摘要:
A method of manufacturing shaped articles of cross-linked poly-.alpha.-olefin composition by irradiation of electron beam which comprises the steps of blending a poly-.alpha.-olefin with a compound miscible therewith which is expressed by the general formula:X--Ym(where X is a group free from acetylenic linkage, Y is a group containing acetylenic linkage and m is an integer of 1 or over) and tetrakis-[methylene-(3,5-di-t-butyl-4-hydroxy-hydrocinnamate)]-methane; molding the blended mass into a desired shape; and cross-linking said shaped articles by irradiation of electron beam.
摘要:
A method of manufacturing an electric wire or cable having an improved rubber or plastic insulation layer which has the maximum wall thickness of beam penetration of 4mm or over and whose properties are improved by irradiation with an electron beam, wherein the wire or cable runs under the scanner of an electron beam accelerator while being rotated about the axis of the wire or cable at such a speed as causes the same portion of the wire or cable to be irradiated with the electron beam at least twice during a period of less than 10 seconds; and the electron beam accelerator directs on the insulation layer of the wire or cable an electron beam which is accelerated to an energy of 1 MeV or over and whose maximum penetration range in the said insulation layer is larger than its thickness.
摘要:
An improved process for cross-linking a shaped polyethylene is herein disclosed comprising irradiating it with electron beams using 0.2 to 2 parts by weight of amine alone or in combination with 0.2 to 1.0 part by weight of alcohol for 100 parts by weight of polyethylene to thereby improve the electrical, mechanical, thermal and other characteristics of the polyethylene.
摘要:
A polymer composition is herein disclosed, which consists essentially of:(A) 90 to 50 wt % of a saturated polymer having in one molecule (1) at least two groups of at least one type selected from the group consisting of an epoxy group of the formula ##STR1## (R is hydrogen or methyl), an alcoholic or phenolic hydroxyl group and an alkoxymethyl-substituted acid amide group of the formula ##STR2## (R is an alkyl group of C.sub.1 to C.sub.4) and (2) a repeating unit made of a nonaromatic methylene group or methine group; and(B) 50 to 10 wt % of a nonfunctional radical polymerizable monomer mixture consisting of (a) a radical polymerizable monomer having in one molecule at least one functional group selected from the group consisting of a carboxyl group, an acid anhydride group, an alcoholic hydroxyl group, an alkoxymethyl-substituted acid amide group of the formula ##STR3## (R is an alkyl group of C.sub.1 to C.sub.4) and an amino group of the formula --NR.sub.1 R.sub.2 (R.sub.1 and R.sub.2 are each an alkyl group of C.sub.1 to C.sub.8) and an ethylenic double bond, and (b) a radical polymerizable monomer having one epoxy ring and one ethylenic double bond in one molecule.
摘要:
A self-curing modified epoxy resin composition produced by irradiating with electron beams a mixture of an epoxy resin, a quaternary salt of .alpha.,.beta.-unsaturated carboxylic acid ester having one quaternized amine nitrogen in the ester group, and optionally a monomer having one ethylenically unsaturated bond in the molecule, as well as an aqueous dispersion of such resin composition is herein disclosed.
摘要:
A self-curing epoxy resin composition is, herein, disclosed produced by irradiating with an electron beam a mixture of 85 to 97 wt % of an epoxy resin and 3 to 15 wt % of a quaternary alkyl ammonium salt of .alpha.,.beta.-unsaturated carboxylic acid or a neutralized product of an .alpha.,.beta.-unsaturated carboxylic acid and a tertiary amine.
摘要:
A cured polyester resin product is obtained by curing a substrate which was treated with a liquid unsaturated polyester resin composition containing an ethylenically unsaturated monomer having at least one epoxy group and was covered with a saturated polyester resin film, the surface of the polyester film having been activated. The cured product has improved resistance to chemicals and weathering and the like.
摘要:
A process for curing a radiation curable composition consisting essentially of (a) an amide represented by the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are defined hereinbelow, and (b) an unsaturated polyester resin by irradiating the composition with an ionizing radiation.
摘要:
A fiber reinforced plastic (FRP) flat plate having no warps is continuously prepared by curing a continuous FRP plate molding material both top and back surfaces of which are covered with film-like sheetings by means of an ionizing radiation. In the process, the FRP molding material is continuously transported in lengthwise direction, and tensions are given to said film-like sheetings in both lengthwise and widthwise directions before and in the course of the irradiation.
摘要:
Radiation-curing reaction of a radiation-curable resin such as an unsaturated polyester resin is promoted by using a combination of an ionizing radiation and a substantial amount of an adding material.