公开(公告)号：US20140018585A1

公开(公告)日：2014-01-16

申请号：US14007166

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06

CPC分类号： C07C4/06 ,  C10G69/04 ,  C10G69/10 ,  C10G2300/4081 ,  C10G2400/30 ,  Y02P20/582

摘要： A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.

摘要翻译： 一种制备单环芳烃的方法包括将原料油引入裂解/重整反应器中，使原料油与催化剂接触并使原料油反应的步骤，纯化和回收单环芳烃 与在反应步骤中产生的产物分离，氢化从产物分离的重馏分的步骤和将重馏分的氢化反应物返回到裂化/重整反应步骤的再循环步骤。 在回收步骤中，将氢化反应物引入到不同于原料油的引入位置到反应器中的位置，使得氢化反应物与反应器中的催化剂接触的时间变得比其中 原料油与反应器中的催化剂接触。

公开(公告)号：US09233892B2

公开(公告)日：2016-01-12

申请号：US14007166

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Ryoji Ida ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C2/42 ,  C07C2/76 ,  C07C5/11 ,  C10G57/00 ,  C07C4/06 ,  C10G69/10 ,  C10G69/04

CPC分类号： C07C4/06 ,  C10G69/04 ,  C10G69/10 ,  C10G2300/4081 ,  C10G2400/30 ,  Y02P20/582

摘要： A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.

摘要翻译： 一种制备单环芳烃的方法包括将原料油引入裂解/重整反应器中，使原料油与催化剂接触并使原料油反应的步骤，纯化和回收单环芳烃 与在反应步骤中产生的产物分离，氢化从产物分离的重馏分的步骤和将重馏分的氢化反应物返回到裂化/重整反应步骤的再循环步骤。 在回收步骤中，将氢化反应物引入到不同于原料油的引入位置到反应器中的位置，使得氢化反应物与反应器中的催化剂接触的时间变得比其中 原料油与反应器中的催化剂接触。

公开(公告)号：US09828309B2

公开(公告)日：2017-11-28

申请号：US14119281

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06 ,  C10G35/06 ,  B01D45/12 ,  B01J8/00 ,  C10G35/14 ,  C10G35/04 ,  C10G35/10 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87

CPC分类号： C07C4/06 ,  B01D45/12 ,  B01J8/005 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  C10G35/04 ,  C10G35/065 ,  C10G35/10 ,  C10G35/14 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： Method for producing monocyclic aromatic hydrocarbons includes a cracking and reforming reaction step of obtaining products containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms by bringing the feedstock oil into contact with a catalyst for producing monocyclic aromatic hydrocarbons containing crystalline aluminosilicate to cause a reaction, a catalyst separation step of separating and removing the catalyst for producing monocyclic aromatic hydrocarbons together with tricyclic aromatic hydrocarbons contained in the products from a mixture of the products and a small amount of the catalyst for producing monocyclic aromatic hydrocarbons carried by the products, both of which are derived in the cracking and reforming reaction step, and a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms which are separated from the products formed in the cracking and reforming reaction step.

公开(公告)号：US09382173B2

公开(公告)日：2016-07-05

申请号：US14006974

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C2/42 ,  C07C2/76 ,  C07C5/11 ,  C07C57/00 ,  C07C5/10 ,  C10G69/04 ,  C10G11/05 ,  C10G35/095 ,  C10G61/02 ,  C07C4/06

CPC分类号： C07C5/10 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095 ,  C10G61/02 ,  C10G69/04 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/30 ,  Y02P20/132

摘要： Provided is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, the method including a cracking reforming reaction step of bringing feedstock oil into contact with a catalyst to effect a reaction; a step of purifying and recovering monocyclic aromatic hydrocarbons separated from the reaction step; and (1) a step of hydrogenating a heavy fraction separated from the reaction step; a dilution step of returning a portion of the hydrogenation product as a diluent oil to the hydrogenation step; and a step of returning the hydrogenation product to the reaction step; or (2) a step of adding a diluent to the heavy fraction separated from the reaction step; a step of hydrogenating the mixture; and a step of returning the hydrogenation product to the reaction step.

摘要翻译： 本发明提供一种具有6〜8个碳原子的单环芳烃的方法，该方法包括：使原料油与催化剂接触以进行反应的裂化重整反应步骤; 从反应步骤中分离出的单环芳烃的纯化和回收步骤; 和（1）氢化从反应步骤分离的重馏分的步骤; 将作为稀释油的氢化产物的一部分返回到氢化步骤的稀释步骤; 和将氢化物返回到反应步骤的步骤; 或（2）向从反应步骤分离的重馏分中加入稀释剂的步骤; 使混合物氢化的步骤; 和将氢化产物返回到反应步骤的步骤。

公开(公告)号：US20140200378A1

公开(公告)日：2014-07-17

申请号：US14119281

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Yuichiro Fujiyama ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C4/06

CPC分类号： C07C4/06 ,  B01D45/12 ,  B01J8/005 ,  B01J29/40 ,  B01J29/70 ,  B01J29/87 ,  C10G35/04 ,  C10G35/065 ,  C10G35/10 ,  C10G35/14 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： Method for producing monocyclic aromatic hydrocarbons includes a cracking and reforming reaction step of obtaining products containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms by bringing the feedstock oil into contact with a catalyst for producing monocyclic aromatic hydrocarbons containing crystalline aluminosilicate to cause a reaction, a catalyst separation step of separating and removing the catalyst for producing monocyclic aromatic hydrocarbons together with tricyclic aromatic hydrocarbons contained in the products from a mixture of the products and a small amount of the catalyst for producing monocyclic aromatic hydrocarbons carried by the products, both of which are derived in the cracking and reforming reaction step, and a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms which are separated from the products formed in the cracking and reforming reaction step.

摘要翻译： 制备单环芳烃的方法包括裂解和重整反应步骤，通过使原料油与用于制备单环芳族化合物的催化剂接触，得到含有6至8个碳原子的单环芳烃和具有9个或更多个碳原子的重馏分的产物 含有结晶硅铝酸盐的碳氢化合物引起反应的催化剂分离步骤，用于分离和除去产物中含有的三环芳烃与单一芳族烃的混合物和少量用于制备单环芳族化合物的催化剂 由裂解和重整反应步骤中衍生的产物携带的烃和净化回收步骤，其纯化和回收与裂化中形成的产物分离的具有6至8个碳原子的单环芳烃和 重整反应步骤。

公开(公告)号：US20140066672A1

公开(公告)日：2014-03-06

申请号：US14006974

申请日：2012-03-23

申请人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

发明人： Shinichiro Yanagawa ,  Ryoji Ida ,  Yasuyuki Iwasa ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC分类号： C07C5/10 ,  C07C4/06

CPC分类号： C07C5/10 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095 ,  C10G61/02 ,  C10G69/04 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/30 ,  Y02P20/132

摘要： Provided is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, the method including a cracking reforming reaction step of bringing feedstock oil into contact with a catalyst to effect a reaction; a step of purifying and recovering monocyclic aromatic hydrocarbons separated from the reaction step; and (1) a step of hydrogenating a heavy fraction separated from the reaction step; a dilution step of returning a portion of the hydrogenation product as a diluent oil to the hydrogenation step; and a step of returning the hydrogenation product to the reaction step; or (2) a step of adding a diluent to the heavy fraction separated from the reaction step; a step of hydrogenating the mixture; and a step of returning the hydrogenation product to the reaction step.

摘要翻译： 本发明提供一种具有6〜8个碳原子的单环芳烃的方法，该方法包括：使原料油与催化剂接触进行反应的裂化重整反应步骤; 从反应步骤中分离出的单环芳烃的纯化和回收步骤; 和（1）氢化从反应步骤分离的重馏分的步骤; 将作为稀释油的氢化产物的一部分返回到氢化步骤的稀释步骤; 和将氢化物返回到反应步骤的步骤; 或（2）向从反应步骤分离的重馏分中加入稀释剂的步骤; 使混合物氢化的步骤; 和将氢化产物返回到反应步骤的步骤。

公开(公告)号：US09487457B2

公开(公告)日：2016-11-08

申请号：US14119576

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

IPC分类号： C07C2/42 ,  C07C2/76 ,  C07C5/11 ,  C07C57/00 ,  C07C5/02 ,  C10G11/05 ,  C07C6/12 ,  C10G11/18 ,  C07C4/02 ,  C07C7/00 ,  C10G35/095 ,  C10G45/44 ,  C10G35/04 ,  C10G35/06 ,  C10G35/10 ,  B01J23/44 ,  B01J23/755 ,  B01J23/883 ,  B01J23/888 ,  B01J29/40

CPC分类号： C07C5/02 ,  B01J23/44 ,  B01J23/755 ,  B01J23/883 ,  B01J23/888 ,  B01J29/405 ,  C07C4/02 ,  C07C6/126 ,  C07C7/00 ,  C10G11/05 ,  C10G11/18 ,  C10G35/04 ,  C10G35/065 ,  C10G35/095 ,  C10G35/10 ,  C10G45/44 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P20/132 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/04

摘要： The present method for producing monocyclic aromatic hydrocarbons is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms. This method includes a cracking and reforming reaction step of bringing oil feedstock into contact with a catalyst to cause a reaction and obtain a product containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms, a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms separated from the product formed by the cracking and reforming reaction step, and a first returning step of returning at least a portion of toluene obtained by the purification and recovery step to the cracking and reforming reaction step.

摘要翻译： 本发明的单环芳烃的制造方法是制造碳原子数为6〜8的单环芳烃的方法。 该方法包括使油原料与催化剂接触以引起反应的裂化和重整反应步骤，并获得含有具有6至8个碳原子的单环芳族烃和具有9个或更多个碳原子的重馏分的产物，纯化和 纯化和回收由裂解和重整反应步骤形成的产物分离出的具有6至8个碳原子的单环芳烃的回收步骤，和将至少一部分通过纯化和回收步骤获得的甲苯返回至 裂化和重整反应步骤。

公开(公告)号：US20140200377A1

公开(公告)日：2014-07-17

申请号：US14119576

申请日：2012-05-24

申请人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

发明人： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Ryoji Ida ,  Masahide Kobayashi ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Akira Utatsu

IPC分类号： C07C5/02 ,  C07C4/02 ,  C07C7/00

CPC分类号： C07C5/02 ,  B01J23/44 ,  B01J23/755 ,  B01J23/883 ,  B01J23/888 ,  B01J29/405 ,  C07C4/02 ,  C07C6/126 ,  C07C7/00 ,  C10G11/05 ,  C10G11/18 ,  C10G35/04 ,  C10G35/065 ,  C10G35/095 ,  C10G35/10 ,  C10G45/44 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P20/132 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/04

摘要： The present method for producing monocyclic aromatic hydrocarbons is a method for producing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms. This method includes a cracking and reforming reaction step of bringing oil feedstock into contact with a catalyst to cause a reaction and obtain a product containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms and a heavy fraction having 9 or more carbon atoms, a purification and recovery step of purifying and recovering the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms separated from the product formed by the cracking and reforming reaction step, and a first returning step of returning at least a portion of toluene obtained by the purification and recovery step to the cracking and reforming reaction step.

摘要翻译： 本发明的单环芳烃的制造方法是制造碳原子数为6〜8的单环芳烃的方法。 该方法包括使油原料与催化剂接触以引起反应的裂化和重整反应步骤，并获得含有具有6至8个碳原子的单环芳族烃和具有9个或更多个碳原子的重馏分的产物，纯化和 纯化和回收由裂解和重整反应步骤形成的产物分离出的具有6至8个碳原子的单环芳烃的回收步骤，和将至少一部分通过纯化和回收步骤获得的甲苯返回至 裂化和重整反应步骤。

公开(公告)号：US09815047B2

公开(公告)日：2017-11-14

申请号：US13976655

申请日：2011-12-28

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

IPC分类号： C07C4/06 ,  B01J29/70 ,  C10G11/18 ,  C10G47/16 ,  C10G11/05 ,  B01J29/85 ,  B01J37/00 ,  C01B39/48 ,  C01B39/10

CPC分类号： B01J29/70 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2229/186 ,  C01B39/10 ,  C01B39/48 ,  C07C4/06 ,  C07C2529/06 ,  C07C2529/40 ,  C10G11/05 ,  C10G11/18 ,  C10G47/16 ,  C10G2300/1033 ,  C10G2300/1048 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/301 ,  C10G2400/30

摘要： The catalyst for producing aromatic hydrocarbon is for producing monocyclic aromatic hydrocarbon having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower and contains crystalline aluminosilicate and phosphorus. A molar ratio (P/Al ratio) between phosphorus contained in the crystalline aluminosilicate and aluminum of the crystalline aluminosilicate is from 0.1 to 1.0. The production method of monocyclic aromatic hydrocarbon is a method of bringing oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower into contact with the catalyst for producing monocyclic aromatic hydrocarbon.

公开(公告)号：US20130281756A1

公开(公告)日：2013-10-24

申请号：US13976701

申请日：2011-12-28

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yasuyuki Iwasa ,  Ryoji Ida

IPC分类号： C10G11/05

CPC分类号： C10G11/05 ,  B01J29/40 ,  B01J29/65 ,  B01J29/703 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/80 ,  B01J29/82 ,  B01J29/87 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/04 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/18 ,  C10G45/68 ,  C10G69/04 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2400/30

摘要： In the production method of monocyclic aromatic hydrocarbons, oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower is brought into contact with a catalyst for producing monocyclic aromatic hydrocarbons that includes a mixture containing a first catalyst which contains crystalline aluminosilicate containing gallium and/or zinc and phosphorus and a second catalyst which contains crystalline aluminosilicate containing phosphorus.

摘要翻译： 在单环芳烃的制造方法中，使具有140℃或更高的10体积％蒸馏温度和380℃或更低的90体积％蒸馏温度的油原料与用于制备单环芳族化合物的催化剂接触 包括含有含有含有镓和/或锌和磷的结晶硅铝酸盐的第一催化剂和含有含磷结晶硅铝酸盐的第二催化剂的混合物的烃。