公开(公告)号：US6162644A

公开(公告)日：2000-12-19

申请号：US268804

申请日：1999-03-16

申请人： Sun Choi ,  Yong-Sueng Kim ,  Hoe-Il Chung ,  Suk-Joon Kim ,  Joon-Sik Lee ,  Min-Sik Ku ,  Young-Hwan Kim

发明人： Sun Choi ,  Yong-Sueng Kim ,  Hoe-Il Chung ,  Suk-Joon Kim ,  Joon-Sik Lee ,  Min-Sik Ku ,  Young-Hwan Kim

IPC分类号： C07C5/27 ,  C07C7/04 ,  C07C7/12 ,  C07C15/08 ,  G01N21/35 ,  G01N21/3577 ,  G01N21/359 ,  G01N35/08 ,  G01N21/00 ,  G05D7/00

CPC分类号： G01N21/359 ,  G01N21/3577 ,  Y10T436/12

摘要： A method for and an apparatus for controlling and optimizing a xylene isomer separation and isomerization process, in which near infrared light of a wavelength ranging from 1,100 nm to 2,500 nm is transmitted through samples obtained at different stages of the process from raw materials flowing in the process by use of an analyzer system using optical fibers, thereby simultaneously measuring, in an on-line manner, xylene isomers and aromatic hydrocarbons containing 6 to 9 carbon atoms from those samples. Accordingly, it is possible to monitor the entire operation state of the process within 15 minutes in an on-line manner. Conventionally, 2 to 3 days are taken for the same monitoring.

摘要翻译： 用于控制和优化二甲苯异构体分离和异构化过程的方法和装置，其中波长为1100nm至2500nm的近红外光通过在该方法的不同阶段获得的样品从在 通过使用使用光纤的分析器系统进行处理，由此同时以在线方式同时测量来自那些样品的含有6至9个碳原子的二甲苯异构体和芳族烃。 因此，可以在15分钟内以在线方式监视处理的整个操作状态。 通常情况下，为了同样的监测需要2到3天的时间。

公开(公告)号：US06870073B2

公开(公告)日：2005-03-22

申请号：US10218846

申请日：2002-08-13

申请人： Sun Choi ,  Sung-Joon Lee ,  Sin-Chul Kang ,  Sang-Won Kim ,  Min-Sik Ku ,  Ahn-Seop Choi ,  Byoung-Mu Chang

发明人： Sun Choi ,  Sung-Joon Lee ,  Sin-Chul Kang ,  Sang-Won Kim ,  Min-Sik Ku ,  Ahn-Seop Choi ,  Byoung-Mu Chang

IPC分类号： G01N21/35 ,  B01D53/04 ,  B01J20/281 ,  C10G25/00 ,  C10G25/03 ,  C10G53/08 ,  C10G53/16 ,  C10G55/04 ,  C10G61/06 ,  C10G73/02 ,  G01N30/00 ,  G01N30/26 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/74 ,  G01N30/88 ,  C07C7/12

CPC分类号： C10G25/03 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/30

摘要： There is provided with a process for separating normal paraffins from hydrocarbons of C5-10 using zeolite molecular sieve 5A, which comprises the steps of (a) selective adsorption (b) cocurrent purge (c) countercurrent desorption. The present process employs butane for purge and desorption step to achieve excellent desorption efficiency and recycles butane in liquid phase to reduce the investment cost. The optimum operating conditions for feedstock change and adsorption capacity reduction are determined by NIR system for on-line monitoring and control. The separated normal paraffins can be efficiently applied to raw material for ethylene production and the separated non-normal paraffins can be efficiently applied to raw material for aromatic hydrocarbons production.

摘要翻译： 提供了一种使用沸石分子筛5A从C5-10烃中分离正链烷烃的方法，其包括以下步骤：（a）选择性吸附（b）并流吹扫（c）逆流解吸。 本发明方法采用丁烷进行吹扫和解吸步骤以达到优异的解吸效率，并在液相中回收丁烷以降低投资成本。 原料变化和吸附容量降低的最佳操作条件由NIR系统确定，用于在线监测和控制。 分离的正链烷烃可以有效地应用于乙烯生产的原料，并且分离的非正常链烷烃可以有效地应用于用于芳烃生产的原料。

公开(公告)号：US09056308B2

公开(公告)日：2015-06-16

申请号：US14168602

申请日：2014-01-30

申请人： Dae Hyun Choo ,  Hong Chan Kim ,  Suk Joon Kim ,  Ji Min Kim ,  Tae Jin Kim ,  Sun Choi ,  Seung Hoon Oh ,  Yong Seung Kim ,  Deuk Soo Park ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

发明人： Dae Hyun Choo ,  Hong Chan Kim ,  Suk Joon Kim ,  Ji Min Kim ,  Tae Jin Kim ,  Sun Choi ,  Seung Hoon Oh ,  Yong Seung Kim ,  Deuk Soo Park ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

IPC分类号： B01J29/06 ,  B01J29/48 ,  B01J29/076 ,  B01J37/00 ,  C10G11/05 ,  B01J37/28

CPC分类号： B01J29/48 ,  B01J29/076 ,  B01J37/0045 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G2300/301 ,  C10G2400/20

摘要： Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO2 and 1˜15 wt % of P2O5 are simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.

摘要翻译： 公开了一种分子筛催化剂及其制备方法，用于在严酷的高温高湿环境下催化裂解石脑油。 详细地，通过喷雾干燥和煅烧混合浆料制备催化剂，其中0.01〜5.0重量％的MnO 2和1〜15重量％的P 2 O 5同时嵌入由沸石，粘土和无机络合物组成的催化剂中。 根据本发明，使用锰和磷酸盐同时嵌入沸石和无机络合物的方法来提高所得球形催化剂的热稳定性，并通过保护沸石的酸性位点来提高裂解烃如石脑油的烯烃产率。 为了合成所需的催化剂，重要的步骤是Mn，P，沸石和无机络合物的混合比和混合顺序。

公开(公告)号：US08840864B2

公开(公告)日：2014-09-23

申请号：US13502607

申请日：2010-10-18

申请人： Sun Choi ,  Deuk Soo Park ,  Suk Joon Kim ,  Dae Hyun Choo ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

发明人： Sun Choi ,  Deuk Soo Park ,  Suk Joon Kim ,  Dae Hyun Choo ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

IPC分类号： C01B39/38 ,  B01J29/40

CPC分类号： C01B39/38 ,  B01J20/18 ,  B01J29/40 ,  B01J39/14

摘要： A method of preparing ZSM-5, including: providing a nanocrystalline ZSM-5 seed having a size of 70-150 nm; adding the nanocrystalline ZSM-5 seed to a stock solution including water glass as a silica source, an alumina source, a neutralizer and water to form a reaction mixture; and maintaining the reaction mixture at 150-200° C. to crystallize the reaction mixture. The method is advantageous in that ZSM-5 having small and uniform crystal sizes and including no impurities can be synthesized in a short period of time.

摘要翻译： 一种制备ZSM-5的方法，包括：提供尺寸为70-150nm的纳米晶体ZSM-5种子; 将纳米晶体ZSM-5种子加入到包含水玻璃作为二氧化硅源的储备溶液中，氧化铝源，中和剂和水以形成反应混合物; 并将反应混合物保持在150-200℃以使反应混合物结晶。 该方法的优点在于，可以在短时间内合成具有小而均匀的晶体尺寸且不含杂质的ZSM-5。

公开(公告)号：US07488700B2

公开(公告)日：2009-02-10

申请号：US11427001

申请日：2006-06-28

申请人： Sun Choi ,  Yong Seung Kim ,  Deuk Soo Park ,  Suk Joon Kim ,  Il Mo Yang ,  Hee Young Kim ,  Yong Ki Park ,  Chul Wee Lee ,  Won Choon Choi ,  Kwang An Ko ,  Na Young Kang

发明人： Sun Choi ,  Yong Seung Kim ,  Deuk Soo Park ,  Suk Joon Kim ,  Il Mo Yang ,  Hee Young Kim ,  Yong Ki Park ,  Chul Wee Lee ,  Won Choon Choi ,  Kwang An Ko ,  Na Young Kang

IPC分类号： B01J29/06 ,  B01J27/16 ,  B01J27/18 ,  B01J27/182

CPC分类号： B01J29/40 ,  B01J29/061 ,  B01J29/405 ,  B01J29/46 ,  B01J2229/12 ,  B01J2229/18 ,  C10G29/205 ,  C10G2400/20

摘要： Disclosed are a hydrothermally stable porous molecular sieve catalyst and a preparation method thereof. The catalyst consists of a product obtained by the evaporation of water from a raw material mixture comprising a molecular sieve having a framework of Si—OH—Al—, a water-insoluble metal salt and a phosphate compound. The catalyst maintains its physical and chemical stabilities even in an atmosphere of high temperature and humidity. Accordingly, the catalyst shows excellent catalytic activity even when it is used in a severe process environment of high temperature and humidity in heterogeneous catalytic reactions, such as various oxidation/reduction reactions, including catalytic cracking reactions, isomerization reactions, alkylation reactions and esterification reactions.

摘要翻译： 公开了一种水热稳定的多孔分子筛催化剂及其制备方法。 催化剂由通过从包含具有Si-OH-Al-骨架的分子筛，水不溶性金属盐和磷酸盐化合物的原料混合物中蒸发水得到的产物组成。 即使在高温和高湿的气氛下，催化剂仍保持其物理和化学稳定性。 因此，即使在非均相催化反应如催化裂化反应，异构化反应，烷基化反应，酯化反应等各种氧化/还原反应中，在恶劣的高温高湿环境下使用，催化剂也具有优异的催化活性。

公开(公告)号：US08673802B2

公开(公告)日：2014-03-18

申请号：US12735647

申请日：2009-02-05

申请人： Dae Hyun Choo ,  Hong Chan Kim ,  Suk Joon Kim ,  Ji Min Kim ,  Tae Jin Kim ,  Sun Choi ,  Seung Hoon Oh ,  Yong Seung Kim ,  Deuk Soo Park ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

发明人： Dae Hyun Choo ,  Hong Chan Kim ,  Suk Joon Kim ,  Ji Min Kim ,  Tae Jin Kim ,  Sun Choi ,  Seung Hoon Oh ,  Yong Seung Kim ,  Deuk Soo Park ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

IPC分类号： B01J29/06

CPC分类号： B01J29/48 ,  B01J29/076 ,  B01J37/0045 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G2300/301 ,  C10G2400/20

摘要： Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO2 and 1˜15 wt % of P2O5 are simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.

摘要翻译： 公开了一种分子筛催化剂及其制备方法，用于在严酷的高温高湿环境下催化裂解石脑油。 详细地，通过喷雾干燥和煅烧混合浆料制备催化剂，其中0.01〜5.0wt％的MnO 2和1〜15wt％的P 2 O 5同时嵌入由沸石，粘土和无机络合物组成的催化剂中。 根据本发明，使用锰和磷酸盐同时嵌入沸石和无机络合物的方法来提高所得球形催化剂的热稳定性，并通过保护沸石的酸性位点来提高裂解烃如石脑油的烯烃产率。 为了合成所需的催化剂，重要的步骤是Mn，P，沸石和无机络合物的混合比和混合顺序。

公开(公告)号：US20120230910A1

公开(公告)日：2012-09-13

申请号：US13502607

申请日：2010-10-18

申请人： Sun Choi ,  Deuk Soo Park ,  Suk Joon Kim ,  Dae Hyun Choo ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

发明人： Sun Choi ,  Deuk Soo Park ,  Suk Joon Kim ,  Dae Hyun Choo ,  Yong Ki Park ,  Chul Wee Lee ,  Hee Young Kim ,  Won Choon Choi ,  Na Young Kang ,  Bu Sub Song

IPC分类号： C01B39/38

CPC分类号： C01B39/38 ,  B01J20/18 ,  B01J29/40 ,  B01J39/14

摘要： Disclosed herein is a method of preparing ZSM-5, including: providing a nanocrystalline ZSM-5 seed having a size of 70˜300 nm; adding the nanocrystalline ZSM-5 seed to a stock solution including water glass as a silica source, an alumina source, a neutralizer and water to form a reaction mixture; and maintaining the reaction mixture at 150˜200° C. to crystallize the reaction mixture. The method is advantageous in that ZSM-5 having small and uniform crystal sizes and including no impurities can be synthesized in a short period of time.

摘要翻译： 本文公开了一种制备ZSM-5的方法，包括：提供尺寸为70〜300nm的纳米晶体ZSM-5种子; 将纳米晶体ZSM-5种子加入到包含水玻璃作为二氧化硅源的储备溶液中，氧化铝源，中和剂和水以形成反应混合物; 并将反应混合物保持在150〜200℃，使反应混合物结晶。 该方法的优点在于，可以在短时间内合成具有小而均匀的晶体尺寸且不含杂质的ZSM-5。

公开(公告)号：US07663013B2

公开(公告)日：2010-02-16

申请号：US12265729

申请日：2008-11-05

申请人： Sun Choi ,  Deuk Soo Park ,  Suk Joon Kim ,  Ahn Seop Choi ,  Hee Young Kim ,  Yong Ki Park ,  Chul Wee Lee ,  Won Choon Choi ,  Sang Yun Han ,  Jeong Ri Kim

发明人： Sun Choi ,  Deuk Soo Park ,  Suk Joon Kim ,  Ahn Seop Choi ,  Hee Young Kim ,  Yong Ki Park ,  Chul Wee Lee ,  Won Choon Choi ,  Sang Yun Han ,  Jeong Ri Kim

IPC分类号： C07C4/02 ,  C10G11/02

CPC分类号： C07C4/06 ,  B01J21/02 ,  B01J21/04 ,  B01J21/08 ,  B01J21/16 ,  B01J27/14 ,  B01J27/16 ,  B01J29/049 ,  B01J29/40 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/08 ,  B01J37/14 ,  C10G2300/1044 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2400/20 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/04

摘要： A porous solid acid catalyst for producing light olefins is prepared through pillaring and a solid state reaction of a raw material mixture. The catalyst is made of a porous material having a crystalline structure that is different from that of the raw material mixture. The catalyst exhibits excellent catalytic activity (i.e., conversion and selectivity) in the production of light olefins from hydrocarbon feeds such as full range naphthas.

摘要翻译： 通过原料混合物的柱状和固态反应制备用于生产轻质烯烃的多孔固体酸催化剂。 催化剂由具有不同于原料混合物的结晶结构的多孔材料制成。 该催化剂在从烃进料如全程石脑油生产轻质烯烃时表现出优异的催化活性（即转化率和选择性）。

公开(公告)号：US08293961B2

公开(公告)日：2012-10-23

申请号：US11996319

申请日：2006-06-07

申请人： Sun Choi ,  Yong Seung Kim ,  Deuk Soo Park ,  Suk Joon Kim ,  Ji Min Kim ,  Hong Chan Kim ,  Seung Hoon Oh ,  Tae-Jin Kim ,  Dae Hyun Choo

发明人： Sun Choi ,  Yong Seung Kim ,  Deuk Soo Park ,  Suk Joon Kim ,  Ji Min Kim ,  Hong Chan Kim ,  Seung Hoon Oh ,  Tae-Jin Kim ,  Dae Hyun Choo

IPC分类号： C07C4/06

CPC分类号： C07C7/04 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/301 ,  C10G2300/4093 ,  C10G2300/802 ,  C10G2400/20 ,  Y02P20/584 ,  C07C11/02

摘要： Disclosed is a catalytic cracking process for the production of light olefins from a hydrocarbon feedstock using fast fluidization, which is a preferred process for more efficiently increasing the production of light olefin hydrocarbons. According to this invention, a fast fluidization regime is applied to a fluidized bed catalytic cracking process of producing light olefins using zeolite, such that a volume fraction and distribution of the catalyst sufficient to induce the catalytic cracking reaction can be provided, thus effectively enhancing the production of light olefin hydrocarbons, in particular, ethylene and propylene, at high selectivity.

摘要翻译： 公开了一种用于使用快速流化从烃原料生产轻质烯烃的催化裂化方法，其是用于更有效地增加轻质烯烃的生产的优选方法。 根据本发明，将快速流化方案应用于使用沸石生产轻质烯烃的流化床催化裂化方法，从而可以提供足以诱导催化裂化反应的催化剂的体积分数和分布，从而有效地提高了 以高选择性生产轻质烯烃，特别是乙烯和丙烯。

公开(公告)号：US07939702B2

公开(公告)日：2011-05-10

申请号：US11421496

申请日：2006-06-01

申请人： Sun Choi ,  Yong Seung Kim ,  Deuk Soo Park ,  Suk Joon Kim ,  Il Mo Yang

发明人： Sun Choi ,  Yong Seung Kim ,  Deuk Soo Park ,  Suk Joon Kim ,  Il Mo Yang

IPC分类号： C07C4/02

CPC分类号： C10G51/04 ,  C10G11/10 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2300/807 ,  C10G2400/20 ,  Y02P30/40

摘要： Disclosed is a process for increasing production of light olefinic hydrocarbons from hydrocarbon feedstock by catalytic cracking. In the process, an effective separation process structure and recycle method of light olefins are used not only to increase the productivity and efficiency of an overall process, thus effectively increasing the production of light olefins, but also to simplify the overall process.

摘要翻译： 公开了一种通过催化裂化从烃原料生产轻质烯烃的方法。 在此过程中，轻质烯烃的有效分离工艺结构和回收方法不仅用于提高整个工艺的生产率和效率，从而有效地增加了轻质烯烃的生产，而且简化了整个工艺。