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公开(公告)号:US20220089885A1
公开(公告)日:2022-03-24
申请号:US17417905
申请日:2019-11-28
申请人: SHOEI CHEMICAL INC.
发明人: Kousuke Nishimura , Naoto Shindo , Hiroshi Mashima
摘要: The present invention provides a silver paste, containing at least a silver powder, a binder resin, and an organic solvent, in which a content of the silver powder based on the silver paste is 80.00 to 97.00% by mass, D10 is 1.00 to 3.00 μm and D50 is 3.00 to 7.00 μm, where D10 and D50 respectively represent a 10% value and a 50% value of a volume-based cumulative fraction obtained by laser diffraction particle size distribution measurement of the silver powder, the silver powder has a specific surface area of 0.10 to 0.30 m2/g, the silver powder has a copper content of 10 to 5000 ppm by mass, a content of the binder resin based on the silver powder is 0.430 to 0.750% by mass, and the silver paste has a dry film density of 7.50 g/cm3 or more.
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公开(公告)号:US20210323859A1
公开(公告)日:2021-10-21
申请号:US16322891
申请日:2017-07-18
申请人: SHOEI CHEMICAL INC.
发明人: Hayato Tateno , Junichi Ikuno , Hiroshi Mashima
摘要: A conductive paste comprising a conductive powder, a glass frit substantially free of lead, and an organic vehicle, wherein the glass frit contains 25 to 50 mol % B in terms of B2O3, 25 to 50 mol % Si in terms of SiO2, 7 to 23 mol % Al in terms of Al2O3, 2 to 15 mol % Mg in terms of MgO, 2 to 5 mol % Ba in terms of BaO, one or two selected from the group consisting of 3 to 18 mol % Zn in terms of ZnO, and 3 to 8 mol % Ti in terms of TiO2, based on the total number of moles in terms of the above oxides. According to the present invention, it is possible to provide a lead-free conductive paste having excellent resistance to dissolution in solder and acid resistance as well as being capable of forming fired films having excellent adherence and adhesion to a substrate.
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公开(公告)号:US09892828B2
公开(公告)日:2018-02-13
申请号:US15119653
申请日:2015-08-20
申请人: Shoei Chemical Inc.
发明人: Hiroshi Mashima , Yukari Morofuji
IPC分类号: H01B1/14 , H01C7/00 , H01B1/08 , H01B1/20 , C03C3/089 , C03C4/14 , C03C8/02 , C03C8/18 , C09D11/03 , C09D11/52 , H01C7/02 , H01C17/065 , C03C3/068 , C03C3/072 , C03C3/074 , C03C3/085 , C03C3/087 , C03C3/091 , C03C3/093 , C03C3/105 , C03C3/108 , C03C8/04 , C03C8/10 , C03C8/22
CPC分类号: H01C7/003 , C03C3/068 , C03C3/072 , C03C3/074 , C03C3/085 , C03C3/087 , C03C3/089 , C03C3/091 , C03C3/093 , C03C3/105 , C03C3/108 , C03C4/14 , C03C8/02 , C03C8/04 , C03C8/10 , C03C8/18 , C03C8/22 , C03C2204/00 , C03C2205/00 , C09D11/03 , C09D11/037 , C09D11/52 , H01B1/08 , H01B1/14 , H01B1/20 , H01C7/00 , H01C7/023 , H01C17/06533
摘要: A thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The thick film resistor is formed of a fired product of a resistive composition, wherein the thick film resistor contains ruthenium-based conductive particles containing ruthenium dioxide and a glass component essentially free of a lead component and has a resistance value in the range of 100Ω/□ to 10 MΩ/□ and a temperature coefficient of resistance within ±100 ppm/° C.
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公开(公告)号:US11535767B2
公开(公告)日:2022-12-27
申请号:US17417895
申请日:2019-11-28
申请人: SHOEI CHEMICAL INC.
发明人: Kousuke Nishimura , Naoto Shindo , Hiroshi Mashima , Yuji Akimoto
IPC分类号: C09D11/52 , B22F1/107 , C09D11/033 , C09D11/037 , C09D11/14 , H01B1/22
摘要: The present invention provides a silver paste containing at least a silver powder, a binder resin, and an organic solvent, wherein the silver powder contains a first silver powder having a D50 of 3.50 to 7.50 μm and a second silver powder having a D50 of 0.80 to 2.00 μm, where D50 represents a 50% value of a volume-based cumulative fraction obtained by laser diffraction particle size distribution measurement; a copper content of the whole silver powder is 10 to 5000 ppm by mass; a copper content of the second silver powder is 80 ppm by mass or more; and the first silver powder contains substantially no copper. The present invention provides a silver paste containing a powder in a high concentration and excellent in printability, and provides a silver conductor film that has a high filling factor, a high film density, high electrical conductivity, and excellent migration resistance.
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公开(公告)号:US20220072607A1
公开(公告)日:2022-03-10
申请号:US17417885
申请日:2019-11-28
申请人: SHOEI CHEMICAL INC.
发明人: Kousuke Nishimura , Naoto Shindo , Hiroshi Mashima
摘要: The present invention provides a silver paste containing at least a silver powder, a binder resin, and an organic solvent, in which a value CBND/SBET is 2.0 to 3.4 where SBET (m2/g) represents a specific surface area of the silver powder, and CBND (% by mass) represents a content percentage of the binder resin based on the silver powder, a copper content of the silver powder is 10 to 5000 ppm by mass, and the silver paste has a dry film density of 7.50 g/cm3 or more. The present invention can provide a silver paste containing a powder in a high concentration and excellent in printability, and accordingly provide a silver conductor film that has a high filling factor and a high film density, exhibits high electrical conductivity, and is excellent in migration resistance.
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公开(公告)号:US10446290B2
公开(公告)日:2019-10-15
申请号:US15718802
申请日:2017-09-28
申请人: Shoei Chemical Inc.
发明人: Hiroshi Mashima , Yukari Morofuji
IPC分类号: H01B1/20 , C03C8/02 , C03C8/04 , C03C8/10 , C03C8/16 , C09D5/24 , H01C7/00 , C03C3/066 , C03C3/074 , C03C3/087 , C03C3/089 , C03C3/091 , C03C14/00
摘要: A resistive composition that can form a thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The resistive composition of the present invention includes: ruthenium-based conductive particles including ruthenium dioxide; a glass frit that is essentially free of a lead component; and an organic vehicle, wherein the glass frit is a glass frit which is constituted such that in a case where a fired product of a mixture of the glass frit and the ruthenium dioxide has in a range of 1 kΩ/□ to 1 MΩ/□, the fired product exhibits a temperature coefficient of resistance in a plus range.
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公开(公告)号:US09805839B2
公开(公告)日:2017-10-31
申请号:US15119637
申请日:2015-08-20
申请人: Shoei Chemical Inc.
发明人: Hiroshi Mashima , Yukari Morofuji
IPC分类号: H01B1/20 , C03C8/02 , C03C8/04 , C03C8/10 , C03C8/16 , C09D5/24 , H01C7/00 , C03C3/066 , C03C3/074 , C03C3/087 , C03C3/089 , C03C3/091 , C03C14/00
CPC分类号: H01B1/20 , C03C3/066 , C03C3/074 , C03C3/087 , C03C3/089 , C03C3/091 , C03C8/02 , C03C8/04 , C03C8/10 , C03C8/16 , C03C14/004 , C03C14/006 , C03C2214/04 , C03C2214/16 , C03C2214/30 , C09D5/24 , H01C7/003
摘要: An object of the present invention is to provide a resistive composition that can form a thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The resistive composition of the present invention includes: ruthenium-based conductive particles including ruthenium dioxide; a glass frit that is essentially free of a lead component; and an organic vehicle, wherein the glass frit is a glass frit which is constituted such that in a case where a fired product of a mixture of the glass frit and the ruthenium dioxide has in a range of 1 kΩ/□ to 1 MΩ/□, the fired product exhibits a temperature coefficient of resistance in a plus range.
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公开(公告)号:US12100530B2
公开(公告)日:2024-09-24
申请号:US17417905
申请日:2019-11-28
申请人: SHOEI CHEMICAL INC.
发明人: Kousuke Nishimura , Naoto Shindo , Hiroshi Mashima
IPC分类号: H01B1/22 , B22F1/00 , B22F1/06 , B22F1/10 , B22F1/102 , B22F1/103 , C09D5/24 , C09D7/40 , C09D7/61 , C09D101/02 , B22F1/052 , B22F1/065
CPC分类号: H01B1/22 , B22F1/00 , B22F1/06 , B22F1/10 , B22F1/102 , B22F1/103 , C09D5/24 , C09D7/61 , C09D7/69 , C09D7/70 , C09D101/02 , B22F1/052 , B22F1/065 , B22F2301/255 , B22F2304/10
摘要: The present invention provides a silver paste, containing at least a silver powder, a binder resin, and an organic solvent, in which a content of the silver powder based on the silver paste is 80.00 to 97.00% by mass, D10 is 1.00 to 3.00 μm and D50 is 3.00 to 7.00 μm, where D10 and D50 respectively represent a 10% value and a 50% value of a volume-based cumulative fraction obtained by laser diffraction particle size distribution measurement of the silver powder, the silver powder has a specific surface area of 0.10 to 0.30 m2/g, the silver powder has a copper content of 10 to 5000 ppm by mass, a content of the binder resin based on the silver powder is 0.430 to 0.750% by mass, and the silver paste has a dry film density of 7.50 g/cm3 or more.
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公开(公告)号:US11183315B2
公开(公告)日:2021-11-23
申请号:US16322891
申请日:2017-07-18
申请人: SHOEI CHEMICAL INC.
发明人: Hayato Tateno , Junichi Ikuno , Hiroshi Mashima
摘要: A conductive paste comprising a conductive powder, a glass frit substantially free of lead, and an organic vehicle, wherein the glass frit contains 25 to 50 mol % B in terms of B2O3, 25 to 50 mol % Si in terms of SiO2, 7 to 23 mol % Al in terms of Al2O3, 2 to 15 mol % Mg in terms of MgO, 2 to 5 mol % Ba in terms of BaO, one or two selected from the group consisting of 3 to 18 mol % Zn in terms of ZnO, and 3 to 8 mol % Ti in terms of TiO2, based on the total number of moles in terms of the above oxides. According to the present invention, it is possible to provide a lead-free conductive paste having excellent resistance to dissolution in solder and acid resistance as well as being capable of forming fired films having excellent adherence and adhesion to a substrate.
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公开(公告)号:US10403421B2
公开(公告)日:2019-09-03
申请号:US15842267
申请日:2017-12-14
申请人: Shoei Chemical Inc.
发明人: Hiroshi Mashima , Yukari Morofuji
IPC分类号: H01B1/08 , H01C7/00 , H01B1/20 , H01B1/14 , C03C3/089 , C03C4/14 , C03C8/02 , C03C8/18 , C09D11/03 , C09D11/52 , H01C17/065 , C03C3/068 , C03C3/072 , C03C3/074 , C03C3/085 , C03C3/087 , C03C3/091 , C03C3/093 , C03C3/105 , C03C3/108 , C03C8/04 , C03C8/10 , C03C8/22 , C09D11/037 , H01C7/06 , H01C7/02
摘要: A thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The thick film resistor is formed of a fired product of a resistive composition, wherein the thick film resistor contains ruthenium-based conductive particles containing ruthenium dioxide and a glass component essentially free of a lead component and has a resistance value in the range of 100 Ω/□ to 10 MΩ/□ and a temperature coefficient of resistance within ±100 ppm/° C.
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