Rheology modification of low density polyethylene
    1.
    发明授权
    Rheology modification of low density polyethylene 有权
    低密度聚乙烯的流变改性

    公开(公告)号:US06521306B1

    公开(公告)日:2003-02-18

    申请号:US09129163

    申请日:1998-08-05

    IPC分类号: B29D2200

    摘要: The invention includes a process of preparing a coupled polymer characterized by heating an admixture containing (1) at least one ethylene polymer or blend of ethylene polymers having a density of at least about 0.89 g/mL and less than about 0.935 g/mL and a comonomer content between about 0.5 and 50 weight percent of an alpha olefin having greater than 2 and less than 20 carbon atoms per molecule and (2) a coupling amount of at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least about 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer. The amount of poly(sulfonyl azide) is preferably from about 0.01 to about 5 weight percent of polymers in the admixture. The invention also includes any composition which is the product of any of the processes of the invention and articles made from those compositions, particularly any film of any composition of the invention. Additionally the invention includes a use of any composition of the invention in a process of blowing, casting or calendaring a film. More particularly the invention includes articles of compositions of the invention which are trash bags, agricultural films, construction films, or geomembranes, grocery sacks, sealant layers, tie layers, produce bags, garment bags, shipping sacks, medical films, stretch films, shrink films, agricultural films, greenhouse films, construction films, or stretch hooders.

    摘要翻译: 本发明包括一种制备偶联聚合物的方法,其特征在于加热含有(1)至少一种乙烯聚合物或密度为至少约0.89g / mL且小于约0.935g / mL的乙烯聚合物的共混物的混合物, 共聚单体含量为约0.5至50重量%的每分子具有大于2个且小于20个碳原子的α-烯烃,和(2)至少一个聚(磺酰基叠氮化物)的偶联量至少达到聚 (磺酰基叠氮化物)足以分解至少约80重量%的聚(磺酰基叠氮化物)并足够导致偶联聚合物的时间。 聚(磺酰基叠氮化物)的量优选为混合物中约0.01至约5重量%的聚合物。 本发明还包括任何组合物,其是本发明任何方法的产物和由这些组合物制成的制品,特别是本发明任何组合物的任何薄膜。 此外,本发明包括在吹塑,浇铸或压延膜的方法中使用本发明的任何组合物。 更具体地,本发明包括本发明的制品,其为垃圾袋,农用膜,建筑膜或土工膜,杂货袋,密封剂层,连接层,生产袋,服装袋,运输袋,医疗膜,拉伸膜,收缩 电影,农膜,温室膜,建筑膜或拉伸罩。

    Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins
    5.
    发明申请
    Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins 有权
    由乙烯/α-烯烃的互聚物制成的粘合剂和标记组合物

    公开(公告)号:US20060199897A1

    公开(公告)日:2006-09-07

    申请号:US11376957

    申请日:2006-03-15

    IPC分类号: A61K9/16

    摘要: An adhesive composition comprises: (i) at least one ethylene/α-olefin interpolymer, (ii) at least one tackifier; and (iii) optionally at least one additive, such as a plasticizer, wax and antioxidant. Preferably, the ethylene/α-olefin interpolymer has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm≧858.91−1825.3(d)+1112.8(d)2. The composition has relatively higher SAFT temperature and can be used in hot melt adhesives pressure-sensitive adhesives, and thermoplastic marking paints.

    摘要翻译: 粘合剂组合物包含:(i)至少一种乙烯/α-烯烃互聚物,(ii)至少一种增粘剂; 和(iii)任选的至少一种添加剂,例如增塑剂,蜡和抗氧化剂。 优选地,乙烯/α-烯烃互聚物具有约1.7至约3.5的至少一个熔点T m, SUB>,以摄氏度表示,密度d(克/立方厘米),其中T m和d的数值对应于以下关系:T m = 858.91-1825.3(d)+1112.8(d)<2>。 该组合物具有相对较高的SAFT温度,并且可用于热熔粘合剂压敏粘合剂和热塑性标记涂料中。

    Interpolymers suitable for use in hot melt adhesives and processes to prepare same
    10.
    发明授权
    Interpolymers suitable for use in hot melt adhesives and processes to prepare same 有权
    适用于热熔胶粘剂的共聚物及其制备方法

    公开(公告)号:US07531601B2

    公开(公告)日:2009-05-12

    申请号:US10567142

    申请日:2004-09-17

    IPC分类号: C08L23/08

    摘要: The present invention relates to an ethylene/α-olefin interpolymer product comprising at least one α-olefin interpolymerized with ethylene and, characterized in at least one aspect, as having improved properties when utilized in a hot melt adhesive formulation. The invention also relates to a process for manufacturing the interpolymer product wherein the process comprises employing two or more single site catalyst systems in at least one reaction environment (or reactor) and wherein the at least two catalyst systems have (a) different comonomer incorporation capabilities or reactivities and/or (b) different termination kinetics, both when measured under the same polymerization conditions. The interpolymer products are useful, for example, in applications such as hot melt adhesives, and also for impact, bitumen and asphalt modification, adhesives, dispersions or latexes and fabricated articles such as, but not limited to, foams, films, sheet, moldings, thermoforms, profiles and fibers.

    摘要翻译: 本发明涉及一种包含至少一种与乙烯共聚的α-烯烃的乙烯/α-烯烃互聚物产品,其特征在于在至少一个方面当用于热熔粘合剂制剂时具有改进的性能。 本发明还涉及制备互聚物产物的方法,其中该方法包括在至少一个反应环境(或反应器)中采用两个或多个单中心催化剂体系,并且其中所述至少两个催化剂体系具有(a)不同的共聚单体掺入能力 或反应性和/或(b)不同的终止动力学,当在相同的聚合条件下测量时。 互聚物产品可用于例如热熔粘合剂,以及用于冲击,沥青和沥青改性,粘合剂,分散体或胶乳和制造的制品,例如但不限于泡沫,薄膜,片材,模制品 ,热成型,型材和纤维。