-
公开(公告)号：US20160060539A1
公开(公告)日：2016-03-03
申请号：US14935429
申请日：2015-11-08
发明人： Dashan WANG , Dechen SONG , Qianqian LIU , Shenke ZHENG , Xiaodong ZHAN , Jiaqi JIN , Yanfeng ZHANG
CPC分类号： C10G3/49 , B01D17/047 , B01J29/088 , B01J29/405 , B01J2229/186 , B01J2229/36 , B01J2229/42 , C10B53/02 , C10G11/18 , C10G33/04 , C10G2300/1011 , C10L1/02 , Y02E50/14 , Y02P30/20
摘要： A method for modifying bio-oil derived from biomass pyrolysis, the method including: 1) adding an inorganic salt and an organic demulsifier to a bio-oil; oscillating or stirring the resulting mixture, and resting the resulting mixture, to yield a lower layer being an aqueous solution and an upper layer being the bio-oil, and collecting the bio-oil; 2) employing a zeolite molecular sieve-loaded clay as a catalyst, and aging the catalyst using pure steam, to yield a modified catalyst; and 3) adding the modified catalyst obtained in 2) to a conventional catalytic cracking reactor, injecting the bio-oil obtained in 1) to the conventional catalytic cracking reactor using a piston pump, and allowing the bio-oil to react under a weight hourly space velocity (WHSV) of between 6 and 15 h−1, a temperature of between 380 and 700° C., and a pressure between 0.1 and 0.8 megapascal.
摘要翻译： 一种改性生物质热解生物油的方法，所述方法包括：1）向生物油中加入无机盐和有机破乳剂; 振荡或搅拌所得混合物，并静置所得混合物，得到作为生物油的水溶液和上层的下层，并收集生物油; 2）使用沸石分子筛负载的粘土作为催化剂，并使用纯蒸汽使催化剂老化，得到改性的催化剂; 和3）将常规催化裂解反应器中的2）中得到的改性催化剂加入到常规催化裂化反应器中，使用活塞泵将1）中得到的生物油注入到生物油中， 在6和15h-1之间的空间速度（WHSV），温度在380和700℃之间，压力在0.1和0.8兆帕之间。
-
2.发明申请METHOD FOR RECOVERING RUTHENIUM FROM SPENT RUTHENIUM-BASED CATALYST CARRIED ON ALUMINUM OXIDE 有权从载于氧化铝上的基于二氧化钛的催化剂回收钌的方法公开(公告)号：US20140373682A1
公开(公告)日：2014-12-25
申请号：US14479268
申请日：2014-09-05
发明人： Bo LAI , Li XU , Yiming HAN , Qianqian LIU , Dechen SONG
IPC分类号： C22B11/06
CPC分类号： C22B11/06 , C22B11/026 , C22B11/048 , Y02P10/214
摘要： A method for recovering ruthenium from a spent ruthenium-based catalyst carried on aluminum oxide includes: drying, calcining, and cooling a spent catalyst; grinding the spent catalyst into black powder; placing the black powder in a fluidized bed reactor, purging the reactor with hydrogen and heating the black powder to obtain ruthenium metal, then heating the black powder in a mixed atmosphere of oxygen and ozone to obtain RuO4 gas; absorbing the RuO4 gas with a sufficient amount of hydrochloric acid to obtain a H3RuCl6 solution; adding an excess oxidant to the H3RuCl6 solution to oxidize the H3RuCl6 into H2RuCl6; adding excess NH4Cl to the H2RuCl6 and then filtering, and washing the filter cake to obtain solid (NH4)2RuCl6; and reducing the solid (NH4)2RuCl6 by hydrogen to obtain ruthenium metal.
摘要翻译： 从氧化铝载带的废钌系催化剂中回收钌的方法包括：干燥，煅烧和冷却废催化剂; 将废催化剂研磨成黑色粉末; 将黑色粉末置于流化床反应器中，用氢气吹扫反应器并加热黑色粉末，得到钌金属，然后在氧气和臭氧的混合气氛中加热黑色粉末，得到RuO 4气体; 用足量的盐酸吸收RuO 4气体，得到H3RuCl6溶液; 向H3RuCl6溶液中加入过量氧化剂，将H3RuCl6氧化成H2RuCl6; 将过量的NH 4 Cl加入到H2RuCl6中，然后过滤，洗涤滤饼得到固体（NH 4）2 RuCl 6; 并用氢还原固体（NH 4）2 RuCl 6，得到钌金属。
-
3.发明申请CATALYST FOR FISCHER-TROPSCH SYNTHESIS AND METHOD FOR PREPARING THE SAME, AND METHOD FOR PREPARING MODIFIED MOLECULAR SIEVE CARRIER 审中-公开用于FISCHER-TROPSCH合成的催化剂及其制备方法，以及制备改性分子筛载体的方法公开(公告)号：US20160045903A1
公开(公告)日：2016-02-18
申请号：US14923404
申请日：2015-10-26
发明人： Weiguang YANG , Qianqian LIU , Dechen SONG , Changyuan LI , Xiaodong ZHAN , Jiaqi JIN , Yanfeng ZHANG
CPC分类号： B01J29/85 , B01J23/8892 , B01J29/005 , B01J29/0356 , B01J29/0358 , B01J29/072 , B01J29/405 , B01J29/46 , B01J29/48 , B01J29/7065 , B01J29/76 , B01J29/763 , B01J29/78 , B01J29/783 , B01J37/0201 , B01J37/0236 , B01J37/08 , B01J37/30 , B01J2229/186 , B01J2229/37 , C07C1/0445 , C07C2523/04 , C07C2523/08 , C07C2523/72 , C07C2523/745 , C07C2523/889 , C07C2529/035 , C07C2529/072 , C07C2529/076 , C07C2529/46 , C07C2529/48 , C07C2529/76 , C07C2529/78 , C07C2529/85 , C10G2/332 , C10G2/334 , C07C11/02
摘要： A catalyst, including a molecular sieve carrier and an active component. The active component includes: iron, manganese, copper, and a basic promoter potassium. The molecular sieve carrier is a cerium salt and/or praseodymium salt modified-aluminosilicate molecular sieve carrier and/or silica-rich molecular sieve carrier. A method for preparing a catalyst for Fischer-Tropsch synthesis, includes: 1) fully dissolving a ferric salt, a manganese salt, a copper salt, and an alkali or a salt containing potassium element in water to yield an aqueous solution, stirring and adding sodium lauryl sulfate to the aqueous solution, and continuing stirring to yield a uniform solution; and impregnating a modified molecular sieve in the uniform solution to yield a mixed solution; and 2) drying and calcining the mixed solution to yield the catalyst.
摘要翻译： 一种催化剂，包括分子筛载体和活性组分。 活性组分包括：铁，锰，铜和碱性促进剂钾。 分子筛载体是铈盐和/或镨盐改性的铝硅酸盐分子筛载体和/或富二氧化硅的分子筛载体。 一种制备费 - 托合成催化剂的方法，包括：1）将三价铁盐，锰盐，铜盐，碱金属或含钾元素的盐完全溶解于水中，得到水溶液，搅拌加入 十二烷基硫酸钠与水溶液反应，继续搅拌，得到均匀的溶液; 并在均匀溶液中浸渍改性分子筛，得到混合溶液; 和2）干燥和煅烧混合溶液以产生催化剂。
-
4.发明申请METHOD FOR PREPARATION OF HIGH PURITY,CRYSTALLINE COBALT NITRATE FROM SPENT COBALT/SILICA CATALYST 有权从苯乙烯/二氧化硅催化剂制备高纯度，结晶硝酸钴的方法公开(公告)号：US20140377153A1
公开(公告)日：2014-12-25
申请号：US14477909
申请日：2014-09-05
发明人： Yiming HAN , Qianqian LIU , Bo LAI , Li XU , Dechen SONG
IPC分类号： C22B3/00
CPC分类号： C22B23/0438 , C01G51/00 , C01G51/04 , C01P2006/80 , C07C51/412 , C22B1/005 , C22B3/0025 , C22B7/009 , Y02P10/214 , Y02P10/234 , C07C55/07
摘要： A method for preparing crystalline cobalt nitrate. The method includes: 1) calcining a spent Co/SiO2 catalyst, cooling the calcined material to room temperature, and grinding it to yield a powder; 2) heating the powder in a fluidized bed reactor; 3) adding the heated powder into excess dilute nitric acid solution and filtering to obtain a cobalt nitrate solution; 4) adjusting the pH value of the cobalt nitrate solution to 1.5, adding a preheated oxalic acid solution, adjusting a pH value of the resulting solution to 1.5, immediately filtering the resulting solution to yield a precipitate of cobalt oxalate, washing the precipitate of cobalt oxalate to yield a neutral filtrate; 5) drying the precipitate and calcining to yield cobalt oxide; 6) dissolving the cobalt oxide in nitric acid to yield a second cobalt nitrate solution; and 7) evaporating the second cobalt nitrate solution to obtain crystalline cobalt nitrate.
摘要翻译： 制备结晶硝酸钴的方法。 该方法包括：1）煅烧废弃的Co / SiO 2催化剂，将煅烧后的材料冷却至室温，并研磨，得到粉末; 2）在流化床反应器中加热粉末; 3）将加热的粉末加入过量的稀硝酸溶液中并过滤得到硝酸钴溶液; 4）将硝酸钴溶液的pH调节至1.5，加入预热的草酸溶液，将所得溶液的pH值调节至1.5，立即过滤所得溶液，得到草酸钴沉淀物，洗涤钴沉淀物 草酸盐，得到中性滤液; 5）干燥沉淀并煅烧产生氧化钴; 6）将氧化钴溶解在硝酸中以产生第二硝酸钴溶液; 和7）蒸发第二硝酸钴溶液以获得结晶硝酸钴。
-
5.发明申请公开(公告)号：US20170335202A1
公开(公告)日：2017-11-23
申请号：US15662310
申请日：2017-07-28
发明人： Yilong CHEN , Shenke ZHENG , Jiangang CHEN , Dechen SONG , Xiaodong ZHAN , Yanfeng ZHANG
IPC分类号： C10G2/00 , B01J23/75 , B01J31/02 , B01J37/00 , B01J23/745 , B01J35/00 , B01J35/12 , B01J37/04
CPC分类号： C10G2/332 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/889 , B01J31/02 , B01J35/0013 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/12 , B01J37/0072 , B01J37/04 , B01J2231/62 , B01J2531/005 , C07C1/0435 , C07C2523/75 , C07C2523/89 , C10G2/00
摘要： A catalyst, including: a transition metal; and an organic solvent. The transition metal is dispersed in the organic solvent in the form of monodisperse nanoparticles; the transition metal has a grain size of between 1 and 100 nm; and the catalyst has a specific surface area of 5 and 300 m2/g. The invention also provides a method for preparing a catalyst, including: 1) dissolving an organic salt of a transition metal in an organic solvent including a polyhydric alcohol, to yield a mixture; and 2) heating and stirring the mixture in the presence of air or inert gas, holding the mixture at the temperature of between 150 and 250° C. for between 30 and 240 min, to yield the catalyst.
-
6.发明申请IRON-BASED CATALYST, METHOD FOR PREPARING THE SAME, AND METHOD FOR PRODUCING ALPHA-OLEFINS USING THE SAME 审中-公开基于铁的催化剂，其制备方法和使用该方法生产α-烯烃的方法公开(公告)号：US20170037321A1
公开(公告)日：2017-02-09
申请号：US15299441
申请日：2016-10-20
发明人： Yilong CHEN , Yanfeng ZHANG , Jiangang CHEN , Dechen SONG , Juan ZHANG , Taomei SUN
IPC分类号： C10G2/00 , B01J23/889 , B01J23/75 , B01J23/745 , B01J23/86 , B01J23/80 , B01J23/89 , B01J23/78 , B01J21/08 , B01J35/00 , B01J35/08 , B01J37/04 , B01J37/02 , B01J37/00 , B01J37/08 , B01J23/83
CPC分类号： C10G2/332 , B01J21/08 , B01J23/745 , B01J23/75 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/86 , B01J23/862 , B01J23/889 , B01J23/8892 , B01J23/89 , B01J23/8906 , B01J35/0006 , B01J35/0013 , B01J35/08 , B01J37/009 , B01J37/0244 , B01J37/04 , B01J37/088 , C10G2/00 , C10G2/333
摘要： A catalyst including between 50.0 and 99.8 percent by weight of iron, between 0 and 5.0 percent by weight of a first additive, between 0 and 10 percent by weight of a second additive, and a carrier. The first additive is ruthenium, platinum, copper, cobalt, zinc, or a metal oxide thereof. The second additive is lanthanum oxide, cerium oxide, magnesium oxide, aluminum oxide, silicon dioxide, potassium oxide, manganese oxide, or zirconium oxide.
摘要翻译： 一种催化剂，其包含50.0至99.8重量％的铁，0至5.0重量％的第一添加剂，0至10重量％的第二添加剂和载体。 第一添加剂是钌，铂，铜，钴，锌或其金属氧化物。 第二添加剂是氧化镧，氧化铈，氧化镁，氧化铝，二氧化硅，氧化钾，氧化锰或氧化锆。
-
7.发明申请MONOLITHIC CATALYST COMPRISING MOLECULAR SIEVE MEMBRANE AND METHOD FOR PERPARING THE MONOLITHIC CATALYST 审中-公开包含分子筛膜的单晶催化剂和单晶催化剂的方法公开(公告)号：US20160288104A1
公开(公告)日：2016-10-06
申请号：US15186583
申请日：2016-06-20
发明人： Changyuan LI , Qianqian LIU , Dechen SONG , Weiguang YANG , Xiaodong ZHAN , Jiaqi JIN , Yanfeng ZHANG
CPC分类号： B01J23/894 , B01J29/0333 , B01J29/70 , B01J35/023 , B01J35/04 , B01J37/0217 , B01J37/0225 , B01J37/0242 , B01J37/0246 , B01J37/06 , B01J37/343 , B01J2229/66 , B01J2523/00 , C10G2/332 , C10G2/333 , C10G2/334 , B01J2523/3712 , B01J2523/828 , B01J2523/845
摘要： A monolithic catalyst, including cobalt, a metal matrix, a molecular sieve membrane, and an additive. The metal matrix is silver, gold, copper, platinum, titanium, molybdenum, iron, tin, or an alloy thereof. The molecular sieve membrane is mesoporous silica SBA-16 which is disposed on the surface of the metal matrix and is a carrier of the active component and the additive. The thickness of the carrier is between 26 and 67 μm. The additive is lanthanum, zirconium, cerium, rhodium, platinum, rhenium, ruthenium, titanium, magnesium, calcium, strontium, or a mixture thereof. A method for preparing the monolithic catalyst is also provided.
摘要翻译： 包括钴，金属基质，分子筛膜和添加剂的整体式催化剂。 金属基体是银，金，铜，铂，钛，钼，铁，锡或它们的合金。 分子筛膜是介孔二氧化硅SBA-16，其设置在金属基质的表面上，并且是活性组分和添加剂的载体。 载体的厚度在26和67μm之间。 添加剂是镧，锆，铈，铑，铂，铼，钌，钛，镁，钙，锶或它们的混合物。 还提供了制备整体式催化剂的方法。
-
8.发明申请CATALYST FOR PREPARING AVIATION FUEL FROM FISCHER-TROPSCH PRODUCTS AND METHOD FOR PREPARING SAID CATALYST 有权从FISCHER-TROPSCH产品制备航空燃料的催化剂和制备催化剂的方法公开(公告)号：US20170056867A1
公开(公告)日：2017-03-02
申请号：US15350132
申请日：2016-11-14
发明人： Wanwan WANG , Dechen SONG , Li XU
IPC分类号： B01J29/78 , B01J37/06 , C10G49/04 , B01J37/08 , B01J37/02 , B01J35/02 , B01J37/04 , B01J37/00
CPC分类号： B01J29/7884 , B01J29/076 , B01J29/48 , B01J35/002 , B01J35/026 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0018 , B01J37/009 , B01J37/02 , B01J37/0201 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/343 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/40 , B01J2229/42 , B01J2523/00 , C10G49/04 , C10G49/08 , C10G2300/1022 , C10G2300/1081 , B01J2523/68 , B01J2523/847
摘要： A catalyst for preparing aviation fuel from synthetic oil obtained by Fischer-Tropsch process, including: between 20 and 50 percent by weight of an amorphous aluminum silicate, between 5 and 20 percent by weight of alumina, between 20 and 60 percent by weight of a hydrothermally modified zeolite, between 0.5 and 1.0 percent by weight of a Sesbania powder, between 0.5 and 5 percent by weight of nickel oxide, and between 5 and 15 percent by weight of molybdenum oxide. The invention also provides a method for preparing the catalyst.
摘要翻译： 一种由费 - 托方法得到的合成油制备航空燃料的催化剂，包括：20-50重量％的无定形硅酸铝，5-20重量％氧化铝，20-60重量％ 水热改性沸石，0.5至1.0重量％的Sesbania粉末，0.5至5重量％的氧化镍和5至15重量％的氧化钼。 本发明还提供了一种制备催化剂的方法。
-
9.发明申请MESOPOROUS MATERIAL-COATED COBALT-BASED CATALYST FOR FISCHER-TROPSCH SYNTHESIS AND METHOD FOR PREPARING THE SAME 审中-公开用于FISCHER-TROPSCH合成的多孔材料涂覆的钴基催化剂及其制备方法公开(公告)号：US20170036198A1
公开(公告)日：2017-02-09
申请号：US15331925
申请日：2016-10-24
发明人： Shasha RAO , Dechen SONG , Qianqian LIU , Shenke ZHENG
IPC分类号： B01J31/02 , B01J21/08 , B01J35/00 , B01J35/10 , C10G2/00 , B01J33/00 , B01J37/02 , B01J37/00 , B01J37/08 , B01J23/75 , B01J35/02
CPC分类号： B01J31/0274 , B01J21/08 , B01J23/75 , B01J33/00 , B01J35/0006 , B01J35/0013 , B01J35/026 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0018 , B01J37/0244 , B01J37/088 , C10G2/00
摘要： A catalyst including cobalt, a carrier including silica, and a selective promoter including zirconium. The cobalt and the selective promoter are disposed on the surface of the carrier, and the outer surfaces of the active component cobalt and the selective promoter zirconium are coated with a shell layer including a mesoporous material. A method for preparing the catalyst, including: 1) soaking the carrier including silica into an aqueous solution including a zirconium salt, aging, drying, and calcining a resulting mixture to yield a zirconium-loaded carrier including silica; 2) soaking the zirconium-loaded carrier including silica into an aqueous solution including a cobalt salt, aging, drying, calcining a resulting mixture to yield a primary cobalt-based catalyst; 3) preparing a precursor solution of a mesoporous material; and 4) soaking the primary cobalt-based catalyst into the precursor solution of the mesoporous material; and crystalizing, washing, drying, and calcining a resulting mixture.
摘要翻译： 包括钴的催化剂，包含二氧化硅的载体和包含锆的选择性促进剂。 钴和选择性促进剂设置在载体的表面上，活性组分钴和选择性促进剂锆的外表面涂覆有包含介孔材料的壳层。 一种制备催化剂的方法，包括：1）将包含二氧化硅的载体浸入包含锆盐的水溶液中，老化，干燥和煅烧所得混合物，得到包含二氧化硅的负载锆的载体; 2）将包含二氧化硅的负载锆的载体浸入包括钴盐的水溶液中，老化，干燥，煅烧所得混合物，得到初级钴基催化剂; 3）制备介孔材料的前体溶液; 和4）将初级钴基催化剂浸入介孔材料的前体溶液中; 并对所得混合物进行结晶，洗涤，干燥和煅烧。
-
-
-
-
-
-
-
-
搜索结果
9 条记录 (耗时 0.017 秒)
