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公开(公告)号：US08445621B2
公开(公告)日：2013-05-21
申请号：US12670965
申请日：2008-08-20
申请人： Tomoyasu Sunaga , Hiroki Kanaya , Mamiko Nomura , Junichi Ishii
发明人： Tomoyasu Sunaga , Hiroki Kanaya , Mamiko Nomura , Junichi Ishii
IPC分类号： C08G77/26
CPC分类号： G03F7/0757 , C08G73/1039 , C08G73/1046 , C08G73/1053 , C08G73/106 , C08G73/1064 , C08G73/14 , C08G77/455 , C08G77/70 , C08K5/0025 , C08K5/357 , C08L63/00 , C08L79/08 , C08L83/10 , G03F7/0387 , H05K3/287 , C08L2666/22
摘要： A novel polyimide resin is formed by imidizing a diamine component including an amide group-containing siloxane diamine compound represented by the following formula (1) and an acid dianhydride component including an aromatic acid dianhydride such as 3,3′,4,4′-diphenylsulfone tetracarboxylic dianhydride. This novel polyimide resin utilizes a novel polyimide resin into which a reaction group capable of reacting with a crosslinking agent to form a crosslinking point is pre-introduced before imidization. The novel polyimide resin can confer a comparatively low elastic modulus and heat resistance to a dry film or a photosensitive cover film formed from a photosensitive polyimide resin composition containing the novel polyimide resin. In the formula (1), R1 and R2 are each independently an optionally-substituted alkylene group, m denotes an integer of 1 to 30, and n denotes an integer of 0 to 20.
摘要翻译： 通过酰亚胺化包含由下式（1）表示的含酰胺基的硅氧烷二胺化合物的二胺组分和包含芳族酸二酐如3,3'，4,4'-二羧酸的酸二酐组分，形成新的聚酰亚胺树脂， 二苯砜四羧酸二酐。 该新颖的聚酰亚胺树脂利用新的聚酰亚胺树脂，其中在酰亚胺化之前预先引入可与交联剂反应形成交联点的反应基团。 新颖的聚酰亚胺树脂可以赋予由含有新型聚酰亚胺树脂的感光性聚酰亚胺树脂组合物形成的干膜或感光性覆盖膜的较低弹性模量和耐热性。 在式（1）中，R 1和R 2各自独立地为任选取代的亚烷基，m表示1〜30的整数，n表示0〜20的整数。
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公开(公告)号：US20100187001A1
公开(公告)日：2010-07-29
申请号：US12670965
申请日：2008-08-20
申请人： Tomoyasu Sunaga , Hiroki Kanaya , Mamiko Nomura , Junichi Ishii
发明人： Tomoyasu Sunaga , Hiroki Kanaya , Mamiko Nomura , Junichi Ishii
CPC分类号： G03F7/0757 , C08G73/1039 , C08G73/1046 , C08G73/1053 , C08G73/106 , C08G73/1064 , C08G73/14 , C08G77/455 , C08G77/70 , C08K5/0025 , C08K5/357 , C08L63/00 , C08L79/08 , C08L83/10 , G03F7/0387 , H05K3/287 , C08L2666/22
摘要： A novel polyimide resin is formed by imidizing a diamine component including an amide group-containing siloxane diamine compound represented by the following formula (1) and an acid dianhydride component including an aromatic acid dianhydride such as 3,3′,4,4′-diphenylsulfone tetracarboxylic dianhydride. This novel polyimide resin utilizes a novel polyimide resin into which a reaction group capable of reacting with a crosslinking agent to form a crosslinking point is pre-introduced before imidization. The novel polyimide resin can confer a comparatively low elastic modulus and heat resistance to a dry film or a photosensitive cover film formed from a photosensitive polyimide resin composition containing the novel polyimide resin. In the formula (1), R1 and R2 are each independently an optionally-substituted alkylene group, m denotes an integer of 1 to 30, and n denotes an integer of 0 to 20.
摘要翻译： 通过酰亚胺化包含由下式（1）表示的含酰胺基的硅氧烷二胺化合物的二胺组分和包含芳族酸二酐如3,3'，4,4'-二羧酸的酸二酐组分，形成新的聚酰亚胺树脂， 二苯砜四羧酸二酐。 该新颖的聚酰亚胺树脂利用新的聚酰亚胺树脂，其中在酰亚胺化之前预先引入可与交联剂反应形成交联点的反应基团。 新颖的聚酰亚胺树脂可以赋予由含有新型聚酰亚胺树脂的感光性聚酰亚胺树脂组合物形成的干膜或感光性覆盖膜的较低弹性模量和耐热性。 在式（1）中，R 1和R 2各自独立地为任选取代的亚烷基，m表示1〜30的整数，n表示0〜20的整数。
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3.发明授权Resin compositions, processes for preparing the resin compositions and processes for forming resin films 有权树脂组合物，树脂组合物的制备方法和树脂膜的形成方法公开(公告)号：US06927274B2
公开(公告)日：2005-08-09
申请号：US10693842
申请日：2003-10-24
IPC分类号： G03F7/037 , C08G73/10 , C08K5/00 , C08L79/08 , C09D5/00 , C09D179/08 , G03F7/022 , G03F7/023 , H01L21/027 , H05K3/46 , C08J3/28
CPC分类号： G03F7/022 , C08K5/0025 , G03F7/0233 , H05K3/4644 , C08L79/04
摘要： Polyimide precursors contained in resin compositions of the present invention have a polymer structure unit represented by formula (1) below: wherein chemical structure A2 includes an alicyclic compound but not an aromatic compound such as a benzene ring so that they provide excellent light transmission over a wide wavelength range. The polyimide precursors are imidized at 7.5% or more and 36% or less so that they are less soluble in developing solutions and therefore are not dissolved in the developing solutions at unexposed parts. Thus, the resin compositions of the present invention can be used to form a resin film having a precise pattern by exposure and development.
摘要翻译： 本发明的树脂组合物中所含的聚酰亚胺前体具有下述式（1）所示的聚合物结构单元：其中化学结构A 2包括脂环族化合物，但不包括苯环等芳香族化合物 它们在宽波长范围内提供优异的光透射。 聚酰亚胺前体在7.5％以上且36％以下被酰亚胺化，使得它们在显影液中的溶解性较差，因此在未曝光部分不溶解在显影液中。 因此，本发明的树脂组合物可用于通过曝光和显影形成具有精确图案的树脂膜。
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4.发明申请公开(公告)号：US20060022634A1
公开(公告)日：2006-02-02
申请号：US10519357
申请日：2003-12-19
申请人： Mamiko Nomura , Hiroshi Samukawa
发明人： Mamiko Nomura , Hiroshi Samukawa
IPC分类号： H02J7/00
CPC分类号： H01M10/052 , C09D175/16 , H01M2/022 , H01M2/1094 , H01M10/4235 , H01M2300/0085 , Y10T29/49115
摘要： A liquid-absorbent composition, which has a liquid-absorbent crosslinked resin that exhibits excellent absorption of the nonaqueous electrolyte of nonaqueous electrolyte secondary cells that constitute a nonaqueous electrolyte battery pack (and particularly a lithium ion nonaqueous electrolyte rechargeable battery pack), contains a powder of a liquid-absorbent crosslinked resin produced by crosslinking a methyl vinyl ether/maleic anhydride copolymer with a polyfunctional isocyanate compound, and a binder resin. Also, a liquid-absorbent sheet for a nonaqueous electrolyte battery pack contains supporting substrate and formed on one side of a supporting substrate a liquid-absorbent crosslinked resin layer, produced by crosslinking a methyl vinyl ether/maleic anhydride copolymer with a polyfunctional isocyanate compound. The nonaqueous electrolyte battery pack contains a battery case and disposed within the battery pack a nonaqueous electrolyte battery cell, a wiring circuit board, and an electrolyte absorption member formed from the liquid-absorbent sheet for absorbing electrolyte in the event that electrolyte leaks from the nonaqueous electrolyte battery cell.
摘要翻译： 构成非水电解质电池组（特别是锂离子非水电解质可充电电池组）的非水电解质二次电池非水电解液吸收性优异的吸液性交联树脂的吸液性组合物含有粉末 通过使甲基乙烯基醚/马来酸酐共聚物与多官能异氰酸酯化合物交联而制造的吸液性交联树脂和粘合剂树脂。 另外，非水电解质电池组用吸液片包含支撑基板，在支撑基板的一侧形成吸液性交联树脂层，其通过使甲基乙烯基醚/马来酸酐共聚物与多官能异氰酸酯化合物交联而制造。 非水电解质电池组包含电池壳体，并且在电池组中设置非水电解质电池单元，布线电路板和电解质吸收构件，所述非水电解质电池单元，布线电路板和电解质吸收构件由吸液片形成，用于在电解液从非水溶液泄漏的情况下吸收电解质 电解液电池。
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公开(公告)号：US20060172199A1
公开(公告)日：2006-08-03
申请号：US10553705
申请日：2004-04-01
CPC分类号： C08F290/061 , C08F290/06 , C08F290/065 , Y10T428/31504
摘要： A liquid absorbing sheet has a liquid-absorbing resin layer that can effectively absorb the nonaqueous electrolyte solution used in nonaqueous electrolyte secondary cells that make nonaqueous electrolyte battery packs (in particular, lithium ion-based nonaqueous secondary battery packs). The liquid-absorbing resin layer is obtained by irradiating a particular monomer composition with UV rays or other energy rays to polymerize the monomer composition. The monomer composition contains a monofunctional monomer component (A) having a polyethylene glycol acrylate monomer and an amide bond-containing acrylic monomer; and a polyfunctional monomer component (B).
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6.发明授权公开(公告)号：US07732078B2
公开(公告)日：2010-06-08
申请号：US10519357
申请日：2003-12-19
申请人： Mamiko Nomura , Hiroshi Samukawa
发明人： Mamiko Nomura , Hiroshi Samukawa
CPC分类号： H01M10/052 , C09D175/16 , H01M2/022 , H01M2/1094 , H01M10/4235 , H01M2300/0085 , Y10T29/49115
摘要： A liquid-absorbent composition, which has a liquid-absorbent crosslinked resin that exhibits excellent absorption of the nonaqueous electrolyte of nonaqueous electrolyte secondary cells that constitute a nonaqueous electrolyte battery pack (and particularly a lithium ion nonaqueous electrolyte rechargeable battery pack), contains a powder of a liquid-absorbent crosslinked resin produced by crosslinking a methyl vinyl ether/maleic anhydride copolymer with a polyfunctional isocyanate compound, and a binder resin. Also, a liquid-absorbent sheet for a nonaqueous electrolyte battery pack contains supporting substrate and formed on one side of a supporting substrate a liquid-absorbent crosslinked resin layer, produced by crosslinking a methyl vinyl ether/maleic anhydride copolymer with a polyfunctional isocyanate compound. The nonaqueous electrolyte battery pack contains a battery case and disposed within the battery pack a nonaqueous electrolyte battery cell, a wiring circuit board, and an electrolyte absorption member formed from the liquid-absorbent sheet for absorbing electrolyte in the event that electrolyte leaks from the nonaqueous electrolyte battery cell.
摘要翻译： 构成非水电解质电池组（特别是锂离子非水电解质可充电电池组）的非水电解质二次电池非水电解液吸收性优异的吸液性交联树脂的吸液性组合物含有粉末 通过使甲基乙烯基醚/马来酸酐共聚物与多官能异氰酸酯化合物交联而制造的吸液性交联树脂和粘合剂树脂。 另外，非水电解质电池组用吸液片包含支撑基板，在支撑基板的一侧形成吸液性交联树脂层，其通过使甲基乙烯基醚/马来酸酐共聚物与多官能异氰酸酯化合物交联而制造。 非水电解质电池组包含电池壳体，并且在电池组中设置非水电解质电池单元，布线电路板和电解质吸收构件，所述非水电解质电池单元，布线电路板和电解质吸收构件由吸液片形成，用于在电解液从非水溶液泄漏的情况下吸收电解质 电解液电池。
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公开(公告)号：US20090148776A1
公开(公告)日：2009-06-11
申请号：US12320769
申请日：2009-02-04
IPC分类号： H01M2/16
CPC分类号： C08F290/061 , C08F290/06 , C08F290/065 , Y10T428/31504
摘要： A liquid absorbing sheet has a liquid-absorbing resin layer that can effectively absorb the nonaqueous electrolyte solution used in nonaqueous electrolyte secondary cells that make nonaqueous electrolyte battery packs (in particular, lithium ion-based nonaqueous secondary battery packs). The liquid-absorbing resin layer is obtained by irradiating a particular monomer composition with UV rays or other energy rays to polymerize the monomer composition. The monomer composition contains a monofunctional monomer component (A) having a polyethylene glycol acrylate monomer and an amide bond-containing acrylic monomer; and a polyfunctional monomer component (B).
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公开(公告)号：US07510767B2
公开(公告)日：2009-03-31
申请号：US10553705
申请日：2004-04-01
IPC分类号： B32B9/04
CPC分类号： C08F290/061 , C08F290/06 , C08F290/065 , Y10T428/31504
摘要： A liquid absorbing sheet has a liquid-absorbing resin layer that can effectively absorb the nonaqueous electrolyte solution used in nonaqueous electrolyte secondary cells that make nonaqueous electrolyte battery packs (in particular, lithium ion-based nonaqueous secondary battery packs). The liquid-absorbing resin layer is obtained by irradiating a particular monomer composition with UV rays or other energy rays to polymerize the monomer composition. The monomer composition contains a monofunctional monomer component (A) having a polyethylene glycol acrylate monomer and an amide bond-containing acrylic monomer; and a polyfunctional monomer component (B).
摘要翻译： 液体吸收片具有能够有效吸收非水电解质二次电池中使用的非水电解质电池的液体吸收性树脂层，该非水电解质二次电池是非水电解质电池组（特别是锂离子型非水系二次电池组）。 液体吸收性树脂层通过用紫外线或其他能量射线照射特定的单体组合物来聚合单体组合物而获得。 单体组合物含有具有聚乙二醇丙烯酸酯单体和含酰胺键的丙烯酸单体的单官能单体组分（A） 和多官能单体组分（B）。
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公开(公告)号：US07592119B2
公开(公告)日：2009-09-22
申请号：US12226822
申请日：2008-01-23
申请人： Mamiko Nomura
发明人： Mamiko Nomura
CPC分类号： G03F7/0233 , C08G73/1042 , C08G73/1046 , C08G73/105 , C08G73/106 , C08G73/1067 , C08G73/1071 , C08G73/1082 , C08G73/16 , C08L61/28 , C08L79/08 , G03F7/0226 , G03F7/40 , H05K1/0393 , H05K3/287 , H05K2201/0154 , C08L2666/20 , C08L2666/16
摘要： The developability of a photosensitive polyimide resin composition with a weakly alkaline aqueous solution is improved without reduction in the solubility in general-purpose organic solvents even when a part of the diamine component is replaced with a diaminopolysiloxane-based compound or a bis(aminobenzoate)-based compound in order to reduce the warpage characteristics of the photosensitive polyimide resin composition by reducing its modulus of elasticity. The photosensitive polyimide resin composition is capable of being developed in a positive manner with a weakly alkaline aqueous solution and is soluble in an organic solvent. The photosensitive polyimide resin composition contains: a polyimide resin including a polyimide unit represented by formula (1) and a polyimide unit represented by one of formulas (2) and (3); an analogue of melamine cyanurate; and an analogue of diazonaphthoquinone. The amount of the analogue of melamine cyanurate is in the range of from 5 to 50 parts by weight with respect to 100 parts by weight of the polyimide resin.
摘要翻译： 即使当二胺组分的一部分被二氨基聚硅氧烷类化合物或双（氨基苯甲酸酯）化合物代替时，改善了具有弱碱性水溶液的光敏聚酰亚胺树脂组合物的显影性，而不降低在通用有机溶剂中的溶解度。 以通过降低其弹性模量来降低感光性聚酰亚胺树脂组合物的翘曲特性。 感光性聚酰亚胺树脂组合物能够用弱碱性水溶液以阳性方式显影，并且可溶于有机溶剂。 感光性聚酰亚胺树脂组合物含有：由式（1）表示的聚酰亚胺单元和由式（2）和（3）之一表示的聚酰亚胺单元的聚酰亚胺树脂; 氰尿酸三聚氰胺的类似物; 和类似的重氮萘醌。 氰尿酸三聚氰胺的类似物的量相对于100重量份的聚酰亚胺树脂为5〜50重量份。
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公开(公告)号：US20090075198A1
公开(公告)日：2009-03-19
申请号：US12226822
申请日：2008-01-23
申请人： Mamiko Nomura
发明人： Mamiko Nomura
CPC分类号： G03F7/0233 , C08G73/1042 , C08G73/1046 , C08G73/105 , C08G73/106 , C08G73/1067 , C08G73/1071 , C08G73/1082 , C08G73/16 , C08L61/28 , C08L79/08 , G03F7/0226 , G03F7/40 , H05K1/0393 , H05K3/287 , H05K2201/0154 , C08L2666/20 , C08L2666/16
摘要： The developability of a photosensitive polyimide resin composition with a weakly alkaline aqueous solution is improved without reduction in the solubility in general-purpose organic solvents even when a part of the diamine component is replaced with a diaminopolysiloxane-based compound or a bis(aminobenzoate)-based compound in order to reduce the warpage characteristics of the photosensitive polyimide resin composition by reducing its modulus of elasticity. The photosensitive polyimide resin composition is capable of being developed in a positive manner with a weakly alkaline aqueous solution and is soluble in an organic solvent. The photosensitive polyimide resin composition contains: a polyimide resin including a polyimide unit represented by formula (1) and a polyimide unit represented by one of formulas (2) and (3); an analogue of melamine cyanurate; and an analogue of diazonaphthoquinone. The amount of the analogue of melamine cyanurate is in the range of from 5 to 50 parts by weight with respect to 100 parts by weight of the polyimide resin.
摘要翻译： 即使当二胺组分的一部分被二氨基聚硅氧烷类化合物或双（氨基苯甲酸酯）化合物代替时，改善了具有弱碱性水溶液的感光性聚酰亚胺树脂组合物的显影性，而不降低在通用有机溶剂中的溶解度。 以通过降低其弹性模量来降低感光性聚酰亚胺树脂组合物的翘曲特性。 感光性聚酰亚胺树脂组合物能够用弱碱性水溶液以阳性方式显影，并且可溶于有机溶剂。 感光性聚酰亚胺树脂组合物含有：由式（1）表示的聚酰亚胺单元和由式（2）和（3）之一表示的聚酰亚胺单元的聚酰亚胺树脂; 氰尿酸三聚氰胺的类似物; 和类似的重氮萘醌。 氰尿酸三聚氰胺的类似物的量相对于100重量份的聚酰亚胺树脂为5〜50重量份。
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