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    Process for producing polymer polyol
    3.
    发明授权
    Process for producing polymer polyol 失效
    制备聚合物多元醇的方法

    公开(公告)号：US4342840A

    公开(公告)日：1982-08-03

    申请号：US214283

    申请日：1980-12-08

    申请人： Shigeyuki Kozawa ,  Takao Doi ,  Nobuaki Kunii

    发明人： Shigeyuki Kozawa ,  Takao Doi ,  Nobuaki Kunii

    IPC分类号： C08G18/63 ,  C08G18/67 ,  C08G18/14 ,  C07C125/06

    CPC分类号： C08G18/675 ,  C08G18/635

    摘要： A polymer polyol is produced by polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least two nitrogen-containing bonds formed by reacting isocyanate groups with active hydrogen groups, at least one polymerizable unsaturated group and at least 1.7 hydroxyl groups, as average.A polymer polyol is produced by polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least 1.7 hydroxyl groups as average obtained by reacting a polyisocyanate with a mixture of a substantially saturated polyol having at least two hydroxyl groups and an unsaturated active hydrogen compound having at least one active hydrogen group and at least one polymerizable unsaturated group or by reacting said polyisocyanate with either of said substantially saturated polyol or said unsaturated active hydrogen compound and then reacting the remainder with the intermediate; or a polyol mixture obtained by diluting said nitrogen bond-containing unsaturated polyol or polyol mixture with a substantially saturated polyol.

    摘要翻译： 聚合物多元醇通过在具有含氮键的不饱和多元醇或多元醇混合物中使具有聚合性不饱和基团的单体聚合而制备，所述多元醇混合物具有至少两个通过异氰酸酯基团与活性氢基团反应形成的含氮键，至少一个可聚合不饱和基团和 至少1.7个羟基，平均值。 聚合物多元醇是通过在具有至少1.7个羟基的含氮键的不饱和多元醇或多元醇混合物中聚合具有可聚合不饱和基团的单体而制备的，所述多元醇混合物的平均值通过使多异氰酸酯与具有至少两个 羟基和具有至少一个活性氢基团和至少一个可聚合不饱和基团的不饱和活性氢化合物，或通过使所述多异氰酸酯与所述基本上饱和的多元醇或所述不饱和活性氢化合物反应，然后使剩余物与中间体反应; 或通过用基本上饱和的多元醇稀释所述含氮键的不饱和多元醇或多元醇混合物而获得的多元醇混合物。

    Aqueous composition
    4.
    发明授权
    Aqueous composition 失效
    水性成分

    公开(公告)号：US5434005A

    公开(公告)日：1995-07-18

    申请号：US31296

    申请日：1993-03-12

    申请人： Tomiya Sugiura ,  Hideki Nakagawa ,  Takao Doi ,  Shigeyuki Kozawa

    发明人： Tomiya Sugiura ,  Hideki Nakagawa ,  Takao Doi ,  Shigeyuki Kozawa

    IPC分类号： C08G18/08 ,  C08G18/10 ,  C08G18/48 ,  C08G18/80 ,  B05D3/02 ,  C08G18/81

    CPC分类号： C08G18/8061 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/4887 ,  Y10T428/31551 ,  Y10T428/31565

    摘要： An aqueous composition comprising a carboxylate group-containing blocked polyurethane and water as essential components, wherein said polyurethane is a reaction product of a carboxylic acid (or carboxylate) group-containing polyoxyalkylene polyol containing at least 50% by weight of oxyethylene groups, with an average number of hydroxyl groups being more than 2 and having, on an average, from 0.005 to 0.8 --COOX group (X: a hydrogen atom or a cation) per molecule at the backbone chain terminals, a polyisocyanate having isocyanate groups in an amount stoichiometrically in excess of the hydroxyl groups of said polyol, and a blocking agent in an amount corresponding to the stoichiometrically excess amount of said polyisocyanate, and when X is a hydrogen atom, X is converted to a cation at an optional stage.

    摘要翻译： 一种包含含羧酸酯基的封端聚氨酯和水作为必要组分的水性组合物，其中所述聚氨酯是含有至少50重量％的氧化乙烯基团的含羧酸（或羧酸根）基的聚氧化烯多元醇的反应产物， 羟基的平均数大于2，在主链末端平均每个分子具有0.005至0.8个-COOX基团（X：氢原子或阳离子），具有异氰酸酯基团的多异氰酸酯的化学计量 超过所述多元醇的羟基和与所述多异氰酸酯的化学计量过量相当的量的封端剂，当X为氢原子时，X在任意阶段转化为阳离子。

    Process for producing a condensed resin dispersion
    7.
    发明授权
    Process for producing a condensed resin dispersion 失效
    缩合树脂分散液的制造方法

    公开(公告)号：US5344874A

    公开(公告)日：1994-09-06

    申请号：US726763

    申请日：1991-07-08

    申请人： Takao Doi ,  Noriko Itaya ,  Masami Yamashita ,  Nobuaki Kunii

    发明人： Takao Doi ,  Noriko Itaya ,  Masami Yamashita ,  Nobuaki Kunii

    IPC分类号： C08G18/08 ,  C08G18/40 ,  C08G18/54 ,  C08J3/07

    CPC分类号： C08G18/40 ,  C08G18/0876 ,  C08G18/409 ,  C08G18/54 ,  C08G2101/00

    摘要： A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.

    摘要翻译： 一种缩合树脂分散体的制造方法，其特征在于，使醛和可与醛缩合的化合物或其预缩合物在基本上由水和/或有机溶剂组成的分散介质中进行缩合反应，使细缩合树脂 几乎不沉淀在所述分散介质中的颗粒，然后用具有至少两个与异氰酸酯基团反应的活性氢基团的活性含氢化合物代替水和/或有机溶剂。

    Process for producing phenyl ester, and catalyst
    9.
    发明申请
    Process for producing phenyl ester, and catalyst 有权
    苯酯生产方法和催化剂

    公开(公告)号：US20050065363A1

    公开(公告)日：2005-03-24

    申请号：US10980238

    申请日：2004-11-04

    申请人： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

    发明人： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

    IPC分类号： C07C67/055 ,  C07C67/39

    CPC分类号： C07C67/055 ,  C07C69/017 ,  C07C69/157

    摘要： A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups IIIb, IVb, Vb and VIb of the periodic table, and (C) at least one element selected from elements of groups IIIa and IVa of the periodic table. Preferably, element (B) is selected from elements of group VIb of the periodic table, and element (C) is contained in a metal oxide form in the catalyst. The catalytic activity can be maintained at a high level, and a phenyl ester is stably produced. The phenyl ester can be converted to phenol by a conventional procedure.

    摘要翻译： 通过使苯，羧酸和分子氧在包含（A）钯，（B）选自IIIb，IVb，Vb族元素中的至少一种元素的催化剂存在下，使苯，羧酸和分子氧彼此反应来制备苯基酯， VIb，和（C）选自元素周期表IIIa和IVa族元素的至少一种元素。 优选地，元素（B）选自元素周期表VIb族的元素，元素（C）以催化剂中的金属氧化物形式包含。 可以将催化活性维持在高水平，并稳定地生产苯酯。 苯基酯可以通过常规方法转化成苯酚。

    Process for producing phenyl esters using palladium-based catalysts
    10.
    发明授权
    Process for producing phenyl esters using palladium-based catalysts 有权
    使用钯基催化剂生产苯基酯的方法

    公开(公告)号：US06528679B1

    公开(公告)日：2003-03-04

    申请号：US09670268

    申请日：2000-09-27

    申请人： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

    发明人： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

    IPC分类号： C07C67055

    CPC分类号： C07C67/055 ,  C07C69/017 ,  C07C69/157

    摘要： A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups 13, 14, 15, and 16 and the fourth to sixth periods of the periodic table, and (C) at least one element selected from elements of groups 3, 4 and lanthanoid elements of the periodic table. Preferably, element (B) is selected from elements of group 16 and the fourth to sixth periods of the periodic table, and element (C) is contained in a metal oxide form in the catalyst. The phenyl ester can be converted to phenol by hydrolysis or ester exchange.

    摘要翻译： 通过使苯，羧酸和分子氧在催化剂的存在下反应来制备苯酯，所述催化剂包含（A）钯，（B）至少一种选自组13,14,15， 周期表的16和第四至第六周期，以及（C）选自元素周期表中的第3,4族和镧系元素的元素中的至少一种元素。 优选地，元素（B）选自元素周期表第16族元素和第四至第六元素元素，元素（C）以催化剂中的金属氧化物形式包含。 苯基酯可以通过水解或酯交换转化成苯酚。