摘要:
A composition is disclosed which is particularly suited for use in extrusion coating. The composition comprises a polymeric material having a rheology such that the slope S of a natural log-natural log plot of loss modulus (or G″) versus storage modulus (or G′) is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.
摘要:
A blend which comprises; A) a heterogeneous or homogenous linear ethylene homopolymer or interpolymer; B) a branched homopolymer or interpolymer; wherein said blend has; 1) a melt index, I2, of about 0.05 to about 20 g/10 min; 2) a flexural modulus of ≧100,000 psi or ≦30,000 psi; 3) a melt strength of ≧2 cN; 4) a melt extensibility of ≧25 mm/sec; and 5) wherein said melt strength of said blend meets the following relationship; Melt strength≧FMS*[(f*A)+((1−f)*B)]; where: A=3.3814*(I2)−06476 and B=16.882*(I2)−06564; where I2 is the measured melt index of the blend; f is the weight fraction of the linear polyethylene in the blend and FMS is ≧1.1. Also included in the present invention are foams, films, fibers, blow molded articles, wire and cable articles and extrusion coatings comprising said blend.
摘要:
A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要:
A polymer composition that has a backbone chain; and a plurality of long chain branches connected to the backbone is described. The polymer composition also has a value of 2g′LCB-1g′LCB g′2LCB-g′1LCB that is less than about 0.22, where 1g′LCB g′2LCB is the long chain branching index for a fraction of the composition having a Mw of 100,000 and 2g′LCB g′1LCB is the long chain branching index for a fraction of the composition having a Mw of 500,000.
摘要:
A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: M S ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: M S ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要:
A method for processing a substrate is provided; wherein the method comprises applying a film of a copolymer composition, comprising a poly(styrene)-b-poly(siloxane) block copolymer component; and, an antioxidant to a surface of the substrate; optionally, baking the film; annealing the film in a gaseous atmosphere containing ≧20 wt % oxygen; followed by a treatment of the annealed film to remove the poly(styrene) from the annealed film and to convert the poly(siloxane) in the annealed film to SiOx.
摘要:
A process of making a polymer is described. The process includes contacting one or more olefinic monomers in the presence of at least a high molecular weight (HMW) catalyst and at least a low molecular weight (LMW) catalyst in a polymerization reactor system; and effectuating the polymerization of the one or more olefinic monomers in the polymerization reactor system to obtain an olefin polymer, wherein the LMW catalyst has an RvL, defined as R v L = [ vinyl ] [ vinyl ] + [ vinylidene ] + [ cis ] + [ trans ] wherein [vinyl] is the concentration of vinyl groups in the olefin polymer produced by the low molecular weight catalyst expressed in vinyls/1,000 carbon atoms; [vinylidene], [cis] and [trans] are the concentration of vinylidene, cis and trans groups in the olefin polymer expressed in the number of the respective groups per 1,000 carbon atoms, of greater than 0.12, and wherein the HMW catalyst has a reactivity ratio, r1 of about 5 or less.
摘要翻译:描述制备聚合物的方法。 该方法包括在聚合反应器系统中在至少一种高分子量(HMW)催化剂和至少一种低分子量(LMW))催化剂的存在下使一种或多种烯属单体接触; 并且在聚合反应器体系中实现一种或多种烯烃单体的聚合以获得烯烃聚合物,其中LMW催化剂具有RvL,定义为R v L = [乙烯基] [乙烯基] + [亚乙烯基] + [顺式] + [反式]其中[乙烯基]是由以乙烯基/ 1,000个碳原子表示的低分子量催化剂制备的烯烃聚合物中乙烯基的浓度; [亚乙烯基],[顺式]和[反式]是烯烃聚合物中每1000个碳原子数目表示的亚乙烯基,顺式和反式基团的浓度大于0.12,并且其中HMW催化剂具有 反应性比例r1约为5或更小。
摘要:
A polymer composition that has a backbone chain; and a plurality of long chain branches connected to the backbone is described. The polymer composition also has a value of 2g′LCB-1g′LCB that is less than about 0.22, where 1g′LCB is the long chain branching index for a fraction of the composition having a Mw of 100,000 and 2g′LCB is the long chain branching index for a fraction of the composition having a Mw of 500,000.