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公开(公告)号：US4746764A
公开(公告)日：1988-05-24
申请号：US939337
申请日：1986-12-08
IPC分类号： B01J29/62 , C07C5/41 , C07C15/00 , C10G35/095 , C07C2/52
CPC分类号： C10G35/095 , B01J29/62 , C07C5/417 , B01J2229/26 , B01J2229/42
摘要： A novel dehydrocyclization process for the conversion of C.sub.6 -plus paraffins to their corresponding aromatics is presented. This process is characterized by a unique catalytic composite which contains a nonacidic L-zeolite, a Group VIII metal component and sufficient surface-deposited alkali metal to provide a surface-deposited alkali metal index of from about 40 to about 500. A further characterization is that the catalyst is prepared without subjecting the L-zeolite to a solution having a pH of greater than 9, and without appreciable loss of SiO.sub.2 from the L-zeolite.
摘要翻译： 提出了一种用于将C6加烷烃转化成其相应芳烃的新型脱氢环化方法。 该方法的特征在于独特的催化复合材料，其含有非酸性L-沸石，第VIII族金属组分和足够的表面沉积碱金属，以提供约40至约500的表面沉积碱金属指数。进一步的表征 制备催化剂，而不使L-沸石经受pH大于9的溶液，并且没有来自L-沸石的可观的SiO 2损失。
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公开(公告)号：US4886927A
公开(公告)日：1989-12-12
申请号：US281424
申请日：1988-12-08
CPC分类号： C07C37/00 , C07C5/2724
摘要： This invention presents a process for isomerizing a non-equilibrium mixture of xylenes containing ethylbenzene, using a novel catalyst formulation comprising at least one Group VIII metal, a gallium-substituted pentasil zeolite and a matrix material of zirconia-alumina.
摘要翻译： 本发明提出了使用包含至少一种第Ⅷ族金属，镓取代的五元沸石和氧化锆 - 氧化铝的基体材料的新型催化剂配制异构化含有乙苯的二甲苯的非平衡混合物的方法。
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公开(公告)号：US06646159B2
公开(公告)日：2003-11-11
申请号：US09746585
申请日：2000-12-21
申请人： Lance A. Baird , Leonid B. Galperin , R. Joe Lawson , Robert H. Jensen , Oleg L. Eliseev , Albert L. Lapidus , Aduard G. Ostapenco
发明人： Lance A. Baird , Leonid B. Galperin , R. Joe Lawson , Robert H. Jensen , Oleg L. Eliseev , Albert L. Lapidus , Aduard G. Ostapenco
IPC分类号： C07C51114
CPC分类号： C07C51/14 , C07C29/149 , C07C53/126 , C07C31/125
摘要： Long chain alcohols and acids or other similar oxygenates such as esters are produced from paraffins of similar carbon number by a process comprising paraffin dehydrogenation, carbonylation, and separation. Preferably a mixture of paraffins extending over several carbon numbers and recovered from a kerosene fraction is processed, and unconverted paraffins are recycled to a dehydrogenation zone. Alternative reaction zone configurations, catalyst systems and product recovery methods are disclosed.
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公开(公告)号：US5498810A
公开(公告)日：1996-03-12
申请号：US293530
申请日：1994-08-19
CPC分类号： C10G65/08 , C10G59/02 , C10G69/08 , Y10S585/94
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain products suitable for further upgrading to reformulated fuels. A naphtha feedstock is hydrogenated to saturate aromatics, followed by selective isoparaffin synthesis to yield light and heavy naphtha and isobutane; isobutane and isopentane in the product are obtained in superequilibrium concentrations. The heavy naphtha may be processed by reforming, light naphtha may be isomerized, and isobutane may be upgraded by dehydrogenation, etherification and/or alkylation to yield gasoline components from the process combination suitable for production of reformulated gasoline.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得适于进一步升级至重整燃料的产品。 将石脑油原料氢化以使芳烃饱和，随后进行选择性异链烷烃合成以产生轻质和重质石脑油和异丁烷; 产物中的异丁烷和异戊烷以超平衡浓度获得。 重石脑油可以通过重整进行处理，轻质石脑油可以被异构化，并且可以通过脱氢，醚化和/或烷基化来提高异丁烷，以从适于生产重整汽油的方法组合产生汽油组分。
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5.发明授权Prevention of noble metal migration in bound zeolites during thermal oxidation 失效在热氧化过程中防止结合沸石中的贵金属迁移
公开(公告)号：US5185306A
公开(公告)日：1993-02-09
申请号：US735213
申请日：1991-07-24
申请人： Michelle J. Cohn , R. Joe Lawson , Mark D. Moser
发明人： Michelle J. Cohn , R. Joe Lawson , Mark D. Moser
IPC分类号： B01J29/068 , B01J37/24
CPC分类号： B01J37/24 , B01J29/068
摘要： Metal migration from molecular sieve particles to binder particles in agglomerates of molecular sieves bearing group VIII zerovalent metal occurs readily at temperatures above 350.degree. C. Such migration can seriously impair the performance of the catalyst whose effectiveness depends on the presence of the metal largely, if not exclusively, on the molecular sieve particle. Exposure of the catalyst, or a catalyst precursor, to temperatures facilitating group VIII metal migration can occur at various periods during the catalyst's history. Group VIII metal migration can be inhibited and often effectively prevented when chlorine or a chlorine-containing compound is present in the non-reducing atmosphere at temperatures which otherwise would bring about metal migration.
摘要翻译： 金属从分子筛颗粒迁移到带有第VIII族分子筛的附聚物中的粘结剂颗粒零价金属容易在高于350℃的温度下发生。这种迁移会严重损害催化剂的性能，其性能主要取决于金属的存在，如果 不排他地，在分子筛颗粒上。 催化剂或催化剂前体暴露于促进第VIII族金属迁移的温度可以在催化剂历史中的不同时期发生。 当否则会导致金属迁移的温度下，当非氯还原气体中存在氯或含氯化合物时，可以抑制VIII族金属迁移。
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公开(公告)号：US4923595A
公开(公告)日：1990-05-08
申请号：US283403
申请日：1988-12-12
申请人： Mark D. Moser , R. Joe Lawson
发明人： Mark D. Moser , R. Joe Lawson
CPC分类号： B01J35/008 , B01J23/624 , B01J23/626 , B01J23/628 , B01J23/8933 , B01J23/8966 , B01J35/0006 , B01J35/0073 , B01J35/0093 , B01J37/18 , C10G35/09
摘要： A novel trimetallic catalytic composite, a method of manufacture and process use thereof is disclosed. The composite comprises a refractory support having a nominal diameter of at least 650 microns and having deposited thereon a uniformly dispersed platinum component, a uniformly dispersed Group IVA metal component and a surface-impregnated metal or metal-containing component selected from the group consisting of rhodium, ruthenium, cobalt, nickel, or iridium. When this catalytic composite is used in the reforming of hydrocarbons at low pressures, significant improvement in activity stability is observed compared to catalysts of the prior art.
摘要翻译： 公开了一种新型的三金属催化复合材料，其制造方法和工艺用途。 该复合材料包括具有至少650微米的公称直径的耐火载体，并且在其上沉积有均匀分散的铂组分，均匀分散的IVA族金属组分和表面浸渍的金属或含金属的组分，其选自铑 ，钌，钴，镍或铱。 当该催化复合材料用于在低压下重整烃时，与现有技术的催化剂相比，观察到活性稳定性显着改善。
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7.发明授权Arylalkane sulfonate compositions produced using isomerization, dehydrogenation, and alkylation 失效使用异构化，脱氢和烷基化生产的芳基磺酸盐组合物公开(公告)号：US06515169B1
公开(公告)日：2003-02-04
申请号：US10205672
申请日：2002-07-25
IPC分类号： C07C30928
CPC分类号： C07C15/107 , C07C2529/18 , C07C2529/70 , C10M105/06 , C10M2203/06
摘要： The present invention is a process for producing aryl-alkanes by paraffin isomerization followed by paraffin dehydrogenation and then by alkylation of an aryl compound by a lightly branched olefin. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过石蜡异构化，然后进行链烷烃脱氢，然后通过轻支化烯烃烷基化芳基化合物来制备芳基烷烃的方法。 烷基化区的流出物包括再循环到异构化步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
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公开(公告)号：US5401388A
公开(公告)日：1995-03-28
申请号：US117466
申请日：1993-09-07
CPC分类号： C10G59/06
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a head-cut fraction to reforming, and a heavy potion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy potion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得符合目前重新配制的燃料标准的汽油。 将石脑油原料分馏以选择性地将轻石脑油引导至异构化或共混，将头馏分转化为重馏分，并将重质部分引入选择性异链烷烃合成以产生轻质和重质合成石脑油和异丁烷。 通过重整处理合成石脑油的重药剂。 轻石脑油可以异构化，有或没有产物的低辛烷值组分的再循环。 来自工艺组合的轻质，合成和重整产物的汽油组分混合。
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公开(公告)号：US5235120A
公开(公告)日：1993-08-10
申请号：US796562
申请日：1991-11-21
CPC分类号： C10L1/023 , C10G59/02 , C10G65/08 , C10G69/08 , C10G2400/02
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain products suitable for further upgrading to reformulated fuels. A naphtha feedstock is hydrogenated to saturate aromatics, followed by selective isoparaffin synthesis to yield light and heavy naphtha and isobutane. The heavy naphtha may be processed by reforming, light naphtha may be isomerized, and isobutane may be upgraded by dehydrogenation, etherification and/or alkylation to yield gasoline components from the process combination suitable for production of reformulated gasoline.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得适于进一步升级至重整燃料的产品。 将石脑油原料氢化以使芳烃饱和，随后进行选择性异链烷烃合成以产生轻质和重质石脑油和异丁烷。 重石脑油可以通过重整进行处理，轻质石脑油可以被异构化，并且可以通过脱氢，醚化和/或烷基化来提高异丁烷，以从适用于生产重整汽油的方法组合产生汽油组分。
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公开(公告)号：US5053558A
公开(公告)日：1991-10-01
申请号：US547705
申请日：1990-07-03
IPC分类号： C07C5/27
CPC分类号： C07C5/2791 , Y02P20/52
摘要： An improved process is disclosed for the isomerization of a non-equilibrium mixture of cresols to achieve a high yield of one or more cresol isomers using a catalyst comprising a Group VIII metal, a modifier, a pentasil zeolite, and an inorganic oxide binder.
摘要翻译： 公开了一种改进的方法，用于使用包含VIII族金属，改性剂，pentasil沸石和无机氧化物粘合剂的催化剂，使甲酚的非平衡混合物异构化以实现高产率的一种或多种甲酚异构体。
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