摘要:
Benzylpyridinium or benzylammonium salts of a benzenesulfonate anion are useful as a proton-donating curing catalyst ion a resinous system capable of curing in the presence of such a catalyst. The catalyst is characterized by its heat-latent nature and thus does not impair the storage stability of the resinous system at an ambient temperature.
摘要:
A novel class of polymerizable monomers containing silicons represented by the formula: ##STR1## wherein R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon residue; R.sup.2 represents an alkylene attached to silicon atom and selected from an unsubstituted alkylene, a substituted alkylene, an unsubstituted alkylene containing hetero atoms or a substituted alkylene containing hetero atoms; m and n each represents a positive number which will fulfil the requirement of 2.ltoreq.m+n.ltoreq.4; R.sup.3 is hydrogen or methyl; A is a direct bond, ##STR2## or a substituted or unsubstituted phenylene; B is ##STR3## R.sup.4 and R.sup.5 each represents an alkylene, providing that when A represents ##STR4## m+n is 2. The invention also provides a preparation method thereof.
摘要:
A novel class of silicon-containing vinyl polymers having in its molecule at least one constitutent unit of the formula ##STR1## wherein R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon residue; R.sup.2 is ##STR2## R.sup.3 is hydrogen or methyl group; R.sup.4 is a substituent directly bonded to silicon atom and is selected from a substituted or unsubstituted alkylene, or a substituted or unsubstituted alkylene containing hetero atoms; m and n each is a positive integer, which will fulfill the requirement of 2.ltoreq.m+m.ltoreq.4; A is a direct bond, ##STR3## phenylene or substituted phenylene; B is ##STR4## R.sup.5 and R.sup.6 each represents an alkylene, providing that when A is ##STR5## m+n is 2. The present vinyl polymers are very useful in various technical fields including preparation of lens and other molding products, paints and various industrial resins.
摘要翻译:一类新颖的含硅乙烯基聚合物,其分子中具有至少一个下式的组成单元,其中R1是取代或未取代的一价烃残基; R2是氢或甲基; R4是与硅原子直接键合的取代基,其选自取代或未取代的亚烷基,或取代或未取代的含有杂原子的亚烷基; m和n分别为正整数,满足2 m + m <= 4的要求; A是直接键合,亚苯基或取代亚苯基; B是图像,R 5和R 6各自表示亚烷基,条件是当A为m + n为2.本发明的乙烯基聚合物在各种技术领域中非常有用,包括制备透镜和其它成型产品,油漆和各种 工业树脂。
摘要:
The present invention provides a process for producing a variety of unsaturated carbamic acid derivatives from corresponding unsaturated carbamates by substitution reaction. The present invention provides a process for producing unsaturated carbamic acid derivatives, comprising reacting an unsaturated carbamate represented by ##STR1## wherein R represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R.sup.1 represents a residue of an alcohol from which an OH group is removed,with an alcohol, a primary or secondary amine or an oxime at a temperature of 80.degree. to 150.degree. C. to substitute the --OR.sup.1 group in the formula (A).
摘要:
Disclosed is a low-temperature curable composition comprising:(a) an acrylic polymer having a molecular weight of 2,000 to 10,000, which has an acyl carbamate group, and(b) a lactone-modified polyol having a molecular weight of 200 to 20,000 in such an amount that a molar ratio of the acyl carbamate group to a hydroxyl group becomes 0.5 to 2.0.The low-temperature curable composition is useful for a binder of a paint for use in plastics.
摘要:
A heat sensitive color developing material containing an electron donating color forming organic compound, a heat activating compound, and a color developer. This material exhibits excellent heat sensitivity and enables rapid color development at low cost.
摘要:
Quaternary ammonium salts of a non-nucleophilic anion having an .alpha.-substituted benzyl group attached to the quatenary nitrogen atom or having a heterocycle including the quaternary nitrogen atom are useful as a cation polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.
摘要:
Quaternary ammonium salts having a 2, 3, 5, 6-tetrahydroxazolo [2, 3-b] oxazole nucleus, such as 4-aralkyl or alkyl-2, 3, 5, 6-tetrahydroxazolo [2, 3-b] oxazolium salts are disclosed. These quarternary ammonium salts are useful a cationic polymerization initiator or proton-donating catalyst of the heat latent type to be incorporated heat-curable coating and other resinous compositions.
摘要:
The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.
摘要:
Disclosed is a novel heterocyclic compound selected from the group consisting of the compounds [IV] to [VII], [IX] and [X]. The heterocyclic compound is useful for reactive materials in chemical industry. A process for producing the heterocyclic compound is also disclosed.