公开(公告)号：US20160060539A1

公开(公告)日：2016-03-03

申请号：US14935429

申请日：2015-11-08

申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.

发明人： Dashan WANG ,  Dechen SONG ,  Qianqian LIU ,  Shenke ZHENG ,  Xiaodong ZHAN ,  Jiaqi JIN ,  Yanfeng ZHANG

IPC分类号： C10G3/00 ,  B01D17/04

CPC分类号： C10G3/49 ,  B01D17/047 ,  B01J29/088 ,  B01J29/405 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/42 ,  C10B53/02 ,  C10G11/18 ,  C10G33/04 ,  C10G2300/1011 ,  C10L1/02 ,  Y02E50/14 ,  Y02P30/20

摘要： A method for modifying bio-oil derived from biomass pyrolysis, the method including: 1) adding an inorganic salt and an organic demulsifier to a bio-oil; oscillating or stirring the resulting mixture, and resting the resulting mixture, to yield a lower layer being an aqueous solution and an upper layer being the bio-oil, and collecting the bio-oil; 2) employing a zeolite molecular sieve-loaded clay as a catalyst, and aging the catalyst using pure steam, to yield a modified catalyst; and 3) adding the modified catalyst obtained in 2) to a conventional catalytic cracking reactor, injecting the bio-oil obtained in 1) to the conventional catalytic cracking reactor using a piston pump, and allowing the bio-oil to react under a weight hourly space velocity (WHSV) of between 6 and 15 h−1, a temperature of between 380 and 700° C., and a pressure between 0.1 and 0.8 megapascal.

摘要翻译： 一种改性生物质热解生物油的方法，所述方法包括：1）向生物油中加入无机盐和有机破乳剂; 振荡或搅拌所得混合物，并静置所得混合物，得到作为生物油的水溶液和上层的下层，并收集生物油; 2）使用沸石分子筛负载的粘土作为催化剂，并使用纯蒸汽使催化剂老化，得到改性的催化剂; 和3）将常规催化裂解反应器中的2）中得到的改性催化剂加入到常规催化裂化反应器中，使用活塞泵将1）中得到的生物油注入到生物油中， 在6和15h-1之间的空间速度（WHSV），温度在380和700℃之间，压力在0.1和0.8兆帕之间。

公开(公告)号：US20170335202A1

公开(公告)日：2017-11-23

申请号：US15662310

申请日：2017-07-28

申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.

发明人： Yilong CHEN ,  Shenke ZHENG ,  Jiangang CHEN ,  Dechen SONG ,  Xiaodong ZHAN ,  Yanfeng ZHANG

IPC分类号： C10G2/00 ,  B01J23/75 ,  B01J31/02 ,  B01J37/00 ,  B01J23/745 ,  B01J35/00 ,  B01J35/12 ,  B01J37/04

CPC分类号： C10G2/332 ,  B01J23/462 ,  B01J23/745 ,  B01J23/75 ,  B01J23/889 ,  B01J31/02 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/12 ,  B01J37/0072 ,  B01J37/04 ,  B01J2231/62 ,  B01J2531/005 ,  C07C1/0435 ,  C07C2523/75 ,  C07C2523/89 ,  C10G2/00

摘要： A catalyst, including: a transition metal; and an organic solvent. The transition metal is dispersed in the organic solvent in the form of monodisperse nanoparticles; the transition metal has a grain size of between 1 and 100 nm; and the catalyst has a specific surface area of 5 and 300 m2/g. The invention also provides a method for preparing a catalyst, including: 1) dissolving an organic salt of a transition metal in an organic solvent including a polyhydric alcohol, to yield a mixture; and 2) heating and stirring the mixture in the presence of air or inert gas, holding the mixture at the temperature of between 150 and 250° C. for between 30 and 240 min, to yield the catalyst.

公开(公告)号：US20190193064A1

公开(公告)日：2019-06-27

申请号：US16288063

申请日：2019-02-27

申请人： WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.

发明人： Li GUO ,  Jiangang CHEN ,  Yanfeng ZHANG ,  Jiaqi JIN ,  Youliang SHI ,  Shenke ZHENG ,  Yan GONG

IPC分类号： B01J35/00 ,  C10G2/00 ,  B01J23/745 ,  B01J35/10 ,  B01J35/08

CPC分类号： B01J35/0006 ,  B01J23/745 ,  B01J35/0046 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1061 ,  B01J37/10 ,  C10G2/00 ,  C10G2/332 ,  C10G2300/70

摘要： A catalyst, including silica and iron. The silica is in the form of a mesoporous spherical particle. The iron is in the form of nanoparticles evenly distributed and encapsulated in the silica. The particle size of the silica is between 140 and 160 nm, and the silica includes pores between 2 and 9 nm in diameter.

公开(公告)号：US20170036198A1

公开(公告)日：2017-02-09

申请号：US15331925

申请日：2016-10-24

申请人： WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.

发明人： Shasha RAO ,  Dechen SONG ,  Qianqian LIU ,  Shenke ZHENG

IPC分类号： B01J31/02 ,  B01J21/08 ,  B01J35/00 ,  B01J35/10 ,  C10G2/00 ,  B01J33/00 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08 ,  B01J23/75 ,  B01J35/02

CPC分类号： B01J31/0274 ,  B01J21/08 ,  B01J23/75 ,  B01J33/00 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0244 ,  B01J37/088 ,  C10G2/00

摘要： A catalyst including cobalt, a carrier including silica, and a selective promoter including zirconium. The cobalt and the selective promoter are disposed on the surface of the carrier, and the outer surfaces of the active component cobalt and the selective promoter zirconium are coated with a shell layer including a mesoporous material. A method for preparing the catalyst, including: 1) soaking the carrier including silica into an aqueous solution including a zirconium salt, aging, drying, and calcining a resulting mixture to yield a zirconium-loaded carrier including silica; 2) soaking the zirconium-loaded carrier including silica into an aqueous solution including a cobalt salt, aging, drying, calcining a resulting mixture to yield a primary cobalt-based catalyst; 3) preparing a precursor solution of a mesoporous material; and 4) soaking the primary cobalt-based catalyst into the precursor solution of the mesoporous material; and crystalizing, washing, drying, and calcining a resulting mixture.

摘要翻译： 包括钴的催化剂，包含二氧化硅的载体和包含锆的选择性促进剂。 钴和选择性促进剂设置在载体的表面上，活性组分钴和选择性促进剂锆的外表面涂覆有包含介孔材料的壳层。 一种制备催化剂的方法，包括：1）将包含二氧化硅的载体浸入包含锆盐的水溶液中，老化，干燥和煅烧所得混合物，得到包含二氧化硅的负载锆的载体; 2）将包含二氧化硅的负载锆的载体浸入包括钴盐的水溶液中，老化，干燥，煅烧所得混合物，得到初级钴基催化剂; 3）制备介孔材料的前体溶液; 和4）将初级钴基催化剂浸入介孔材料的前体溶液中; 并对所得混合物进行结晶，洗涤，干燥和煅烧。