摘要:
Bisamides of the formula ##STR1## wherein R denotes the alkyl skeleton of a dimerized fatty acid having 22 to 42, preferably 34, C atoms, R.sub.1 denotes hydrogen or a group of the formula--(C.sub.n H.sub.2n --X).sub.a --Z.sub.v --R.sub.2,R.sub.2 denotes hydrogen or a group --COR.sub.3, R.sub.3 denotes C.sub.1 -C.sub.22 -, preferably C.sub.8 -C.sub.22 -alkyl, X denotes an oxygen atom or a group of the formula N--B.sub.m, B denotes hydrogen, methyl, ethyl, benzyl or a group of the formula --Z.sub.v --R.sub.2, n denotes a number from 2 to 6, preferably 2 or 3, a denotes a number from 0 to 5, v denotes a number from 0 to 100, preferably 0 to 20, Z denotes a group of the formula --C.sub.2 H.sub.4 X(C.sub.3 H.sub.6 X).sub.b or CH.sub.2 --CHY O or C.sub.n H.sub.2n, b denotes a number from 0 to 5, preferably 0, 1 or 2, i denotes a number from 0 to 2(a+b)+2 and A denotes an anion, m denotes a number from 1 to 2 and Y denotes hydrogen, methyl or ethyl, a process for their preparation and their use as demulsifiers for crude oil emulsions.
摘要翻译:其中R表示具有22至42个,优选34个C原子的二聚脂肪酸的烷基骨架,R1表示氢或式 - (C n H 2n-X)a-Zv-R 2的基团, R 2表示氢或基团-COR 3,R 3表示C 1 -C 22 - ,优选C 8 -C 22 - 烷基,X表示氧原子或式N-Bm基团,B表示氢,甲基,乙基,苄基或基团 式为-Zv-R2,n表示2〜6的数,优选为2或3,a表示0〜5的数,v表示0〜100的数,优选为0〜20,Z表示 式-C2H4X(C3H6X)b或CH2-CHYO或CnH2n,b表示0至5,优选0,1或2的数,i表示0至2(a + b)+2的数,A表示 阴离子,m表示1至2的数,Y表示氢,甲基或乙基,其制备方法及其用作原油乳液的破乳剂。
摘要:
New bisimidazolines of the formula ##STR1## wherein R denotes the alkyl skeleton of a dimerised fatty acid having 22 to 42, preferably 34, C atoms,X denotes an oxygen atom or a group of the formula >N--B.sub.m,B denotes hydrogen, methyl, ethyl, benzyl or a group of the formula --(CH.sub.2 CHYO).sub.n --R.sub.1,Y denotes hydrogen, methyl or ethyl,R.sub.1 denotes hydrogen or a group --COR.sub.2,R.sub.2 denotes C.sub.1 -C.sub.22, preferably C.sub.8 -C.sub.22, alkyl,a denotes 0 or 1, b denotes a number from 0 to 4, m denotes 1 or 2, n denotes a number from 0 to 100, preferably 0 to 20, i denotes a number from 0 to 2b+2 and A denotes an anion.A process for their preparation and their use a demulsifiers for crude petroleum emulsions.
摘要:
Polyether polyamines of the formula 1 ##STR1## in which R.sub.1 and R.sub.2 are identical or different and denote C.sub.8 -C.sub.30 -alkyl, -2-hydroxyalkyl or -alkenyl or C.sub.8 -C.sub.24 -alkoxypropyl, m and n are 2 or 3, R.sub.3 is hydrogen or methyl and the sum of o+p+q+r is an integer from 4 to 600, process for their manufacture and their use as dispersing agents, corrosion inhibitors, demulsifiers and acid retarders.
摘要:
Guanidiunium salts of the formula 1 ##STR1## in which R.sub.1 and R.sub.2 are identical or different and denote alkyl, 2-hydroxyalkyl or alkenyl each having from 8 to 18 carbon atoms, or C.sub.8 -C.sub.18 alkoxypropyl, m and n are 2 or 3, a is a number from 1 to 4 and A denotes an anion, process for their manufacture and their use as microbiocidal agents.
摘要:
Thus, the invention relates to compounds of the formula I ##STR1## where R is aromatic, preferably phenylene, R.sub.1 and R.sub.2 denote C.sub.1 -C.sub.4 -alkyl, preferably C.sub.1 -C.sub.2 -alkyl, R.sub.3 denotes methyl or ethyl, x and z together denote a number from 2 to 360, preferably from 2 to 140, y denotes a number from 15 to 70, preferably 25 to 60, n denotes a number from 1 to 10 and A.sup.- denotes an anion, preferably chloride or bromide, a process for their preparation and their use as demulsifiers for demulsifying crude oil emulsions and as corrosion inhibitors in equipment for lifting and processing natural gas and crude oil.
摘要:
Oxyalkylated addition products from ethylene oxide-propylene oxide block polymers and bis-glycidyl ethers, obtained by the addition of ethylene oxide-propylene oxide block polymers of the formula ##STR1## wherein R denotes methyl or ethyl, n and m are numbers which are so chosen that the content of polyethylene oxide groups is 5 to 80% of the molecular weight of the block polymer, and p is a number larger than 10, to bis-glycidyl ethers of the formula ##STR2## wherein the R.sup.1 's can be identical or different and denote hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, in particular chlorine, A denotes a direct bond, a sulfonyl or cyclohexyl group or a group of the formula ##STR3## R.sup.2 denotes hydrogen, methyl or phenyl, and a denotes an integer from 0 to 10, and subsequent oxyalkylation with propylene oxide or butylene oxide and, if appropriate, ethylene oxide, the amount of propylene oxide or butylene oxide which is added last being 1 to 90% by weight of the total molecule and the amount of ethylene oxide which, optionally, has also been added, being 50% by weight of the total molecule. These addition compounds are used for breaking crude oil emulsions.
摘要:
Addition products from ethylene oxide-propylene oxide block polymers of the formula ##STR1## wherein R denotes methyl or ethyl, n and m are numbers which are so chosen that the content of polyethylene oxide constitutes 5 to 80% of the molecular weight of the total molecule and p is a number larger than 10, and bis-glycidyl ethers of the formulae ##STR2## wherein the R.sup.1 's can be identical or different and denote hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, in particular chlorine, A denotes a direct bond, a sulfonyl or cyclohexyl group or a group of the formula ##STR3## R.sup.2 denotes hydrogen, methyl or phenyl and a denotes an integer from 0 to 10. These addition products are used for breaking petroleum emulsions.
摘要:
The water-soluble copolymer comprises 5-90% by weight of groups of the formula ##STR1## in which R.sup.1 is hydrogen or methyl, R.sup.2 is C.sub.2 -C.sub.10 -alkylene, and Me is ammonium or an alkali metal, 5-90% by weight of groups of the formula--CH.dbd.CH--CH.sub.2 --N.sup.+ R.sup.3 R.sup.4 --CH.sub.2 --CH.dbd.CH-- X.sup.- IIin which X is a halogen, R.sup.3 and R.sup.4, independently of one another, are C.sub.1 -C.sub.6 -alkyl, 0-60% by weight of groups of the formula ##STR2## in which R.sup.5 and R.sup.6 together are a propylene group which with inclusion of the radical ##STR3## forms a pyrrolidone radical, and 0-30% by weight of groups of the formula--CHR.sup.7 --CHR.sup.8 -- IVin which R.sup.7 is hydrogen or methyl and R.sup.8 is CONH.sub.2, CON(CH.sub.3).sub.2, cyano, SO.sub.3 H, SO.sub.3 Me, C.sub.6 H.sub.4 SO.sub.3 H, C.sub.6 H.sub.4 SO.sub.3 Me, CH.sub.2 SO.sub.3 H, CH.sub.2 SO.sub.3 Me, COOH, COOMe, or carboxy-C.sub.1 -C.sub.15 --alkyl, and Me is an ammonium cation or an alkali metal cation, and the order of components I to IV can be as desired.The copolymer is used as water-binding additive for suspensions of solids, preferably for cement slurries, gypsum slurries, mortars, drilling muds or pigment suspensions, or as water-binding additive for aqueous salt solutions.
摘要翻译:水溶性共聚物包含5-90重量%的式I的基团,其中R 1是氢或甲基,R 2是C 2 -C 10 - 亚烷基,Me是铵或碱金属,5-90% 的式-CH = CH-CH 2 -N + R 3 -CH 4 -CH = CH-X-II的基团,其中X是卤素,R 3和R 4彼此独立地是C 1 -C 6 - 烷基, 0-60重量%的其中R 5和R 6一起是含有基团“IMAGE”的丙烯基团的式“IMAGE”III形成吡咯烷酮基团,和0-30重量%的 其中R 7是氢或甲基,R 8是CONH 2,CON(CH 3)2,氰基,SO 3 H,SO 3 Me,C 6 H 4 SO 3 H,C 6 H 4 SO 3 Me,CH 2 SO 3 H,CH 2 SO 3 Me,COOH,COOMe或羧基-C 1 -C 15 - 烷基,Me是铵阳离子或碱金属阳离子,组分I至IV的顺序可以根据需要进行。 该共聚物用作固体悬浮液的水结合添加剂,优选用于水泥浆料,石膏浆料,砂浆,钻井泥浆或颜料悬浮液,或作为盐水溶液的水结合添加剂。
摘要:
A process for the separation of crude oil emulsions of the water-in-oil typeIn the novel process addition products made from certain ethylene oxide/propylene oxide block polymers and certain polyglycidyl ethers of phenol/formaldehyde condensation products are added to the crude oil emulsions.
摘要:
Branched, quaternary polyoxyalkylene copolyesters are described which are prepared by esterifying an oxyalkylated primary fatty amine and an at least trihydric oxyalkylated alkanol or an oxyalkylated polyamine using a dicarboxylic acid or a dicarboxylic anhydride with polycondensation, and quaternizing the esterification product obtained using ethylene oxide or propylene oxide in the presence of a mineral acid or carboxylic acid. The novel, branched, quaternary polyoxyalkylene copolyesters are used as demulsifiers and corrosion inhibitors in the processing of crude oil emulsions.