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1.发明授权公开(公告)号：US07550399B2
公开(公告)日：2009-06-23
申请号：US12075358
申请日：2008-03-11
申请人： William C. Kimbrell, Jr. , Xinggao Fang , Yunzhang Wang , Dominick J. Valenti , Daniel T. McBride
发明人： William C. Kimbrell, Jr. , Xinggao Fang , Yunzhang Wang , Dominick J. Valenti , Daniel T. McBride
CPC分类号： D03D15/00 , D03D15/0011 , D03D15/0027 , D03D15/0061 , D03D15/0077 , D04B1/14 , D10B2101/06 , D10B2101/20 , D10B2201/02 , D10B2201/04 , D10B2201/06 , D10B2201/08 , D10B2201/24 , D10B2211/02 , D10B2211/04 , D10B2321/02 , D10B2321/021 , D10B2321/022 , D10B2321/10 , D10B2331/02 , D10B2331/021 , D10B2331/04 , D10B2331/10 , D10B2501/00 , D10B2501/04 , Y10T442/2279 , Y10T442/2287 , Y10T442/30 , Y10T442/3008 , Y10T442/3244 , Y10T442/3252 , Y10T442/3285 , Y10T442/3366
摘要： The present invention relates generally to substrates that exhibit useful, auto adaptable surface energy properties that depend on the environment of the substrate. Such surface energy properties provide relatively high advancing and receding contact angles for liquids when in contact with the target substrate surface. The substrates exhibit low surface energy quantities of at most about 20 millijoules per square meter (mJ/m2) at a temperature of about 25 degrees C. and a surface energy greater than about 20 mJ/m2 at, or with exposure to, a temperature of about 40 degrees C. More specifically, encompassed within the present invention are textile substrates having this highly desirable unique surface energy modification property and which exhibit wash durable oil and water repellency and stain release features. Novel compositions and formulations that impart such surface energy modifications to substrates are also encompassed within this invention, as well as methods for producing such treated substrates.
摘要翻译： 本发明一般涉及依赖于衬底环境的有用的，自动适应的表面能特性的衬底。 当与目标基板表面接触时，这种表面能量特性为液体提供相对高的前进和后退接触角。 这些基材在约25℃的温度下表现出低至多约20毫焦耳/平方米（mJ / m 2）的低表面能量，并且在暴露于温度时表面能大于约20mJ / m 2 更具体地，本发明中包括具有这种非常理想的独特表面能改性性能的织物基材，并且具有洗涤耐久的防油和防水性和脱色特性。 赋予基质的这种表面能改变的新型组合物和制剂也包括在本发明内，以及生产这种处理过的基材的方法。
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2.发明授权Methods for imparting reversibly adaptable surface energy properties to target surfaces 有权赋予目标表面可逆适应表面能特性的方法公开(公告)号：US06899923B2
公开(公告)日：2005-05-31
申请号：US10339840
申请日：2003-01-10
CPC分类号： D06M15/277 , B05D5/08 , D06M15/256 , D06M15/576 , D06M15/653 , D06M15/657 , D06M2200/11 , D06M2200/12
摘要： The present invention relates generally to substrates that exhibit useful, auto adaptable surface energy properties that depend on the environment of the substrate. Such surface energy properties provide relatively high advancing and receding contact angles for liquids when in contact with the target substrate surface. The substrates exhibit low surface energy quantities of at most about 20 millijoules per square meter (mJ/m2) at a temperature of about 25 degrees C. and a surface energy greater than about 20 mJ/m2 at, or with exposure to, a temperature of about 40 degrees C. More specifically, encompassed within the present invention are textile substrates having this highly desirable unique surface energy modification property and which exhibit wash durable oil and water repellency and stain release features. Novel compositions and formulations that impart such surface energy modifications to substrates are also encompassed within this invention, as well as methods for producing such treated substrates.
摘要翻译： 本发明一般涉及依赖于衬底环境的有用的，自动适应的表面能特性的衬底。 当与目标基板表面接触时，这种表面能量特性为液体提供相对高的前进和后退接触角。 在约25℃的温度和大于约20mJ / m 2的表面能的情况下，基材表现出低至多约20毫焦耳每平方米（mJ / m 2）的低表面能量， SUP> 2 在约40℃的温度下或暴露于约40℃。更具体地说，本发明包括具有这种非常理想的独特的表面能改性性能的织物基材，并且具有洗涤耐久性的油和水 排斥性和脱色特性。 赋予基质的这种表面能改变的新型组合物和制剂也包括在本发明内，以及生产这种处理过的基材的方法。
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3.发明授权公开(公告)号：US07468333B2
公开(公告)日：2008-12-23
申请号：US10339971
申请日：2003-01-10
申请人： Wiliam C. Kimbrell, Jr. , Xinggao Fang , Yunzhang Wang , Dominick J. Valenti , Daniel T. McBride
发明人： Wiliam C. Kimbrell, Jr. , Xinggao Fang , Yunzhang Wang , Dominick J. Valenti , Daniel T. McBride
CPC分类号： D06M15/277 , D06M15/256 , D06M15/576 , D06M15/653 , D06M15/657 , D06M2101/32 , D06M2200/11 , D06M2200/12 , Y10T442/2279 , Y10T442/2861
摘要： The present invention relates generally to substrates that exhibit useful, auto adaptable surface energy properties that depend on the environment of the substrate. Such surface energy properties provide relatively high advancing and receding contact angles for liquids when in contact with the target substrate surface. The substrates exhibit low surface energy quantities of at most about 20 millijoules per square meter (mJ/m2) at a temperature of about 25 degrees C. and a surface energy greater than about 20 mJ/m2 at, or with exposure to, a temperature of about 40 degrees C. More specifically, encompassed within the present invention are textile substrates having this highly desirable unique surface energy modification property and which exhibit wash durable oil and water repellency and stain release features. Novel compositions and formulations that impart such surface energy modifications to substrates are also encompassed within this invention, as well as methods for producing such treated substrates.
摘要翻译： 本发明一般涉及依赖于衬底环境的有用的，自动适应的表面能特性的衬底。 当与目标基板表面接触时，这种表面能量特性为液体提供相对高的前进和后退接触角。 这些基材在约25℃的温度下表现出低至多约20毫焦耳/平方米（mJ / m 2）的低表面能量，并且在暴露于温度时表面能大于约20mJ / m 2 更具体地，本发明中包括具有这种非常理想的独特表面能改性性能的织物基材，并且具有洗涤耐久的防油和防水性和脱色特性。 赋予基质的这种表面能改变的新型组合物和制剂也包括在本发明内，以及生产这种处理过的基材的方法。
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4.发明申请公开(公告)号：US20080160850A1
公开(公告)日：2008-07-03
申请号：US12075358
申请日：2008-03-11
IPC分类号： B32B27/12
CPC分类号： D03D15/00 , D03D15/0011 , D03D15/0027 , D03D15/0061 , D03D15/0077 , D04B1/14 , D10B2101/06 , D10B2101/20 , D10B2201/02 , D10B2201/04 , D10B2201/06 , D10B2201/08 , D10B2201/24 , D10B2211/02 , D10B2211/04 , D10B2321/02 , D10B2321/021 , D10B2321/022 , D10B2321/10 , D10B2331/02 , D10B2331/021 , D10B2331/04 , D10B2331/10 , D10B2501/00 , D10B2501/04 , Y10T442/2279 , Y10T442/2287 , Y10T442/30 , Y10T442/3008 , Y10T442/3244 , Y10T442/3252 , Y10T442/3285 , Y10T442/3366
摘要： The present invention relates generally to substrates that exhibit useful, auto adaptable surface energy properties that depend on the environment of the substrate. Such surface energy properties provide relatively high advancing and receding contact angles for liquids when in contact with the target substrate surface. The substrates exhibit low surface energy quantities of at most about 20 millijoules per square meter (mJ/m2) at a temperature of about 25 degrees C. and a surface energy greater than about 20 mJ/m2 at, or with exposure to, a temperature of about 40 degrees C. More specifically, encompassed within the present invention are textile substrates having this highly desirable unique surface energy modification property and which exhibit wash durable oil and water repellency and stain release features. Novel compositions and formulations that impart such surface energy modifications to substrates are also encompassed within this invention, as well as methods for producing such treated substrates.
摘要翻译： 本发明一般涉及依赖于衬底环境的有用的，自动适应的表面能特性的衬底。 当与目标基板表面接触时，这种表面能量特性为液体提供相对高的前进和后退接触角。 在约25℃的温度和大于约20mJ / m 2的表面能的情况下，基材表现出低至多约20毫焦耳每平方米（mJ / m 2）的低表面能量， SUP> 2 在约40℃的温度下或暴露于约40℃。更具体地说，本发明包括具有这种非常理想的独特的表面能改性性能的织物基材，并且具有洗涤耐久性的油和水 排斥性和脱色特性。 赋予基质的这种表面能改变的新型组合物和制剂也包括在本发明内，以及生产这种处理过的基材的方法。
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公开(公告)号：US07213309B2
公开(公告)日：2007-05-08
申请号：US10785218
申请日：2004-02-24
IPC分类号： D06C11/00
CPC分类号： B32B5/02 , B32B5/024 , B32B5/26 , B32B7/12 , B32B2307/73 , B32B2307/754 , D06M15/277 , D06M15/564 , D06M23/08 , D06M2200/11 , D06M2200/12 , Y10T156/10 , Y10T442/2221 , Y10T442/2238 , Y10T442/2279 , Y10T442/2287 , Y10T442/30
摘要： Compositions and methods for treating textile substrates to obtain superior liquid repellent properties are disclosed. Durable microscopic surface structures imparted to the fibrous substrate allow liquids to bead up and roll off of its surface. Mechanical abrasion or sanding techniques may be used to create the microscopic surface structures on the surface of a fibrous textile substrate, without substantially breaking fibers, followed by a chemical treatment using, for example, fluorocarbon-containing repellent compositions. Particles may be employed in combination with repellent compositions to achieve superior repellent properties. A property of the roughened surface fibers, the Roughness Factor, is used to characterize the microscopic surface structures on the treated textile surface. Treated textile substrates are disclosed which achieve superior water and oil repellency, even after multiple abrasion or laundering cycles.
摘要翻译： 公开了用于处理纺织基材以获得优异的防液性的组合物和方法。 赋予纤维基质的耐用微观表面结构允许液体从其表面起珠和滚落。 可以使用机械磨损或砂磨技术来在纤维织物基材的表面上产生微观表面结构，而基本上不破坏纤维，然后使用例如含氟烃的驱避剂组合物进行化学处理。 颗粒可以与驱避剂组合物组合使用以获得优异的驱避剂性能。 使用粗糙表面纤维（粗糙度因子）的特性来表征经处理的织物表面上的微观表面结构。 公开了处理过的纺织品基材，即使在多次磨损或洗涤循环之后，其也具有优异的拒水拒油性。
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公开(公告)号：US08541056B2
公开(公告)日：2013-09-24
申请号：US12779987
申请日：2010-05-14
IPC分类号： B29C65/46
CPC分类号： B32B5/02 , B32B5/024 , B32B5/26 , B32B7/12 , B32B2307/73 , B32B2307/754 , D06M15/277 , D06M15/564 , D06M23/08 , D06M2200/11 , D06M2200/12 , Y10T156/10 , Y10T442/2221 , Y10T442/2238 , Y10T442/2279 , Y10T442/2287 , Y10T442/30
摘要： Compositions and methods for treating textile substrates to obtain superior liquid repellent properties are disclosed. Durable microscopic surface structures imparted to the fibrous substrate allow liquids to bead up and roll off of its surface. Mechanical abrasion or sanding techniques may be used to create the microscopic surface structures on the surface of a fibrous textile substrate, without substantially breaking fibers, followed by a chemical treatment using, for example, fluorocarbon-containing repellent compositions. Particles may be employed in combination with repellent compositions to achieve superior repellent properties. A property of the roughened surface fibers, the Roughness Factor, is used to characterize the microscopic surface structures on the treated textile surface. Treated textile substrates are disclosed which achieve superior water and oil repellency, even after multiple abrasion or laundering cycles.
摘要翻译： 公开了用于处理纺织基材以获得优异的防液性的组合物和方法。 赋予纤维基质的耐用微观表面结构允许液体从其表面起珠和滚落。 可以使用机械磨损或砂磨技术来在纤维织物基材的表面上产生微观表面结构，而基本上不破坏纤维，然后使用例如含氟烃的驱避剂组合物进行化学处理。 颗粒可以与驱避剂组合物组合使用以获得优异的驱避剂性能。 使用粗糙表面纤维（粗糙度因子）的特性来表征经处理的织物表面上的微观表面结构。 公开了处理过的纺织品基材，即使在多次磨损或洗涤循环之后，其也具有优异的拒水拒油性。
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公开(公告)号：US20100218878A1
公开(公告)日：2010-09-02
申请号：US12779987
申请日：2010-05-14
CPC分类号： B32B5/02 , B32B5/024 , B32B5/26 , B32B7/12 , B32B2307/73 , B32B2307/754 , D06M15/277 , D06M15/564 , D06M23/08 , D06M2200/11 , D06M2200/12 , Y10T156/10 , Y10T442/2221 , Y10T442/2238 , Y10T442/2279 , Y10T442/2287 , Y10T442/30
摘要： Compositions and methods for treating textile substrates to obtain superior liquid repellent properties are disclosed. Durable microscopic surface structures imparted to the fibrous substrate allow liquids to bead up and roll off of its surface. Mechanical abrasion or sanding techniques may be used to create the microscopic surface structures on the surface of a fibrous textile substrate, without substantially breaking fibers, followed by a chemical treatment using, for example, fluorocarbon-containing repellent compositions. Particles may be employed in combination with repellent compositions to achieve superior repellent properties. A property of the roughened surface fibers, the Roughness Factor, is used to characterize the microscopic surface structures on the treated textile surface. Treated textile substrates are disclosed which achieve superior water and oil repellency, even after multiple abrasion or laundering cycles.
摘要翻译： 公开了用于处理纺织基材以获得优异的防液性的组合物和方法。 赋予纤维基质的耐用微观表面结构允许液体从其表面起珠和滚落。 可以使用机械磨损或砂磨技术来在纤维织物基材的表面上产生微观表面结构，而基本上不破坏纤维，然后使用例如含氟烃的驱避剂组合物进行化学处理。 颗粒可以与驱避剂组合物组合使用以获得优异的驱避剂性能。 使用粗糙表面纤维（粗糙度因子）的特性来表征经处理的织物表面上的微观表面结构。 公开了处理过的纺织品基材，即使在多次磨损或洗涤循环之后，其也具有优异的拒水拒油性。
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公开(公告)号：US08293353B2
公开(公告)日：2012-10-23
申请号：US12313863
申请日：2008-11-25
CPC分类号： B32B5/26 , B32B5/022 , B32B5/024 , B32B5/026 , B32B5/08 , B32B5/12 , B32B2250/40 , B32B2262/101 , B32B2262/106 , B32B2262/14 , B32B2307/516 , B32B2307/56 , B32B2419/00 , B32B2471/00 , B32B2605/00 , B32B2607/00 , Y10T156/1052 , Y10T428/187 , Y10T428/24058 , Y10T428/24074 , Y10T428/24107 , Y10T428/24132 , Y10T428/24174 , Y10T428/24479 , Y10T428/2495 , Y10T428/24983 , Y10T428/2913
摘要： An energy absorbing panel containing a pair of generally parallel spaced apart rigid end plates having a stiffness of at least about 200 N-m and a plurality of fabric layers extending between the rigid end plates oriented in a z-axis direction defined as being perpendicular to the rigid end plates. Each fabric layer contains a plurality of monoaxially drawn, thermoplastic fibers. The plurality of fabric layers are fused together forming a bonded structure. Methods of making the energy absorbing panel are also disclosed.
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公开(公告)号：US20120183720A1
公开(公告)日：2012-07-19
申请号：US12157668
申请日：2008-06-12
申请人： Yunzhang Wang
发明人： Yunzhang Wang
CPC分类号： F41H5/0485 , Y10T428/23 , Y10T428/24033 , Y10T428/24851 , Y10T428/24942 , Y10T442/2615 , Y10T442/3154 , Y10T442/3472 , Y10T442/3504 , Y10T442/3512 , Y10T442/352 , Y10T442/3528 , Y10T442/3537 , Y10T442/3602 , Y10T442/3667 , Y10T442/3699 , Y10T442/3707 , Y10T442/3715
摘要： A flexible spike and knife resistant composite incorporating a stack of at least ten consolidated layer groupings. Each layer grouping has a normalized stiffness of less than about 5 g/g/m2 as tested by a modified ASTM Test Method D6828-02 and contains one or two spike resistant textile layers, an adhesive layer, and one or two knife resistant textile layers. The spike resistant textile layers contain a plurality of interlocked yarns or fibers, where the yarns or fibers have a tenacity of about 8 or more grams per denier and the fiber size is less than ten denier per filament. The knife resistant textile layers contain monoaxially drawn fiber elements, where the fiber elements have an aspect ratio of greater than one and have a size greater than 100 denier per filament. The fiber elements of the knife resistant textile layer are bonded to each other or to the spike resistant layer.
摘要翻译： 结合了至少十个固结层组的叠层的柔性穗状和耐刀具复合材料。 通过改进的ASTM测试方法D6828-02测试，每层分组具有小于约5g / g / m 2的归一化刚度，并且包含一个或两个抗刺绣织物层，粘合剂层和一个或两个耐刀织织物层 。 抗刺绣织物层包含多个互锁的纱线或纤维，其中纱线或纤维的强度为约8或更多克每旦尼尔，纤维尺寸小于十旦尼尔每丝。 耐磨织物层包含单轴拉伸纤维元件，其中纤维元件具有大于1的纵横比，并且具有大于100旦尼尔/丝的尺寸。 防刀织物层的纤维元件彼此结合或者与防钉层接合。
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公开(公告)号：US20100189963A1
公开(公告)日：2010-07-29
申请号：US12360576
申请日：2009-01-27
CPC分类号： D01D5/426 , B29C47/0014 , B29C47/0019 , B29C47/0021 , B29C47/0023 , B29C47/0026 , B29C47/0057 , B29C47/025 , B29C47/128 , B29C70/202 , B29C70/465 , B29C70/506 , B29K2023/12 , B29L2031/731 , B32B5/022 , B32B5/024 , B32B5/026 , B32B5/08 , B32B5/26 , B32B7/02 , B32B27/08 , B32B27/12 , B32B27/32 , B32B27/327 , B32B2250/40 , B32B2262/0253 , B32B2262/0261 , B32B2262/0269 , B32B2262/101 , B32B2262/106 , B32B2307/54 , B32B2307/702 , B32B2307/704 , D01F8/06 , Y10T428/24802 , Y10T428/249938 , Y10T428/249939 , Y10T428/249946 , Y10T428/2967
摘要： A multi-layered fiber containing a core and a skin layer. The core has an exterior surface portion containing polypropylene. The skin layer is disposed on at least a portion of the core and contains a first polymer and a second polymer. The first polymer contains a polymer having at least 70% α-olefin units and is characterized by a melting temperature lower than the melting temperature of the exterior surface portion of the core. The second polymer contains a co-polymer having at least 50% α-olefin units and is characterized by a number-average molecular weight of about 7,000 g/mol to 50,000 g/mol, a viscosity of between about 2,500 and 150,000 cP measured at 170° C., and a melting temperature lower than the melting temperature of the exterior surface portion of the core. The viscosity of the second polymer is not greater than about 10 percent of the viscosity of the first polymer measured at 170° C. Methods of forming the multi-layered fiber are also disclosed.
摘要翻译： 含有核心和皮肤层的多层纤维。 芯具有包含聚丙烯的外表面部分。 表层设置在芯的至少一部分上并含有第一聚合物和第二聚合物。 第一聚合物含有具有至少70％的α-烯烃单元的聚合物，其特征在于熔融温度低于芯的外表面部分的熔融温度。 第二聚合物含有具有至少50％α-烯烃单元的共聚物，其特征在于数均分子量为约7,000g / mol至50,000g / mol，粘度在约2,500至150,000cP之间 170℃，并且熔融温度低于芯的外表面部分的熔融温度。 第二聚合物的粘度不高于在170℃下测量的第一聚合物的粘度的约10％。还公开了形成多层纤维的方法。
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