifying capability at low temperatures and low SOx desorbing property, is provided.The catalyst is an absorption reduction-type NOx purifying catalyst where NOx absorbent particles and support particles having supported thereon a catalyst component are mixed. Preferably, acidic support particles are added to the support particle, the NOx absorbent particles are a metal oxide having a base point, and the metal oxide is rare earth-added zirconia. In conventional catalysts, the NOx absorbent such as alkali metal having strong basicity exposes the catalyst component present together on the same support to the basic condition to decrease the catalytic performance. However, in the present invention, the NOx absorbent and the support are separate particles, whereby the catalyst component can exert its original catalytic performance and, as a result, the NOx purifying capability at low temperatures and the SOx desorbing property are improved.
摘要翻译:能够克服吸收还原型NO x x H净化催化剂的缺陷的催化剂,例如在低温和低SO x x 2+纯化催化剂的低纯度能力下, SUB>解吸属性。 该催化剂是吸收还原型NO x X 2净化催化剂,其中将NO x吸收剂颗粒和负载有催化剂组分的载体颗粒混合。 优选地,将酸性载体颗粒加入到载体颗粒中,NO x吸收颗粒是具有基点的金属氧化物,并且金属氧化物是稀土添加的氧化锆。 在常规催化剂中,具有强碱性的碱金属的NO x吸收剂将催化剂组分一起存在于与碱性条件相同的载体上以降低催化性能。 然而,在本发明中,NO x吸收剂和载体是分离的颗粒,由此催化剂组分可以发挥其最初的催化性能,结果是NO x >低温下的净化能力和SO x x解吸性能得到改善。
摘要:
A device for purifying the exhaust gas of an engine comprises a NO.sub.X absorbent arranged in the exhaust passage. The NO.sub.X absorbent absorbs NO.sub.X therein when the air-fuel ratio of the inflowing exhaust gas is lean, and releases the absorbed NO.sub.X therefrom when the oxygen concentration in the inflowing exhaust gas becomes lower. The NO.sub.X absorbent also absorbs SO.sub.X therein when the air-fuel ratio of the inflowing exhaust gas is lean, and releases the absorbed SO.sub.X therefrom when the oxygen concentration in the inflowing exhaust gas becomes lower, with the temperature of the NO.sub.X absorbent being higher than a SO.sub.X releasing temperature. The air-fuel ratio of the exhaust gas flowing to the NO.sub.X absorbent is made rich temporarily when the temperature of the NO.sub.X absorbent is higher than SO.sub.X releasing temperature and when the flow rate of the exhaust gas flowing through the NO.sub.X absorbent is lower than a predetermined flow rate, to release the absorbed SO.sub.X from the NO.sub.X absorbent.
摘要:
It is suppressed that nanoparticles generated in an internal combustion engine are discharged into the atmosphere. In a cylinder or an exhaust system of the internal combustion engine, microparticles having a particle diameter larger than that of the nanoparticles are generated, and the nanoparticles generated in the internal combustion engine are adsorbed by the microparticles, thereby increasing the diameter of the nanoparticles. The microparticles can be generated in the cylinder as the soot, for example. Additionally, by providing a carbon microparticle generation device in the exhaust system, the microparticles can be generated, too. By making the nanoparticles adsorbed by the microparticles and increasing the diameter of the nanoparticles, discharging of the nanoparticles can be suppressed.
摘要:
A refrigerating apparatus includes a high temperature side first cycle; a high temperature side second cycle; a low temperature side cycle in which carbon dioxide is used as a refrigerant; a first cascade condenser and a second cascade condenser, which each exchange heat between a high temperature side refrigerant and a low temperature side refrigerant; and a control unit lowering an evaporation temperature of a high temperature side evaporator in correspondence to the flow of the low temperature side refrigerant.