Process for the preparation of hydrocarbons
    1.
    发明授权
    Process for the preparation of hydrocarbons 失效
    烃类制备方法

    公开(公告)号:US5936135A

    公开(公告)日:1999-08-10

    申请号:US917347

    申请日:1997-08-26

    IPC分类号: C07C2/00 C07C2/52 C07C15/00

    摘要: The present invention describes a process for the conversion of a lower alkane or a mixture of lower alkanes or a feed containing lower alkane(s) to aromatics or higher hydrocarbons, which comprises (i) treating a bifunctional pentasil zeolite catalyst, optionally containing one or more transition elements, having strong dehydrogenation and acid sites with a mixture of H.sub.2, steam and optionally the presence of an inert gas at a gas hourly space velocity of at least about 500 cm.sup.3 g.sup.-1 h.sup.-1 at a temperature in the range of 400.degree.-800.degree. C. and pressure in the range of 1-5 atm. for a period of at least 0.5 h; (ii) treating the catalyst obtained in step (i) with air or O.sub.2 at a gas hourly space velocity of at least about 200 cm.sup.3 g.sup.-1 h.sup.-1) at a temperature in the range of 400-800.degree. C. and pressure in the range of 1-5 atm for a period of at least 0.2 h, and (iii) contacting the catalyst obtained in step (ii) with a lower alkane or mixture of lower alkanes and at least one olefin or at least one higher paraffin or both, at a gas hourly space velocity in the range of 1000-100000 cm.sup.3 g.sup.-1 h.sup.-1 at a temperature in the range of 300.degree.-600.degree. C. and pressure in the range of 1-5 atm, (iv) separating the aromatics formed from the reaction mixture by known methods and if desired, (v) recycling the unconverted lower alkanes and non-aromatics to step (iii) for further conversion.

    摘要翻译: 本发明描述了将低级烷烃或低级烷烃或含低级烷烃的进料的混合物转化为芳烃或高级烃的方法,其包括(i)处理双官能五硅烷沸石催化剂,任选地含有一种或多种 更多的过渡元素,具有H2和蒸汽的混合物的强脱氢和酸性位点,并且任选存在的惰性气体的气体时间空间速度为至少约500cm 3 g-1 h -1,其温度范围为 400°-800℃,压力范围为1-5atm。 至少0.5小时; (ii)在400-800℃的温度范围内以空气或O 2以至少约200cm 3 g-1 h-1的气时空速处理所述步骤(i)中获得的催化剂和压力 在1-5atm的范围内至少0.2h的时间,和(iii)使步骤(ii)中获得的催化剂与低级烷烃或低级烷烃和至少一种烯烃或至少一种较高级链烷烃 或二者在300〜600℃的温度范围内的气时空速为1000-100000cm 3 g-1h-1,压力为1-5atm,(iv )通过已知方法分离由反应混合物形成的芳族化合物,如果需要,(v)将未转化的低级烷烃和非芳族化合物再循环到步骤(iii)以进一步转化。

    Methodology to determine feed quality (di+ring aromatic content) of FCC and hydrocracking feeds
    5.
    发明授权
    Methodology to determine feed quality (di+ring aromatic content) of FCC and hydrocracking feeds 有权
    确定FCC和加氢裂化进料的进料质量(二环芳烃含量)的方法

    公开(公告)号:US08992766B2

    公开(公告)日:2015-03-31

    申请号:US13163204

    申请日:2011-06-17

    摘要: A method of upgrading naphtha and diesel yields from fluid catalytic cracking and hydrocracking units by improving a feed quality of a petroleum feedstock, product or fraction mixture. The method of improving the feed quality of the petroleum feedstock, product or fraction mixture occurs by first determining the API Gravity of a petroleum feedstock, product or fraction mixture. A temperature at which about fifty percent of the petroleum feedstock, product or fraction boils (T50) is then determined. The feed quality for the petroleum feedstock, product or fraction mixture as determined from the API Gravity and the T50 for the feedstock, product or fraction mixture is then estimated followed by adjusting the petroleum feedstock, product or fraction mixture to achieve a higher feed quality.

    摘要翻译: 通过提高石油原料,产物或级分混合物的进料质量来提高来自流化催化裂化和加氢裂化装置的石脑油和柴油产率的方法。 通过首先确定石油原料,产物或级分混合物的API重力来改善石油原料,产物或级分混合物的进料质量的方法。 然后测定约50%的石油原料,产物或部分沸腾(T50)的温度。 然后估计从API Gravity和原料,产物或级分混合物的T50确定的石油原料,产物或级分混合物的进料质量,然后调整石油原料,产物或级分混合物以获得更高的进料质量。

    Upgrading Slurry Oil Using Chromatographic Reactor Systems
    6.
    发明申请
    Upgrading Slurry Oil Using Chromatographic Reactor Systems 审中-公开
    使用色谱反应器系统升级泥浆油

    公开(公告)号:US20100176029A1

    公开(公告)日:2010-07-15

    申请号:US12351391

    申请日:2009-01-09

    IPC分类号: C10G25/00 B01J19/00

    摘要: Methods and apparatus relate to reducing content of nitrogen-containing compounds within slurry oil using a chromatographic based assembly, which may not affect aromatic content, prior to feeding the slurry oil into a coking system. The slurry oil passes through the chromatographic based assembly to upgrade the slurry oil and make the slurry oil suitable for feedstock in making needle coke. Further, a hydrotreater utilized in combination with the chromatographic based assembly may provide additional upgrading of the slurry oil.

    摘要翻译: 方法和装置涉及在将浆料油进料到焦化系统之前,使用基于色谱的组件来降低浆料油中含氮化合物的含量,其可能不影响芳族成分。 浆料油通过基于色谱的组件以升级浆料油,并使浆料油适于制备针状焦炭的原料。 此外,与基于色谱的组合物组合使用的加氢处理器可以提供浆料油的额外升级。

    METHODOLOGY TO DETERMINE FEED QUALITY (DI+RING AROMATIC CONTENT) OF FCC AND HYDROCRACKING FEEDS
    9.
    发明申请
    METHODOLOGY TO DETERMINE FEED QUALITY (DI+RING AROMATIC CONTENT) OF FCC AND HYDROCRACKING FEEDS 有权
    FCC和加氢饲料测定饲料质量(DI + RING AROMATIC CONTENT)的方法

    公开(公告)号:US20110308996A1

    公开(公告)日:2011-12-22

    申请号:US13163204

    申请日:2011-06-17

    IPC分类号: C10G47/02

    摘要: A method of upgrading naphtha and diesel yields from fluid catalytic cracking and hydrocracking units by improving a feed quality of a petroleum feedstock, product or fraction mixture. The method of improving the feed quality of the petroleum feedstock, product or fraction mixture occurs by first determining the API Gravity of a petroleum feedstock, product or fraction mixture. A temperature at which about fifty percent of the petroleum feedstock, product or fraction boils (T50) is then determined. The feed quality for the petroleum feedstock, product or fraction mixture as determined from the API Gravity and the T50 for the feedstock, product or fraction mixture is then estimated followed by adjusting the petroleum feedstock, product or fraction mixture to achieve a higher feed quality.

    摘要翻译: 通过提高石油原料,产物或级分混合物的进料质量来提高来自流化催化裂化和加氢裂化装置的石脑油和柴油产率的方法。 通过首先确定石油原料,产物或级分混合物的API重力来改善石油原料,产物或级分混合物的进料质量的方法。 然后测定约50%的石油原料,产物或部分沸腾(T50)的温度。 然后估计从API Gravity和原料,产物或级分混合物的T50确定的石油原料,产物或级分混合物的进料质量,然后调整石油原料,产物或级分混合物以获得更高的进料质量。