公开(公告)号：US09828309B2

公开(公告)日：2017-11-28

申请号：US14119281

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06 ,  C10G35/06 ,  B01D45/12 ,  B01J8/00 ,  C10G35/14 ,  C10G35/04 ,  C10G35/10 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87

CPC分类号： C07C4/06 ,  B01D45/12 ,  B01J8/005 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  C10G35/04 ,  C10G35/065 ,  C10G35/10 ,  C10G35/14 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： Method for producing monocyclic aromatic hydrocarbons includes a cracking and reforming reaction step of obtaining products containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms by bringing the feedstock oil into contact with a catalyst for producing monocyclic aromatic hydrocarbons containing crystalline aluminosilicate to cause a reaction, a catalyst separation step of separating and removing the catalyst for producing monocyclic aromatic hydrocarbons together with tricyclic aromatic hydrocarbons contained in the products from a mixture of the products and a small amount of the catalyst for producing monocyclic aromatic hydrocarbons carried by the products, both of which are derived in the cracking and reforming reaction step, and a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms which are separated from the products formed in the cracking and reforming reaction step.

公开(公告)号：US09382173B2

公开(公告)日：2016-07-05

申请号：US14006974

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C2/42 ,  C07C2/76 ,  C07C5/11 ,  C07C57/00 ,  C07C5/10 ,  C10G69/04 ,  C10G11/05 ,  C10G35/095 ,  C10G61/02 ,  C07C4/06

CPC分类号： C07C5/10 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095 ,  C10G61/02 ,  C10G69/04 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/30 ,  Y02P20/132

摘要： Provided is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, the method including a cracking reforming reaction step of bringing feedstock oil into contact with a catalyst to effect a reaction; a step of purifying and recovering monocyclic aromatic hydrocarbons separated from the reaction step; and (1) a step of hydrogenating a heavy fraction separated from the reaction step; a dilution step of returning a portion of the hydrogenation product as a diluent oil to the hydrogenation step; and a step of returning the hydrogenation product to the reaction step; or (2) a step of adding a diluent to the heavy fraction separated from the reaction step; a step of hydrogenating the mixture; and a step of returning the hydrogenation product to the reaction step.

摘要翻译： 本发明提供一种具有6〜8个碳原子的单环芳烃的方法，该方法包括：使原料油与催化剂接触以进行反应的裂化重整反应步骤; 从反应步骤中分离出的单环芳烃的纯化和回收步骤; 和（1）氢化从反应步骤分离的重馏分的步骤; 将作为稀释油的氢化产物的一部分返回到氢化步骤的稀释步骤; 和将氢化物返回到反应步骤的步骤; 或（2）向从反应步骤分离的重馏分中加入稀释剂的步骤; 使混合物氢化的步骤; 和将氢化产物返回到反应步骤的步骤。

公开(公告)号：US20140200378A1

公开(公告)日：2014-07-17

申请号：US14119281

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06

CPC分类号： C07C4/06 ,  B01D45/12 ,  B01J8/005 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  C10G35/04 ,  C10G35/065 ,  C10G35/10 ,  C10G35/14 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： Method for producing monocyclic aromatic hydrocarbons includes a cracking and reforming reaction step of obtaining products containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms by bringing the feedstock oil into contact with a catalyst for producing monocyclic aromatic hydrocarbons containing crystalline aluminosilicate to cause a reaction, a catalyst separation step of separating and removing the catalyst for producing monocyclic aromatic hydrocarbons together with tricyclic aromatic hydrocarbons contained in the products from a mixture of the products and a small amount of the catalyst for producing monocyclic aromatic hydrocarbons carried by the products, both of which are derived in the cracking and reforming reaction step, and a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms which are separated from the products formed in the cracking and reforming reaction step.

摘要翻译： 制备单环芳烃的方法包括裂解和重整反应步骤，通过使原料油与用于制备单环芳族化合物的催化剂接触，得到含有6至8个碳原子的单环芳烃和具有9个或更多个碳原子的重馏分的产物 含有结晶硅铝酸盐的碳氢化合物引起反应的催化剂分离步骤，用于分离和除去产物中含有的三环芳烃与单一芳族烃的混合物和少量用于制备单环芳族化合物的催化剂 由裂解和重整反应步骤中衍生的产物携带的烃和净化回收步骤，其纯化和回收与裂化中形成的产物分离的具有6至8个碳原子的单环芳烃和 重整反应步骤。

公开(公告)号：US20140066672A1

公开(公告)日：2014-03-06

申请号：US14006974

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C5/10 ,  C07C4/06

CPC分类号： C07C5/10 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095 ,  C10G61/02 ,  C10G69/04 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/30 ,  Y02P20/132

摘要： Provided is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, the method including a cracking reforming reaction step of bringing feedstock oil into contact with a catalyst to effect a reaction; a step of purifying and recovering monocyclic aromatic hydrocarbons separated from the reaction step; and (1) a step of hydrogenating a heavy fraction separated from the reaction step; a dilution step of returning a portion of the hydrogenation product as a diluent oil to the hydrogenation step; and a step of returning the hydrogenation product to the reaction step; or (2) a step of adding a diluent to the heavy fraction separated from the reaction step; a step of hydrogenating the mixture; and a step of returning the hydrogenation product to the reaction step.

摘要翻译： 本发明提供一种具有6〜8个碳原子的单环芳烃的方法，该方法包括：使原料油与催化剂接触进行反应的裂化重整反应步骤; 从反应步骤中分离出的单环芳烃的纯化和回收步骤; 和（1）氢化从反应步骤分离的重馏分的步骤; 将作为稀释油的氢化产物的一部分返回到氢化步骤的稀释步骤; 和将氢化物返回到反应步骤的步骤; 或（2）向从反应步骤分离的重馏分中加入稀释剂的步骤; 使混合物氢化的步骤; 和将氢化产物返回到反应步骤的步骤。

公开(公告)号：US20140018585A1

公开(公告)日：2014-01-16

申请号：US14007166

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06

CPC分类号： C07C4/06 ,  C10G69/04 ,  C10G69/10 ,  C10G2300/4081 ,  C10G2400/30 ,  Y02P20/582

摘要： A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.

摘要翻译： 一种制备单环芳烃的方法包括将原料油引入裂解/重整反应器中，使原料油与催化剂接触并使原料油反应的步骤，纯化和回收单环芳烃 与在反应步骤中产生的产物分离，氢化从产物分离的重馏分的步骤和将重馏分的氢化反应物返回到裂化/重整反应步骤的再循环步骤。 在回收步骤中，将氢化反应物引入到不同于原料油的引入位置到反应器中的位置，使得氢化反应物与反应器中的催化剂接触的时间变得比其中 原料油与反应器中的催化剂接触。

公开(公告)号：US09233892B2

公开(公告)日：2016-01-12

申请号：US14007166

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C2/42 ,  C07C2/76 ,  C07C5/11 ,  C10G57/00 ,  C07C4/06 ,  C10G69/10 ,  C10G69/04

CPC分类号： C07C4/06 ,  C10G69/04 ,  C10G69/10 ,  C10G2300/4081 ,  C10G2400/30 ,  Y02P20/582

摘要： A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.

摘要翻译： 一种制备单环芳烃的方法包括将原料油引入裂解/重整反应器中，使原料油与催化剂接触并使原料油反应的步骤，纯化和回收单环芳烃 与在反应步骤中产生的产物分离，氢化从产物分离的重馏分的步骤和将重馏分的氢化反应物返回到裂化/重整反应步骤的再循环步骤。 在回收步骤中，将氢化反应物引入到不同于原料油的引入位置到反应器中的位置，使得氢化反应物与反应器中的催化剂接触的时间变得比其中 原料油与反应器中的催化剂接触。

公开(公告)号：US20140200377A1

公开(公告)日：2014-07-17

申请号：US14119576

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

IPC分类号： C07C5/02 ,  C07C4/02 ,  C07C7/00

CPC分类号： C07C5/02 ,  B01J23/44 ,  B01J23/755 ,  B01J23/883 ,  B01J23/888 ,  B01J29/405 ,  C07C4/02 ,  C07C6/126 ,  C07C7/00 ,  C10G11/05 ,  C10G11/18 ,  C10G35/04 ,  C10G35/065 ,  C10G35/095 ,  C10G35/10 ,  C10G45/44 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P20/132 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/04

摘要： The present method for producing monocyclic aromatic hydrocarbons is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms. This method includes a cracking and reforming reaction step of bringing oil feedstock into contact with a catalyst to cause a reaction and obtain a product containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms, a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms separated from the product formed by the cracking and reforming reaction step, and a first returning step of returning at least a portion of toluene obtained by the purification and recovery step to the cracking and reforming reaction step.

摘要翻译： 本发明的单环芳烃的制造方法是制造碳原子数为6〜8的单环芳烃的方法。 该方法包括使油原料与催化剂接触以引起反应的裂化和重整反应步骤，并获得含有具有6至8个碳原子的单环芳族烃和具有9个或更多个碳原子的重馏分的产物，纯化和 纯化和回收由裂解和重整反应步骤形成的产物分离出的具有6至8个碳原子的单环芳烃的回收步骤，和将至少一部分通过纯化和回收步骤获得的甲苯返回至 裂化和重整反应步骤。

公开(公告)号：US09487457B2

公开(公告)日：2016-11-08

申请号：US14119576

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

IPC分类号： C07C2/42 ,  C07C2/76 ,  C07C5/11 ,  C07C57/00 ,  C07C5/02 ,  C10G11/05 ,  C07C6/12 ,  C10G11/18 ,  C07C4/02 ,  C07C7/00 ,  C10G35/095 ,  C10G45/44 ,  C10G35/04 ,  C10G35/06 ,  C10G35/10 ,  B01J23/44 ,  B01J23/755 ,  B01J23/883 ,  B01J23/888 ,  B01J29/40

CPC分类号： C07C5/02 ,  B01J23/44 ,  B01J23/755 ,  B01J23/883 ,  B01J23/888 ,  B01J29/405 ,  C07C4/02 ,  C07C6/126 ,  C07C7/00 ,  C10G11/05 ,  C10G11/18 ,  C10G35/04 ,  C10G35/065 ,  C10G35/095 ,  C10G35/10 ,  C10G45/44 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P20/132 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/04

摘要： The present method for producing monocyclic aromatic hydrocarbons is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms. This method includes a cracking and reforming reaction step of bringing oil feedstock into contact with a catalyst to cause a reaction and obtain a product containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms, a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms separated from the product formed by the cracking and reforming reaction step, and a first returning step of returning at least a portion of toluene obtained by the purification and recovery step to the cracking and reforming reaction step.

摘要翻译： 本发明的单环芳烃的制造方法是制造碳原子数为6〜8的单环芳烃的方法。 该方法包括使油原料与催化剂接触以引起反应的裂化和重整反应步骤，并获得含有具有6至8个碳原子的单环芳族烃和具有9个或更多个碳原子的重馏分的产物，纯化和 纯化和回收由裂解和重整反应步骤形成的产物分离出的具有6至8个碳原子的单环芳烃的回收步骤，和将至少一部分通过纯化和回收步骤获得的甲苯返回至 裂化和重整反应步骤。

公开(公告)号：US09255042B2

公开(公告)日：2016-02-09

申请号：US14119571

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C2/42 ,  C10G35/00 ,  C10G15/00 ,  C07C4/06 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  B01D3/00 ,  C10G35/14 ,  C10G35/24 ,  C10G49/26 ,  C10G11/18 ,  B01J29/04 ,  B01J29/08 ,  B01J29/18 ,  B01J29/82 ,  B01J29/86

CPC分类号： C07C4/06 ,  B01D3/009 ,  B01J29/047 ,  B01J29/048 ,  B01J29/08 ,  B01J29/18 ,  B01J29/185 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/82 ,  B01J29/86 ,  B01J29/87 ,  B01J2229/186 ,  C10G11/187 ,  C10G35/14 ,  C10G35/24 ,  C10G49/26 ,  C10G2300/301 ,  C10G2400/30

摘要： A producing method of monocyclic aromatic hydrocarbons from the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140° C. and a 90 volume % distillation temperature of less than or equal to 380° C. by bringing into contact with an aromatic production catalyst includes the steps of: introducing the oil feedstock into a cracking and reforming reaction apparatus housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other at the inside of the cracking and reforming reaction apparatus; heating the oil feedstock in advance before introducing the oil feedstock into the cracking and reforming reaction apparatus and forming a two-phase gas-liquid stream; separating the two-phase gas-liquid stream into a gas fraction and a liquid fraction; and introducing the gas fraction and the liquid fraction at different positions of the cracking and reforming reaction apparatus.

摘要翻译： 来自油原料的单环芳烃的制备方法，其具有大于或等于140℃的10体积％蒸馏温度和小于或等于380℃的90体积％蒸馏温度，通过与 芳族生产催化剂包括以下步骤：将油原料引入到容纳芳族生产催化剂的裂化和重整反应装置中; 使油原料和芳香族生成催化剂在裂化和重整反应装置的内部彼此接触; 在将油原料引入裂解和重整反应装置中并形成两相气 - 液流之前，预先加热油原料; 将两相气 - 液流分离成气体馏分和液体馏分; 并在裂化和重整反应装置的不同位置引入气体馏分和液体馏分。

公开(公告)号：US09388096B2

公开(公告)日：2016-07-12

申请号：US14119609

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo ,  Osamu Hirohata

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo ,  Osamu Hirohata

IPC分类号： C07C4/16 ,  C10G35/02 ,  C10G35/14 ,  C07C4/06 ,  C10G45/68 ,  C10G45/70 ,  C10G11/18

CPC分类号： C07C4/06 ,  C10G11/18 ,  C10G35/14 ,  C10G45/68 ,  C10G45/70 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2400/30

摘要： A producing method of monocyclic aromatic hydrocarbons in which reaction products including monocyclic aromatic hydrocarbons are produced by bringing an oil feedstock and an aromatic production catalyst into contact with each other, the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140° C. and a 90 volume % distillation temperature of less than or equal to 380° C., the method including the steps of: introducing the oil feedstock into a fluidized-bed reaction apparatus housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other in the fluidized-bed reaction apparatus; and introducing steam into the fluidized-bed reaction apparatus based on the introducing amount of the oil feedstock per hour.

摘要翻译： 一种单环芳烃的制备方法，其中通过使油原料和芳族生产催化剂彼此接触来制备包括单环芳烃的反应产物，所述油原料具有大于或等于140的10体积％蒸馏温度 ℃和90体积％的蒸馏温度小于或等于380℃，所述方法包括以下步骤：将油原料引入到容纳芳族生产催化剂的流化床反应装置中; 使油原料和芳香族生产催化剂在流化床反应装置中相互接触; 并且基于每小时的油原料的引入量将蒸汽引入流化床反应装置。