Extrusion of vinylidene chloride copolymers under inert atmosphere
    3.
    发明授权
    Extrusion of vinylidene chloride copolymers under inert atmosphere 失效
    在惰性气氛下挤出偏二氯乙烯共聚物

    公开(公告)号:US5045259A

    公开(公告)日:1991-09-03

    申请号:US493100

    申请日:1990-03-14

    IPC分类号: B29C47/00 B29C47/76

    摘要: The present invention is a process for forming an extruded article containing a copolymer of vinylidene chloride and at least one other ethylenically-unsaturated comonomer, said process comprising the step of extruding the copolymer in the presence of (1) at least one gas which is inert with respect to the copolymer and does not plasticize the copolymer; and (2) essentially no gases which are not inert with respect to the copolymer. Vinylidene chloride copolymers extruded according to the process of the present invention have lower metal adhesion and less tendency to contain specks of carbon than do vinylidene chloride copolymer copolymers extruded under an air atmosphere.

    摘要翻译: 本发明是一种形成含有偏二氯乙烯与至少一种其它烯属不饱和共聚单体的共聚物的挤压制品的方法,所述方法包括在(1)至少一种惰性气体的存在下挤出共聚物的步骤 并且不使共聚物增塑; 和(2)基本上没有相对于共聚物不是惰性的气体。 根据本发明的方法挤出的偏二氯乙烯共聚物在空气气氛下挤出的偏二氯乙烯共聚物共聚物具有较低的金属粘附性和较少的含有碳斑的趋势。

    Block copolymer compositions containing substantially inert thermoelastic extenders
    5.
    发明授权
    Block copolymer compositions containing substantially inert thermoelastic extenders 有权
    含有基本上惰性的热弹性增量剂的嵌段共聚物组合物

    公开(公告)号:US06403710B1

    公开(公告)日:2002-06-11

    申请号:US09690039

    申请日:2000-10-16

    IPC分类号: C08L900

    摘要: The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

    摘要翻译: 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物,其中组合物与组合物未未改性的未稀释(纯)嵌段共聚物部分具有基本上相同的比较弹性,高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性,并且非常适用于制造弹性模制品,薄膜和纤维,以及用沥青,粘合剂和密封剂配制。 新型热塑性弹性体组合物包含(a)约50至约99重量%的至少一种嵌段共聚物和(b)约1至约50重量%的至少一种乙烯互聚物,其密度约为0.855克/ cc至约0.905g / cc,其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂,组合物进一步表征为具有: 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2,ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4,和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。

    Extrudable polymeric compositions
    6.
    发明授权
    Extrudable polymeric compositions 失效
    可挤压聚合物组合物

    公开(公告)号:US4937279A

    公开(公告)日:1990-06-26

    申请号:US230932

    申请日:1988-08-11

    IPC分类号: C08K3/32

    CPC分类号: C08K3/32 Y10T428/1321

    摘要: The present invention is a polymeric composition with improved extrudability comprising a vinylidene chloride interpolymer and a Group IIA alkaline-earth hydroxyphosphate, which is incorporated with the vinylidene chloride interpolymer by advance addition, polymer slurry addition or, finally, by dry blending addition. The Group IIA alkaline-earth hydroxyphosphate will be present in an amount of between about 0.01 to about 5 weight percent, said weight percents being based on the total weight of the polymeric composition.

    摘要翻译: 本发明是一种具有改进的挤出性的聚合物组合物,其包含偏二氯乙烯互聚物和IIA型碱土金属羟基磷酸酯,其通过预先添加加入偏二氯乙烯互聚物,加入聚合物浆料,或最后通过干混添加。 IIA族碱土金属羟基磷酸酯的存在量为约0.01至约5重量%,所述重量百分比基于聚合物组合物的总重量。