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公开(公告)号：US09168518B2
公开(公告)日：2015-10-27
申请号：US13637404
申请日：2010-04-28
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Hans Karel Theresia Goris , Roger Eijkhoudt , Stephen Harold Brown
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Hans Karel Theresia Goris , Roger Eijkhoudt , Stephen Harold Brown
IPC分类号： B01J38/12 , B01J29/90 , B01J29/70 , B01J29/80 , B01J38/02 , B01J38/26 , B01J38/28 , C07C2/12
CPC分类号： B01J29/90 , B01J29/7026 , B01J29/7042 , B01J29/80 , B01J38/02 , B01J38/12 , B01J38/26 , B01J38/28 , C07C2/12
摘要： Deactivation of a zeolite catalyst during its use to catalyse the oligomerisation of olefins, is often believed to be a result of the formation of high boiling polymers as by-products. These by-products can remain on the catalyst and undergo further conversion to higher molecular weight polymers, which resemble heavy tars and in some cases even have the appearance of coke-like material. These materials can coat the catalyst particles and plug pores in the catalyst, thereby causing catalyst deactivation. The invention relates to an improved method for regenerating such a catalyst.
摘要翻译： 沸石催化剂在其用于催化烯烃低聚的情况下的失活通常被认为是作为副产物形成高沸点聚合物的结果。 这些副产物可以保留在催化剂上并进一步转化成更高分子量的聚合物，其类似于重焦油，并且在一些情况下甚至具有焦炭状材料的外观。 这些材料可以涂覆催化剂颗粒并堵塞催化剂中的孔，从而导致催化剂失活。 本发明涉及一种用于再生这种催化剂的改进方法。
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2.发明授权公开(公告)号：US07989668B2
公开(公告)日：2011-08-02
申请号：US11700979
申请日：2007-02-01
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Hubertus Joseph Beckers , Charles Morris Yarbrough , Stephen Harold Brown , Yeo-Meng Lim
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Hubertus Joseph Beckers , Charles Morris Yarbrough , Stephen Harold Brown , Yeo-Meng Lim
IPC分类号： C07C2/12
CPC分类号： C07C2/12 , C07C7/10 , C07C29/141 , C07C29/16 , C07C45/50 , C07C51/235 , C07C67/08 , C07C2529/70 , C07C2601/14 , C10G21/00 , C10G25/00 , C10G50/00 , C10L1/06 , C12C11/02 , C07C11/02 , C07C31/02 , C07C31/12 , C07C63/15 , C07C69/76 , C07C69/80 , C07C69/82 , C07C69/78 , C07C69/75 , C07C47/02
摘要： Nitrogen-containing Lewis bases act as poisons for molecular sieve catalysts used in oligomerisation reactions. A lowering of their presence in the feed prior to the contacting thereof with the molecular sieve brings a significant extension of catalyst life. Excessive elimination of these poisons may be disadvantageous. Lowering the levels of these catalyst poisons to more manageable concentrations is therefore preferred.
摘要翻译： 含氮路易斯碱作为低聚反应中使用的分子筛催化剂的毒物。 在与分子筛接触之前，它们在进料中的存在降低导致催化剂寿命的显着延长。 过度消除这些毒素可能是不利的。 因此优选将这些催化剂毒物的水平降低到更易于控制的浓度。
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公开(公告)号：US20130204060A1
公开(公告)日：2013-08-08
申请号：US13637404
申请日：2010-04-28
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Hans Karel Theresia Goris , Roger Eijkhoudt , Stephen Harold Brown
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Hans Karel Theresia Goris , Roger Eijkhoudt , Stephen Harold Brown
CPC分类号： B01J29/90 , B01J29/7026 , B01J29/7042 , B01J29/80 , B01J38/02 , B01J38/12 , B01J38/26 , B01J38/28 , C07C2/12
摘要： Deactivation of a zeolite catalyst during its use to catalyse the oligomerisation of olefins, is often believed to be a result of the formation of high boiling polymers as by-products. These by-products can remain on the catalyst and undergo further conversion to higher molecular weight polymers, which resemble heavy tars and in some cases even have the appearance of coke-like material. These materials can coat the catalyst particles and plug pores in the catalyst, thereby causing catalyst deactivation. The invention relates to an improved method for regenerating such a catalyst.
摘要翻译： 沸石催化剂在其用于催化烯烃低聚的情况下的失活通常被认为是作为副产物形成高沸点聚合物的结果。 这些副产物可以保留在催化剂上并进一步转化成更高分子量的聚合物，其类似于重焦油，并且在一些情况下甚至具有焦炭状材料的外观。 这些材料可以涂覆催化剂颗粒并堵塞催化剂中的孔，从而导致催化剂失活。 本发明涉及一种用于再生这种催化剂的改进方法。
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公开(公告)号：US08115042B2
公开(公告)日：2012-02-14
申请号：US12518023
申请日：2009-06-05
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Paul Hamilton , Stephen Harold Brown , Yeo-Meng Lim
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Paul Hamilton , Stephen Harold Brown , Yeo-Meng Lim
CPC分类号： C10G50/00 , C07C2/12 , C10G2300/1088 , C10G2300/1092 , C10G2400/20 , C10G2400/22
摘要： In the oligomerization of olefins in a tubular reactor employing a molecular sieve catalyst, the temperature of the reaction is monitored and the space velocity of the olefin feed to the reactor is reduced as the temperature increases. This has been found to increase catalyst life and lead to extended production runs. Further extensions of the production run are achieved by improving reactor operating stability as the end of the production run approaches.
摘要翻译： 在使用分子筛催化剂的管式反应器中烯烃的低聚反应中，监测反应温度，并且随着温度的升高，进入反应器的烯烃进料的空速降低。 已经发现这可以增加催化剂寿命并导致生产延长。 生产运行的进一步扩展是通过在生产运行结束时改进反应堆运行稳定性来实现的。
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公开(公告)号：US07834229B2
公开(公告)日：2010-11-16
申请号：US11596168
申请日：2005-05-26
CPC分类号： B01J29/7042 , B01J29/06 , B01J29/7026 , B01J29/703 , B01J29/7046 , B01J37/0009 , B01J2229/42 , C07C2/12 , C07C2529/70 , C07C2529/80 , C10G50/00 , C07C11/02
摘要： In a process for oligomerizing an olefinic hydrocarbon feedstock comprising at least 65 wt % olefins and/or sulfur-containing molecules, the feedstock is contacted under oligomerization conditions with (a) a first unidimensional 10-ring molecular sieve catalyst and (b) a second multidimensional crystalline molecular sieve catalyst. The first and second catalysts may be contained in separate reactors or as separate beds in a single reactor.
摘要翻译： 在包含至少65重量％的烯烃和/或含硫分子的烯烃原料低聚的方法中，原料在低聚条件下与（a）第一单维10环分子筛催化剂接触，（b）第二 多维结晶分子筛催化剂。 第一和第二催化剂可以包含在单独的反应器中或作为单个反应器中的分离床。
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公开(公告)号：US20100331591A1
公开(公告)日：2010-12-30
申请号：US12874852
申请日：2010-09-02
IPC分类号： C07C2/12
CPC分类号： B01J29/7042 , B01J29/06 , B01J29/7026 , B01J29/703 , B01J29/7046 , B01J37/0009 , B01J2229/42 , C07C2/12 , C07C2529/70 , C07C2529/80 , C10G50/00 , C07C11/02
摘要： In a process for oligomerizing an olefinic hydrocarbon feedstock comprising at least 65 wt % olefins and/or sulfur-containing molecules, the feedstock is contacted under oligomerization conditions with (a) a first unidimensional 10-ring molecular sieve catalyst and (b) a second multidimensional crystalline molecular sieve catalyst. The first and second catalysts may be contained in separate reactors or as separate beds in a single reactor.
摘要翻译： 在包含至少65重量％的烯烃和/或含硫分子的烯烃原料低聚的方法中，原料在低聚条件下与（a）第一单维10环分子筛催化剂接触，（b）第二 多维结晶分子筛催化剂。 第一和第二催化剂可以包含在单独的反应器中或作为单个反应器中的分离床。
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公开(公告)号：US08716542B2
公开(公告)日：2014-05-06
申请号：US12874852
申请日：2010-09-02
IPC分类号： C07C2/12
CPC分类号： B01J29/7042 , B01J29/06 , B01J29/7026 , B01J29/703 , B01J29/7046 , B01J37/0009 , B01J2229/42 , C07C2/12 , C07C2529/70 , C07C2529/80 , C10G50/00 , C07C11/02
摘要： In a process for oligomerizing an olefinic hydrocarbon feedstock comprising at least 65 wt % olefins and/or sulfur-containing molecules, the feedstock is contacted under oligomerization conditions with (a) a first unidimensional 10-ring molecular sieve catalyst and (b) a second multidimensional crystalline molecular sieve catalyst. The first and second catalysts may be contained in separate reactors or as separate beds in a single reactor.
摘要翻译： 在包含至少65重量％的烯烃和/或含硫分子的烯烃原料低聚的方法中，原料在低聚条件下与（a）第一单维10环分子筛催化剂接触，（b）第二 多维结晶分子筛催化剂。 第一和第二催化剂可以包含在单独的反应器中或作为单个反应器中的分离床。
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公开(公告)号：US20110124827A1
公开(公告)日：2011-05-26
申请号：US12518023
申请日：2009-06-05
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Paul Hamilton , Stephen Harold Brown , Yeo-Meng Lim
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Paul Hamilton , Stephen Harold Brown , Yeo-Meng Lim
IPC分类号： C08F2/01
CPC分类号： C10G50/00 , C07C2/12 , C10G2300/1088 , C10G2300/1092 , C10G2400/20 , C10G2400/22
摘要： In the oligomerisation of olefins in a tubular reactor employing a molecular sieve catalyst, the temperature of the reaction is monitored and the space velocity of the olefin feed to the reactor is reduced as the temperature increases. This has been found to increase catalyst life and lead to extended production runs. Further extensions of the production run are achieved by improving reactor operating stability as the end of the production run approaches.
摘要翻译： 在使用分子筛催化剂的管式反应器中烯烃的低聚反应中，监测反应的温度，并且随着温度的升高，进入反应器的烯烃进料的空速降低。 已经发现这可以增加催化剂寿命并导致生产延长。 生产运行的进一步扩展是通过在生产运行结束时改进反应堆运行稳定性来实现的。
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9.发明申请公开(公告)号：US20070213575A1
公开(公告)日：2007-09-13
申请号：US11700979
申请日：2007-02-01
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Hubertus Joseph Beckers , Charles Morris Yarbrough , Stephen Harold Brown , Yeo-Meng Lim
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Hubertus Joseph Beckers , Charles Morris Yarbrough , Stephen Harold Brown , Yeo-Meng Lim
IPC分类号： C07C2/02
CPC分类号： C07C2/12 , C07C7/10 , C07C29/141 , C07C29/16 , C07C45/50 , C07C51/235 , C07C67/08 , C07C2529/70 , C07C2601/14 , C10G21/00 , C10G25/00 , C10G50/00 , C10L1/06 , C12C11/02 , C07C11/02 , C07C31/02 , C07C31/12 , C07C63/15 , C07C69/76 , C07C69/80 , C07C69/82 , C07C69/78 , C07C69/75 , C07C47/02
摘要： Nitrogen-containing Lewis bases act as poisons for molecular sieve catalysts used in oligomerisation reactions. A lowering of their presence in the feed prior to the contacting thereof with the molecular sieve brings a significant extension of catalyst life. Excessive elimination of these poisons may be disadvantageous. Lowering the levels of these catalyst poisons to more manageable concentrations is therefore preferred.
摘要翻译： 含氮路易斯碱作为低聚反应中使用的分子筛催化剂的毒物。 在与分子筛接触之前，它们在进料中的存在降低导致催化剂寿命的显着延长。 过度消除这些毒素可能是不利的。 因此优选将这些催化剂毒物的水平降低到更易于控制的浓度。
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公开(公告)号：US07572947B2
公开(公告)日：2009-08-11
申请号：US11500004
申请日：2006-08-07
IPC分类号： C07C2/12
CPC分类号： C07C2/12 , C07C2529/70 , C10G50/00 , C10G2300/1092 , C10G2300/202 , C10G2300/4081 , C10G2400/22
摘要： The invention is directed to a method of selectively oligomerizing olefin monomers by controlling feedstock composition and reaction conditions. Reaction conditions are chosen to include at least one of: (a) dimer recycle; (b) staged injection of monomer; and (c) utilization of a two catalyst system.
摘要翻译： 本发明涉及通过控制原料组成和反应条件来选择性低聚烯烃单体的方法。 选择反应条件以包括以下至少一种：（a）二聚体再循环; （b）单体注射; 和（c）利用两个催化剂体系。
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