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    Polymer bound calixarenes
    2.
    发明授权
    Polymer bound calixarenes 失效
    聚合物结合的杯芳烃

    公开(公告)号：US4642362A

    公开(公告)日：1987-02-10

    申请号：US717251

    申请日：1985-03-28

    申请人： Stephen J. Harris ,  John G. Woods ,  John M. Rooney

    发明人： Stephen J. Harris ,  John G. Woods ,  John M. Rooney

    IPC分类号： C07F7/18 ,  C08F8/00 ,  C08G18/32 ,  C08G18/54 ,  C08G75/02 ,  C08G77/38 ,  C08G85/00 ,  C09J4/00 ,  C07F7/10

    CPC分类号： C08G85/00 ,  C07F7/1836 ,  C08F8/00 ,  C08G18/3215 ,  C08G18/542 ,  C08G75/02 ,  C08G77/38 ,  C09J4/00

    摘要： A linear or cross-linked polymer selected from polythioethers, polyethers, styrenic polymers, polyacrylates, and polyorganosiloxanes having a plurality of calixarene groups bound thereon, the calixarene groups having the formula ##STR1## where the R.sup.1 groups are the same or different H or hydrocarbyl groups; the R.sup.2 groups are H, hydrocarbyl, --CH.sub.2 C(.dbd.O)OR.sup.3, --CH.sub.2 C(.dbd.O)R.sup.3, or --C(.dbd.O)NHR.sup.3, R.sup.3 is hydrocarbyl or substituted hydrocarbyl; n is an integer of 1-8, m is an integer of 0-7 and n+m is 4-8.

    摘要翻译： 选自聚硫醚，聚醚，苯乙烯聚合物，聚丙烯酸酯和结合有多个杯芳烃的聚有机硅氧烷的线性或交联聚合物，具有式I'或II'的杯芳烃基团，其中R 1基团为 相同或不同的H或烃基; R 2是H，烃基，-CH 2 C（= O）OR 3，-CH 2 C（= O）R 3或-C（= O）NHR 3，R 3是烃基或取代的烃基; n为1-8的整数，m为0-7的整数，n + m为4-8。

    Resists formed by vapor deposition of anionically polymerizable monomer
    4.
    发明授权
    Resists formed by vapor deposition of anionically polymerizable monomer 失效
    通过阴离子聚合单体的气相沉积形成的抗蚀剂

    公开(公告)号：US4675273A

    公开(公告)日：1987-06-23

    申请号：US828107

    申请日：1986-02-10

    申请人： John G. Woods ,  John M. Rooney

    发明人： John G. Woods ,  John M. Rooney

    IPC分类号： G03F7/004 ,  G03F7/16 ,  G03F7/40 ,  G03C5/00 ,  B05D5/12 ,  C23C16/00

    CPC分类号： G03F7/167 ,  G03F7/004 ,  G03F7/40

    摘要： A method for applying a polymeric resist coating of very high molecular weight to a suitable substrate without the necessity of elaborate purification steps and for ensuring adequate coverage of raised regions in three-dimensionally patterned substrates. The method comprises exposing the substrate to be coated to the vapor of an anionically polymerizable monomer of the formula:CHR.dbd.CXYwhere X and Y are strong electron withdrawing groups and R si H or, provided that X and Y are both --CN, C.sub.1 -C.sub.4 alkyl for sufficient time to deposit a polymerizable coating thereon. Particularly preferred monomers are 2-cyanoacrylate esters. The monomer condenses and polymerizes on the surface of the substrate to give a highly uniform high molecular weight polymeric coating which is useful as a resist coating in lithographic processes employing plasma or acid etch techniques.

    摘要翻译： 一种将非常高分子量的聚合物抗蚀剂涂层施加到合适的基底上的方法，而不需要精心的纯化步骤，并且确保在三维图案化的基底中充分覆盖凸起区域。 该方法包括将待涂覆的基底暴露于下式的阴离子可聚合单体的蒸气：CHR = CXY，其中X和Y是强吸电子基团和R si H，或者X和Y都是-CN，C1 -C4烷基，足以在其上沉积可聚合涂层。 特别优选的单体是2-氰基丙烯酸酯。 单体在基材的表面上缩合和聚合，得到高度均匀的高分子量聚合物涂层，其在使用等离子体或酸蚀刻技术的光刻工艺中用作抗蚀剂涂层。

    Imaging method for vapor deposited photoresists of anionically polymerizable monomer
    5.
    发明授权
    Imaging method for vapor deposited photoresists of anionically polymerizable monomer 失效
    阴离子聚合单体气相沉积光刻胶成像方法

    公开(公告)号：US4675270A

    公开(公告)日：1987-06-23

    申请号：US828109

    申请日：1986-02-10

    申请人： John G. Woods ,  John M. Rooney

    发明人： John G. Woods ,  John M. Rooney

    IPC分类号： G03F7/004 ,  G03F7/16 ,  G03F7/40 ,  G03C5/00 ,  G03C5/04

    CPC分类号： G03F7/40 ,  G03F7/004 ,  G03F7/167

    摘要： A method for imaging vapor deposited photoresists of cyanoacrylates or related anionically polymerizable monomers without the use of solvent development. This method consists of treating the substrate with a compound which releases acid when exposed to high-energy radiation. In certain cases when the surface of the substrate is slightly acidic or neutral, it is necessary to activate the surface with a basic liquid or vapor which must be chosen so as not to react with the radiation-sensitive acid precursor. The substrate is exposed to actinic or ionizing radiation through a mask or to steered high-energy beams. Finally, the substrate is exposed to a vapor of cyanoacrylate monomer which condenses and polymerizes on the unirradiated regions forming a relief image.

    摘要翻译： 用于成像氰基丙烯酸酯或相关阴离子聚合单体的蒸镀沉积光致抗蚀剂的方法，而不使用溶剂显影。 该方法包括用暴露于高能量辐射时释放酸的化合物处理底物。 在某些情况下，当基质的表面呈酸性或中性时，必须用碱性液体或蒸汽来活化表面，碱性液体或蒸汽必须选择为不与辐射敏感的酸前体反应。 衬底通过掩模暴露于光化或电离辐射，或引导高能束。 最后，将基底暴露于氰基丙烯酸酯单体的蒸汽，其在形成浮雕图像的未照射区域上冷凝和聚合。

    Thiol/ene compositions
    6.
    发明授权
    Thiol/ene compositions 失效
    硫醇/烯组合物

    公开(公告)号：US5021512A

    公开(公告)日：1991-06-04

    申请号：US351310

    申请日：1989-05-04

    申请人： John G. Woods ,  John M. Rooney

    发明人： John G. Woods ,  John M. Rooney

    IPC分类号： C07C43/23 ,  C08F12/34 ,  C08F257/00 ,  C08F273/00 ,  C08F283/00 ,  C08G77/38

    CPC分类号： C08G77/38 ,  C07C43/23 ,  C08F12/34

    摘要： Curable thiol/ene compositions comprise:(1) a multifunctional styryloxy monomer having one or more of the following structures ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are selected from vinyl (--CH.dbd.CH.sub.2), 1-propenyl (--CH.dbd.CH--CH.sub.3), isopropenyl ##STR2## hydrogen, lower alkyl or alkoxy, provided that at least one of R.sup.1, R.sup.2 and R.sup.3 must be vinyl, 1-propenyl or isopropenyl;n is an integer .gtoreq.1;if n=1, then R.sup.4 is a monovalent hydrocarbon radical containing one free-radically copolymerizable alkenyl or cycloalkenyl group,if n.gtoreq.2, R.sup.4 is a multivalent hydrocarbon radical which may contain a maximum of one free-radically copolymerizable alkenyl or cycloalkenyl group;R.sup.5 is a divalent hydrocarbon radical; or a carbon atom which is part of a cyclic group in the radical G; or a radical of formula ##STR3## where R.sup.7 is a divalent hydrocarbon radical; if n=1, G is a monovalent organic or inorganic radical, free of phenolic hydroxyl groups or other groups which substantially interfere with radical polymerization, containing one free-radically copolymerizable alkenyl or cycloalkenyl group;if n.gtoreq.2, G is a multivalent organic or inorganic radical, free of phenolic hydroxyl groups or other groups which substantially interfere with radical polymerization, which may contain a maximum of one free-radically copolymerizable alkenyl or cycloalkenyl group;R.sup.6 is a lower alkyl or cycloalkyl group; or if n=1, R.sup.6 may also be an alkenyl or cycloalkenyl group, provided that G does not contain an alkenyl or cycloalkenyl group.(2) a multifunction thiol.(3) a free-radical curing rate accelerator.Novel styryloxy compounds are described which are reaction products of isoeugenol and (a) multifunctional epoxy compounds or (b) allyl glycidyl ether with or without a multifunctional polydimethylsiloxane.

    摘要翻译： 可固化硫醇/烯组合物包含：（1）具有一个或多个以下结构的多官能苯乙烯基氧基单体，其中R 1，R 2和R 3选自乙烯基（-CH = CH 2），1- 丙烯基（-CH = CH-CH 3），异丙烯基氢，低级烷基或烷氧基，条件是R 1，R 2和R 3中的至少一个必须是乙烯基，1-丙烯基或异丙烯基; n是整数> / = 1; 如果n = 1，那么R 4是含有一个可自由基共聚的烯基或环烯基的单价烃基，如果n≥2，R4是多价烃基，其可以含有最多一个可自由基共聚的烯基或环烯基 组; R5是二价烃基; 或作为基团G中的环状基团的一部分的碳原子; 或其中R 7为二价烃基的式“IMAGE”基团; 如果n = 1，G是不含酚羟基或基本上干扰自由基聚合的其它基团的单价有机或无机基团，其中含有一个可自由基共聚的烯基或环烯基; 如果n> / = 2，G是多价有机或无机基团，不含酚羟基或基本上干扰自由基聚合的其它基团，其可以含有最多一个可自由基共聚的烯基或环烯基; R6是低级烷基或环烷基; 或者如果n = 1，则R6也可以是烯基或环烯基，条件是G不含有烯基或环烯基。 （2）多功能硫醇。 （3）自由基固化速率加速剂。 描述了新颖的苯乙烯基氧基化合物，其是异丁子香酚和（a）多官能环氧化合物的反应产物或（b）具有或不具有多官能聚二甲基硅氧烷的烯丙基缩水甘油醚。

    Instant adhesive composition utilizing calixarene accelerators
    9.
    发明授权
    Instant adhesive composition utilizing calixarene accelerators 失效
    使用杯芳烃加速剂的速溶胶组合物

    公开(公告)号：US4636539A

    公开(公告)日：1987-01-13

    申请号：US776536

    申请日：1985-09-16

    申请人： Stephen J. Harris ,  M. Anthony McKervey ,  David P. Melody ,  John Woods ,  John M. Rooney

    发明人： Stephen J. Harris ,  M. Anthony McKervey ,  David P. Melody ,  John Woods ,  John M. Rooney

    IPC分类号： C08G18/32 ,  C08G18/54 ,  C08G75/02 ,  C08G77/38 ,  C09J4/00 ,  C08F220/34

    CPC分类号： C08G77/38 ,  C08G18/3215 ,  C08G18/542 ,  C08G75/02 ,  C09J4/00

    摘要： Cyanoacrylate adhesive compositions which employ calixarene compounds as additives give substantially reduced fixture and cure times on de-activating substrates such as wood. The calixarene compounds are preferably employed at levels of about 0.1-1% by weight of the composition. The calixarene compounds particularly useful in this invention may be represented by the formula: ##STR1## where R.sup.1 is alkyl, alkoxy, substituted alkyl or substituted alkoxy; R.sup.2 is H or alkyl; and n=4, 6, or 8.The compositions are further characterized by a thickener component, which may suitably be selected from various polymers such as poly(methyl methacrylate), methacrylate type copolymers, acrylic rubbers, polyvinyl acetate and poly(.alpha.-cyanoacrylate) or silicas treated with polydialkylsiloxanes or trialkylsilanes.

    摘要翻译： 使用杯芳烃化合物作为添加剂的氰基丙烯酸酯粘合剂组合物在去活化底物例如木材上显着降低夹具和固化时间。 杯芳烃化合物优选以组合物重量的约0.1-1％的量使用。 特别可用于本发明的杯芳烃化合物可以由下式表示：其中R 1是烷基，烷氧基，取代的烷基或取代的烷氧基; R2是H或烷基; 组合物的进一步特征在于增稠剂组分，其可以适当地选自各种聚合物，例如聚（甲基丙烯酸甲酯），甲基丙烯酸酯型共聚物，丙烯酸橡胶，聚乙酸乙烯酯和聚（α- 氰基丙烯酸酯）或用聚二烷基硅氧烷或三烷基硅烷处理的二氧化硅。