公开(公告)号：US5743951A

公开(公告)日：1998-04-28

申请号：US688897

申请日：1996-07-31

申请人： Toshiyuki Ozai ,  Masatoshi Miyake ,  Shinichi Sato ,  Keisuke Imai ,  Masaharu Sato

发明人： Toshiyuki Ozai ,  Masatoshi Miyake ,  Shinichi Sato ,  Keisuke Imai ,  Masaharu Sato

IPC分类号： C09J5/02 ,  C08K5/5455 ,  C09D4/00 ,  C09D5/00 ,  C09D183/04 ,  C09D183/08 ,  C09J11/00 ,  C09J183/08 ,  C09D183/06

CPC分类号： C08K5/5455 ,  C09D183/04 ,  C09D4/00

摘要： A primer composition comprises (A) an organosilicon compound of the general formula (1) ##STR1## wherein R represents an alkylene group having from 1 to 6 carbon atoms, R.sup.1 represents a divalent hydrocarbon group having not less than 4 carbon atoms, R.sup.2 's may be the same or different and independently represent an unsubstituted or substituted monovalent hydrocarbon group, a is 0 or 1, and b is 0, 1, 2 or 3, and (B) a catalyst for condensation of the organosilicon compound and (C) an organopolysiloxane resin.

摘要翻译： 底漆组合物包含（A）通式（1）的有机硅化合物其中R表示具有1至6个碳原子的亚烷基，R 1表示不少于4个碳原子的二价烃基 R2可以相同或不同，独立地表示未取代或取代的单价烃基，a为0或1，b为0,1,2或3，（B）有机硅化合物的缩合催化剂和（ C）有机聚硅氧烷树脂。

公开(公告)号：US07875695B2

公开(公告)日：2011-01-25

申请号：US12251252

申请日：2008-10-14

申请人： Hiroshi Kamohara ,  Toshiyuki Ozai ,  Hideki Sugahara

发明人： Hiroshi Kamohara ,  Toshiyuki Ozai ,  Hideki Sugahara

IPC分类号： C08G77/20

CPC分类号： A61K6/10 ,  C08L83/04

摘要： A hydrophilic organopolysiloxane composition of the hydrosilylation reaction cure type for use as dental impression material is characterized by comprising as essential components (A) a diorganopolysiloxane having at least 0.1 silicon-bonded alkenyl group in a molecule, (B) a liquid or solid organopolysiloxane having average compositional formula (1), comprising SiO2 units and R3SiO1/2 units (R is a monovalent hydrocarbon, alkoxy or hydroxyl group) and having a viscosity of at least 10 mPa-s at 23° C., (C) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule, (D) a hydrosilylation catalyst, and (E) a polyether having average compositional formula (2).

摘要翻译： 用作牙印模材料的氢化硅烷化反应固化型的亲水性有机聚硅氧烷组合物的特征在于包含作为必需组分（A）在分子中具有至少0.1个硅键合的烯基的二有机聚硅氧烷，（B）具有 平均组成式（1），其包含SiO 2单元和R 3 SiO 1/2单元（R是单价烃，烷氧基或羟基），并且在23℃具有至少10mPa·s的粘度，（C）有机氢聚硅氧烷， 分子中至少两个硅键合的氢原子，（D）氢化硅烷化催化剂和（E）具有平均组成式（2）的聚醚。

公开(公告)号：US07737212B2

公开(公告)日：2010-06-15

申请号：US11439277

申请日：2006-05-24

申请人： Toshiyuki Ozai ,  Naoki Yamakawa

发明人： Toshiyuki Ozai ,  Naoki Yamakawa

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/045 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08L83/00

摘要： A heat conductive silicone composition is provided, which includes (A) an organopolysiloxane having the formula (1): {(CH2═CH)R12SiO1/2}L(R1SiO3/2)m(R12SiO)n{O1/2SiR12—R2—SiR1(3-a)(OR3)a}o  (1) wherein R1 represents monovalent hydrocarbon groups, R2 represents an oxygen atom or a bivalent hydrocarbon group, R3 represents an alkyl group, alkoxyalkyl group, alkenyl group, or acyl group, L and o represent numbers from 1 to 10, m represents a number from 0 to 10, n represents a number from 5 to 100, a represents an integer from 1 to 3, and when m=0, L+o=2 and R2 is a bivalent hydrocarbon group, (B) a heat conductive filler, and (C) an organopolysiloxane other than the component (A). Even upon high-level packing with the heat conductive filler to obtain a highly heat conductivity, the composition still exhibits favorable handling and moldability properties.

摘要翻译： 提供了一种导热硅氧烷组合物，其包括（A）具有式（1）的有机聚硅氧烷：{（CH 2 = CH）R 12 SiO 1/2/2）L（R 1 SiO 3/2）m（R 12 SiO）n {O 1 / 2SiR 12 -R 2 - SiR1（3-a）（OR3）a} o（1）其中R1表示一价烃基，R2表示氧原子或二价烃基，R3表示烷基，烷氧基烷基，烯基或酰基，L o表示1〜10的数，m表示0〜10的数，n表示5〜100的数，a表示1〜3的整数，m = 0时，L + o = 2，R2表示 二价烃基，（B）导热性填料，（C）除（A）成分以外的有机聚硅氧烷。 即使使用导热填料进行高级包装以获得高导热性，组合物仍然表现出良好的处理和成型性能。

公开(公告)号：US07563843B2

公开(公告)日：2009-07-21

申请号：US10438863

申请日：2003-05-16

申请人： Toshiyuki Ozai ,  Yoshifumi Inoue

发明人： Toshiyuki Ozai ,  Yoshifumi Inoue

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08K5/544 ,  C08L83/00

摘要： An amino compound having a secondary amino group directly bonded to a phenyl group is modified by silylating the secondary amino group. When the silylated amino compound is compounded in a silicone composition comprising an organopolysiloxane containing at least two lower alkenyl groups, an organohydrogenpolysiloxane, and a platinum base curing catalyst, the composition is improved in flame retardance to the level of UL-94 V-0 without sacrificing the activity of the curing catalyst.

摘要翻译： 具有与苯基直接键合的仲氨基的氨基化合物通过使仲氨基甲硅烷基化而被修饰。 当甲硅烷基化的氨基化合物在包含含有至少两个低级链烯基的有机聚硅氧烷，有机氢聚硅氧烷和铂基固化催化剂的硅氧烷组合物中配混时，该组合物的阻燃性提高到UL-94V-0的水平，而没有 牺牲固化催化剂的活性。

公开(公告)号：US20070287014A1

公开(公告)日：2007-12-13

申请号：US11808082

申请日：2007-06-06

申请人： Toshiyuki Ozai ,  Mitsuhiro Iwata

发明人： Toshiyuki Ozai ,  Mitsuhiro Iwata

IPC分类号： B32B9/04 ,  C08K3/40

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08K7/22 ,  Y10T428/24372 ,  Y10T428/24421 ,  Y10T428/31663 ,  C08L83/00

摘要： A liquid organopolysiloxane composition is provided. This composition can readily form a cured article having a matted surface without requiring separate step such as mechanical surface roughening, and this composition is well adapted for use as a potting material or a coating material in electric and electronic components such as LED. An article having a matted surface produced by curing such composition is also provided. The liquid organopolysiloxane composition for matting comprises (A) 100 parts by weight of a thermosetting liquid organopolysiloxane composition, and (B) 0.1 to 100 parts by weight of a hollow filler having a melting point of at least 150° C., a specific weight of 0.01 to 0.8, and a particle size of up to 200 μm. The composition has a viscosity at room temperature of 100 to 100,000 mPa·s. The resulting cured article has a surface glossiness of up to 40.

摘要翻译： 提供液体有机聚硅氧烷组合物。 该组合物可以容易地形成具有无光表面的固化制品，而不需要诸如机械表面粗糙化的单独步骤，并且该组合物很好地适用于诸如LED的电气和电子部件中的灌封材料或涂料。 还提供了通过固化该组合物制成的具有无光泽表面的制品。 用于消光的液体有机基聚硅氧烷组合物包含（A）100重量份的热固性液体有机基聚硅氧烷组合物，和（B）0.1至100重量份的熔点至少为150℃的中空填料， 为0.01〜0.8，粒径可达200​​μm。 该组合物在室温下具有100至100,000mPa.s的粘度。 所得到的固化制品的表面光泽度高达40。

公开(公告)号：US08293810B2

公开(公告)日：2012-10-23

申请号：US11212711

申请日：2005-08-29

申请人： Takashi Ito ,  Tsuneo Hagiwara ,  Toshiyuki Ozai ,  Takeshi Miyao

发明人： Takashi Ito ,  Tsuneo Hagiwara ,  Toshiyuki Ozai ,  Takeshi Miyao

IPC分类号： C08F283/12 ,  C08F2/50 ,  C08J3/28 ,  G03F7/031 ,  C08G77/04 ,  C08G77/20 ,  C08L83/07

CPC分类号： C08F283/12 ,  B33Y70/00 ,  C08L83/08 ,  C08L83/00

摘要： A resin composition suited for rapid prototyping is provided comprising (I) an actinic energy radiation-curable silicone composition, (II) an actinic energy radiation-sensitive polymerization initiator, and (III) an actinic energy radiation absorber. The resin composition experiences little viscosity buildup and maintains fluidity during long-term storage at elevated temperature, and is effective in rapid prototyping or shaping by stereolithography using any actinic energy radiation.

摘要翻译： 提供了适用于快速成型的树脂组合物，其包括（I）光化能辐射可固化硅氧烷组合物，（II）光化能辐射敏感聚合引发剂，和（III）光化能辐射吸收剂。 树脂组合物在高温下长时间储存​​期间几乎不产生粘度增加并保持流动性，并且通过使用任何光化能量辐射的立体光刻技术在快速成型或成型中是有效的。

公开(公告)号：US07915362B2

公开(公告)日：2011-03-29

申请号：US11859123

申请日：2007-09-21

申请人： Toshiyuki Ozai

发明人： Toshiyuki Ozai

IPC分类号： C08G77/20

CPC分类号： C09K3/1018 ,  C08K5/14 ,  C08L83/06 ,  C08L83/14 ,  H01L33/56 ,  C08L2666/34

摘要： Provided is a heat-curable silicone composition containing: (A) an organopolysiloxane having at least one structure represented by the following general formula (2) within each molecule: wherein m represents an integer of 0, 1 or 2, R1 represents a hydrogen atom, a phenyl group or a halogenated phenyl group, R2 represents a hydrogen atom or a methyl group, R3 represents an identical or different monovalent organic group having 1 to 10 carbon atoms, and R4 represents an identical or different bivalent organic group having 1 to 10 carbon atoms; and (B) a quantity of an organic peroxide that is effective as a curing catalyst. The heat-curable silicon composition yields a cured product having excellent transparency and minimal discoloration over time. Also provided is a light emitting diode element having a material composed of the cured product.

摘要翻译： 本发明提供一种可热固化的硅氧烷组合物，其含有：（A）在每个分子内具有至少一个由以下通式（2）表示的结构的有机聚硅氧烷：其中m表示0,1或2的整数，R 1表示氢原子 ，苯基或卤代苯基，R 2表示氢原子或甲基，R 3表示相同或不同的具有1〜10个碳原子的一价有机基团，R 4表示相同或不同的1价〜10元的有机基团 碳原子 和（B）一定量的作为固化催化剂有效的有机过氧化物。 可热固化的硅组合物产生具有优异透明度和随时间变化最小的固化产物。 还提供了具有由固化产物组成的材料的发光二极管元件。

公开(公告)号：US07456246B2

公开(公告)日：2008-11-25

申请号：US10724221

申请日：2003-12-01

申请人： Hiroshi Kamohara ,  Toshiyuki Ozai

发明人： Hiroshi Kamohara ,  Toshiyuki Ozai

IPC分类号： C08G77/12 ,  C08G77/14 ,  C08G77/20

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/44 ,  C08G77/70 ,  C08G77/80 ,  C08L71/02 ,  C08L2666/22

摘要： A hydrophilic polyorganosiloxane composition comprising (A) a curable organopolysiloxane containing at least 5 mol % of diphenylsiloxane units or at least 10 mol % of methylphenylsiloxane units, (B) a curing agent, and (C) a specific polyether cures into an elastomeric or gel-like silicone product having excellent hydrophilic properties and prevents separation of the polyether over time.

摘要翻译： 亲水性聚有机硅氧烷组合物，其包含（A）含有至少5摩尔％的二苯基硅氧烷单元或至少10摩尔％的甲基苯基硅氧烷单元的可固化的有机聚硅氧烷，（B）固化剂，和（C）特定聚醚固化成弹性体或凝胶 类硅氧烷产品具有优异的亲水性，并防止聚醚随时间分离。

公开(公告)号：US20050101791A1

公开(公告)日：2005-05-12

申请号：US11015024

申请日：2004-12-20

申请人： Toshiyuki Ozai ,  Hiroyasu Hara ,  Yoshifumi Inoue ,  Tomoyuki Goto

发明人： Toshiyuki Ozai ,  Hiroyasu Hara ,  Yoshifumi Inoue ,  Tomoyuki Goto

IPC分类号： C07F7/08 ,  C07F7/18

CPC分类号： C07F7/1804

摘要： An organosilicon compound represented by the following general formula (1): wherein R1 is a hydrogen atom, a phenyl group or a halogenated phenyl group; R2 is a hydrogen atom or a methyl group; R3's are each a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms; X is a hydrolyzable group; Z1 is —R4—, —R4O— or —R4(CH3)2SiO—, where R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; Z2 is an oxygen atom or a substituted or unsubstituted divalent hydrocarbon group having 1 to 10 carbon atoms; and m is 0, 1 or 2 and n is 0, 1 or 2. When incorporated in silicone compositions, the organosilicon compound acts as a cross-linking agent having well-balanced photopolymerizability and condensation curability.

摘要翻译： 由以下通式（1）表示的有机硅化合物：其中R 1是氢原子，苯基或卤代苯基; R 2是氢原子或甲基; R 3各自为取代或未取代的碳原子数为1〜10的一价烃基; X是可水解基团; Z 1是-R 4 - ， - R 4 O-或-R 4（CH 3） 3 SiO 2，其中R 4是取代或未取代的具有1至10个碳原子的二价烃基; Z 2是氧原子或取代或未取代的碳原子数为1〜10的二价烃基; 并且m为0,1或2，n为0,1或2.当掺入有机硅组合物中时，有机硅化合物用作具有良好平衡光聚合性和缩合固化性的交联剂。

公开(公告)号：US20080021190A1

公开(公告)日：2008-01-24

申请号：US11898900

申请日：2007-09-17

申请人： Atsushi Yaginuma ,  Toshiyuki Ozai ,  Toshio Yamazaki ,  Masayuki Yoshida

发明人： Atsushi Yaginuma ,  Toshiyuki Ozai ,  Toshio Yamazaki ,  Masayuki Yoshida

IPC分类号： C09D183/05 ,  C09D183/06

CPC分类号： C08K5/5455 ,  Y10T428/31663 ,  C08L83/04

摘要： A silicone rubber coating composition comprising (A) a diorganopolysiloxane containing an average of at least two alkenyl groups, (B) silica powder having a specific surface area of at least 50 m2/g, (C) an organosilicon compound containing a ureido group, an isocyanuric acid ester modified with an organosilicon compound or a (partial) hydrolytic condensate thereof, and (D) a curing agent is applied and vulcanized to base fabric to form a coated fabric, from which airbags are prepared. The composition has a sufficient adhesion to withstand high temperature and abrupt elongation upon inflation of the airbag even after long-term storage under hot humid conditions.

摘要翻译： 一种硅橡胶涂料组合物，其包含（A）含有平均至少两个烯基的二有机聚硅氧烷，（B）比表面积至少为50m 2 / g的二氧化硅粉末，（C） 含有脲基的有机硅化合物，用有机硅化合物改性的异氰脲酸酯或其（部分）水解缩合物）和（D）固化剂，并将其硫化成基础织物，形成涂布织物，气囊为 准备 该组合物具有足够的粘附性，即使在热潮湿条件下长期储存后，气囊充气时也能承受高温和突然伸长。