公开(公告)号：US5104718A

公开(公告)日：1992-04-14

申请号：US481220

申请日：1990-02-20

申请人： Shiro Asada ,  Ikuo Takiguchi ,  Akira Agata ,  Toshihiro Hattori

发明人： Shiro Asada ,  Ikuo Takiguchi ,  Akira Agata ,  Toshihiro Hattori

IPC分类号： B29B11/14 ,  B29B11/16 ,  B29C37/00 ,  B29C43/22 ,  B29C59/04 ,  B29C70/50 ,  B29C70/54 ,  B29K105/10 ,  C08J5/24

CPC分类号： B29C37/0064 ,  B29C43/222 ,  B29C59/04 ,  B29C70/504 ,  B29C70/547 ,  B29K2105/101 ,  Y10T156/1002 ,  Y10T156/1023 ,  Y10T428/24124 ,  Y10T428/2457 ,  Y10T428/2495 ,  Y10T428/2918 ,  Y10T428/292 ,  Y10T428/30

摘要： A novel unidirectionally paralleled fiber reinforced thermosetting resin prepreg excellent in moldability which has plural grooves arranged continuously in longitudinal direction on at least one side surface thereof.

摘要翻译： 一种成型性优异的新颖的单向平行纤维增强热固性树脂预浸料，其具有在其至少一个侧表面上沿纵向连续布置的多个凹槽。

公开(公告)号：US06670006B1

公开(公告)日：2003-12-30

申请号：US09381628

申请日：1999-09-27

申请人： Masahiro Sugimori ,  Kazuya Gotou ,  Akira Agata ,  Yukio Nishimoto ,  Masato Taguchi

发明人： Masahiro Sugimori ,  Kazuya Gotou ,  Akira Agata ,  Yukio Nishimoto ,  Masato Taguchi

IPC分类号： C08G1858

CPC分类号： C08G59/38 ,  C08G59/226 ,  C08G59/26 ,  Y10T428/139 ,  Y10T428/292 ,  Y10T428/31511

摘要： The present invention relates to an epoxy resin composition for FRP that will be used for fishing rods, golf club shafts, and the like, a prepreg that is an intermediate material made up of an epoxy resin composition combined with reinforcing fibers, and a tubular molded article obtained using it. The epoxy resin composition for FRP of the present invention comprises (A) a bisphenol A-type epoxy resin, (B) an epoxy resin having oxazolidone rings, and (C) a curing agent. By using the epoxy resin composition for FRP of the present invention, a prepreg quite excellent in handleability and a tubular molded article improved in flexural strength in the longitudinal direction and crushing strength in the diametrical direction can be obtained.

摘要翻译： 本发明涉及用于钓鱼竿，高尔夫球杆杆等的FRP用环氧树脂组合物，作为由与增强纤维组合的环氧树脂组合物构成的中间材料的预浸料，以及管状成型体 使用它获得的文章。 本发明的FRP用环氧树脂组合物包含（A）双酚A型环氧树脂，（B）具有恶唑烷酮环的环氧树脂和（C）固化剂。 通过使用本发明的FRP用环氧树脂组合物，可以获得具有良好的可操作性的预浸料和提高长度方向的弯曲强度以及直径方向的抗碎强度的管状成型体。

公开(公告)号：US4767805A

公开(公告)日：1988-08-30

申请号：US012236

申请日：1987-02-09

申请人： Hisashi Tada ,  Akira Agata ,  Yasuaki Ii

发明人： Hisashi Tada ,  Akira Agata ,  Yasuaki Ii

IPC分类号： C07D303/24 ,  C07D303/36 ,  C08G59/14 ,  C08G59/22 ,  C08G59/38 ,  C08G59/62 ,  C08G59/64 ,  C08J5/24 ,  C08K3/04

CPC分类号： C08J5/24 ,  C07D303/24 ,  C07D303/36 ,  C08G59/1433 ,  C08G59/226 ,  C08G59/38 ,  C08G59/62 ,  C08G59/64 ,  C08J2363/00

摘要： An intermediate for a composite material is disclosed. The intermediate is obtained by impregnating an epoxy resin composition containing a specific additive into a carbon fiber. The composite material obtained from the intermediate has improved mechanical properties.

摘要翻译： 公开了一种复合材料的中间体。 通过将含有特定添加剂的环氧树脂组合物浸渍到碳纤维中而获得中间体。 从中间体获得的复合材料具有改善的机械性能。

公开(公告)号：US08404616B2

公开(公告)日：2013-03-26

申请号：US10593249

申请日：2005-03-11

申请人： Tetsuo Yazawa ,  Kaori Oki ,  Akira Agata

发明人： Tetsuo Yazawa ,  Kaori Oki ,  Akira Agata

IPC分类号： B01J21/06 ,  B01D53/56 ,  C01B33/113

CPC分类号： B01J21/08 ,  B01D53/8628 ,  B01D53/8668 ,  B01D2255/30 ,  B01D2255/802 ,  B01J35/004 ,  Y02W10/37

摘要： A photocatalyst produced from an easily available, relatively low-cost silicon oxide material is disclosed which is capable of decomposing environmental pollutants with improved efficiency. The photocatalyst is produced by pulverizing an artificial crystal, specifically machining waste thereof, into powder particles having a particle diameter of not more than 3.0 mm and then immersing the particles into a solution containing a hydrogen fluoride for activation. Environmental pollutants such as nitrogen oxides (NOx) and harmful organic compounds can be efficiently decomposed by coming into contact with this photocatalyst while being irradiated with activation light under oxidizing conditions.

摘要翻译： 公开了一种由易于获得的相对低成本的氧化硅材料制成的光催化剂，其能够以改进的效率分解环境污染物。 通过将人造晶体粉碎，特别是将其废弃物粉碎成粒径不大于3.0mm的粉末颗粒，然后将颗粒浸入含有氟化氢的溶液进行活化来制备光催化剂。 环境污染物如氮氧化物（NOx）和有害有机化合物可通过与氧化条件下的活化光照射而与该光催化剂接触而有效分解。

公开(公告)号：US4959438A

公开(公告)日：1990-09-25

申请号：US302199

申请日：1989-01-27

申请人： Hisashi Tada ,  Akira Agata ,  Masahiro Saruta ,  Takashi Murata

发明人： Hisashi Tada ,  Akira Agata ,  Masahiro Saruta ,  Takashi Murata

IPC分类号： C08G59/40 ,  C08G59/28 ,  C08G59/38 ,  C08G59/56 ,  C08G59/62 ,  C08J5/24

CPC分类号： C08G59/56 ,  C08G59/38 ,  C08G59/621 ,  Y10T428/31511

摘要： An epoxy resin composition is disclosed, which comprises the following elements:(A) a bifunctional epoxy resin;(B) a trifunctional epoxy resin;(C) a phenolic compound represented by the following general formula: ##STR1## wherein X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5, X.sub.6, X.sub.7, X.sub.8, X.sub.9, X.sub.10, X.sub.11, X.sub.12, R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a methyl group; and(D) 4,4'-diaminodiphenyl sulfone or 3,3'-diaminodiphenyl sulfone, wherein the molar ratio of epoxy groups in element (A) to those in element (B) is in the range of from 1/4.0 to 1/0.1, element (C) is used in an amount that satisfies the condition:1/0.9.ltoreq.(A+B)/C.ltoreq.1/0.1and element (D) is used in an amount that satisfies the condition:1/1.3.ltoreq.(A+B-C)/D.ltoreq.1/0.8wherein A represents the number of epoxy groups by moles in element (A), B represents the number of epoxy groups by moles in element (B), C represents the number of phenolic hydroxyl groups by moles in element (C), and D represents the number of NH groups by moles in element (D).A prepreg for composite materials is also disclosed, wherein the prepreg comprises reinforcing fibers impregnated with the epoxy resin composition described above.

公开(公告)号：US20070042902A1

公开(公告)日：2007-02-22

申请号：US10593249

申请日：2005-03-11

申请人： Tetsuo Yazawa ,  Kaori Oki ,  Akira Agata

发明人： Tetsuo Yazawa ,  Kaori Oki ,  Akira Agata

IPC分类号： B01J23/00

CPC分类号： B01J21/08 ,  B01D53/8628 ,  B01D53/8668 ,  B01D2255/30 ,  B01D2255/802 ,  B01J35/004 ,  Y02W10/37

摘要： A photocatalyst produced from an easily available, relatively low-cost silicon oxide material is disclosed which is capable of decomposing environmental pollutants with improved efficiency. The photocatalyst is produced by pulverizing an artificial crystal, specifically machining waste thereof, into powder particles having a particle diameter of not more than 3.0 mm and then immersing the particles into a solution containing a hydrogen fluoride for activation. Environmental pollutants such as nitrogen oxides (NOx) and harmful organic compounds can be efficiently decomposed by coming into contact with this photocatalyst while being irradiated with activation light under oxidizing conditions.

摘要翻译： 公开了一种由易于获得的相对低成本的氧化硅材料制成的光催化剂，其能够以改进的效率分解环境污染物。 通过将人造晶体粉碎，特别是将其废弃物粉碎成粒径不大于3.0mm的粉末颗粒，然后将颗粒浸入含有氟化氢的溶液进行活化来制备光催化剂。 环境污染物如氮氧化物（NOx）和有害有机化合物可通过与氧化条件下的活化光照射而与该光催化剂接触而有效分解。

公开(公告)号：USRE33965E

公开(公告)日：1992-06-16

申请号：US369496

申请日：1989-06-21

申请人： Hisashi Tada ,  Akira Agata ,  Yasuaki Ii

发明人： Hisashi Tada ,  Akira Agata ,  Yasuaki Ii

IPC分类号： C08G59/64 ,  C08J5/24

CPC分类号： C08J5/24 ,  C08G59/64 ,  C08J2363/00

摘要： An intermediate for a composite material is disclosed. The intermediate is obtained by impregnating an epoxy resin composition containing a specific additive into a carbon fiber. The composite material obtained from the intermediate has improved mechanical properties.

公开(公告)号：US5053475A

公开(公告)日：1991-10-01

申请号：US499343

申请日：1990-06-22

申请人： Hisashi Tada ,  Akira Agata ,  Masahiro Saruta ,  Takashi Murata ,  Takatoshi Kubo

发明人： Hisashi Tada ,  Akira Agata ,  Masahiro Saruta ,  Takashi Murata ,  Takatoshi Kubo

IPC分类号： C08G59/38 ,  C08G59/56 ,  C08G59/62

CPC分类号： C08G59/621 ,  C08G59/38 ,  C08G59/56

摘要： An epoxy resin composition characterized by comprising, as essential components,(A) a bifunctional epoxy resin,(B) a trifunctional epoxy resin,(C) a phenol compound represented by the following formula ##STR1## (X.sub.1 to X.sub.8 each represent Br, Cl or H and at least four of X.sub.1 to X.sub.8 each represent Br or Cl; R.sub.1 and R.sub.2 each represent H or CH.sub.3), and(D) 4,4'-diaminodiphenyl sulfone or 3,3'-diaminodiphenyl sulfone.

公开(公告)号：US5003013A

公开(公告)日：1991-03-26

申请号：US320803

申请日：1989-03-09

申请人： Hisashi Tada ,  Takayuki Iseki ,  Akira Agata

发明人： Hisashi Tada ,  Takayuki Iseki ,  Akira Agata

IPC分类号： C08G59/40 ,  C08G73/12 ,  C08L63/00 ,  C08L79/08

CPC分类号： C08L79/085 ,  C08G59/4042 ,  C08G73/12 ,  C08L63/00 ,  Y10S428/902 ,  Y10T442/2246 ,  Y10T442/2615 ,  Y10T442/2721

摘要： An intermediate for a composite material is described, comprising a reinforcing material impregnated with a resin composition which comprises: (A) 100 parts by weight of a mixture of (I) a polyfunctional maleimide and (II) a polyfunctional cyanate or an oligomer thereof, or a preliminary reaction product of (I) and (II); (B) from 5 to 100 parts by weight of an epoxy compound; and (C) from 5 to 50 parts by weight of a polyester compound.

摘要翻译： 描述了复合材料的中间体，其包含浸渍有树脂组合物的增强材料，其包含：（A）100重量份的（I）多官能马来酰亚胺和（II）多官能氰酸酯或其低聚物的混合物， 或（I）和（II）的预反应产物; （B）5〜100重量份的环氧化合物; 和（C）5〜50重量份的聚酯化合物。

公开(公告)号：US4832932A

公开(公告)日：1989-05-23

申请号：US93567

申请日：1987-08-07

申请人： Hisashi Tada ,  Masahiro Saruta ,  Takashi Murata ,  Akira Agata ,  Setuo Kashiyama

发明人： Hisashi Tada ,  Masahiro Saruta ,  Takashi Murata ,  Akira Agata ,  Setuo Kashiyama

IPC分类号： C08K7/06 ,  D01F11/12 ,  D06M10/00 ,  D06M15/55

CPC分类号： D01F11/122 ,  C08K7/06

摘要： Oxidizing treatment of carbon fibers under specific conditions provides carbon fibers having oxygen concentration (O.sub.1S /C.sub.1S atom number ratio) in the surface part of the carbon fibers of 0.05 to 0.30 as measured by X-ray photoelectron spectroscopy, coefficients of water-extractable fraction of up to 2.0, and coefficients of tow spread of at least 1.times.10.sup.-3. These carbon fibers are excellent in adhesion to various matrix resins and when mixed as reinforcements with matrix resins, provide composite materials superior especially in impact resistance. The thus obtained composite materials are useful for aircraft, automobiles, and general industrial materials.