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公开(公告)号：US4861743A
公开(公告)日：1989-08-29
申请号：US126192
申请日：1987-11-25
CPC分类号： C01B37/08 , B01J29/84 , C01B37/04 , C01B37/06 , B01J2229/64
摘要： Non-zeolitic molecular sieves are prepared by contacting a body of alumina or silica-alumina (optionally containing reactive sources of phosphorus pentoxide and/or other elements desired in the non-zeolitic molecular sieve) with a liquid reaction mixture containing a reactive source of phosphorus pentoxide (and optionally reactive sources of silica and/or other elements desired in the non-zeolitic molecular sieve), and an organic templating agent, thereby causing the body to react with the liquid reaction mixture and to form crystals of the non-zeolitic molecular sieve within the body.
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2.发明授权Hydrocarbon conversion processes using a novel crystalline microporous metal oxysulfide composition 失效使用新的结晶微孔金属氧硫化物组合物的烃转化方法
公开(公告)号：US5128025A
公开(公告)日：1992-07-07
申请号：US803936
申请日：1991-12-09
CPC分类号： B01J29/85 , B01J29/005 , C01B33/2884 , B01J29/84
摘要： This invention deals with a hydrocarbon conversion process using a crystalline oxysulfide composition. The crystalline oxysulfide composition has a three-dimensional microporous framework structure of at least MO.sub.2, MS.sub.2, and MOS tetrahedral units, having an intracrystalline pore system and an empirical formula expressed in molar ratios:(M.sub.s Al.sub.t P.sub.u Si.sub.v)S.sub.w O.sub.2-wwhere M is at least one metal selected from the group consisting of metals which: 1) can be incorporated into the framework structure of a microporous molecular sieve and 2) form hydrolytically stable sulfides; s, t, u, v and w are the mole fractions of M, Al, P, Si and S respectively. The values of s, t, u and v are chosen such that when t is greater than zero u is greater than zero, s+t+u+v=1 and when s=1, M is only a combination of gallium and germanium.
摘要翻译： 本发明涉及使用结晶氧硫化物组合物的烃转化方法。 结晶氧硫化物组合物具有至少具有MO2，MS2和MOS四面体单元的三维微孔骨架结构，具有结晶孔系统和以摩尔比表示的经验式：（MsAltPuSiv）SwO 2 -w，其中M为至少一个 选自以下的金属的金属：1）可以结合到微孔分子筛的骨架结构中，2）形成水解稳定的硫化物; s，t，u，v和w分别是M，Al，P，Si和S的摩尔分数。 选择s，t，u和v的值，使得当t大于零时，u大于零，s + t + u + v = 1，当s = 1时，M只是镓和锗的组合 。
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3.发明授权Process for separating a mixture of molecular species using crystalline microporous metal sulfide compositions 失效使用结晶微孔金属硫化物组合物分离分子物质的混合物的方法
公开(公告)号：US5013337A
公开(公告)日：1991-05-07
申请号：US507819
申请日：1990-04-12
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82 , Y10S95/902
摘要： This invention relates to a process for separating a mixture of molecular species based on the molecular size (kinetic diameter) or on the degree of polarity of the molecular species using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. A composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium may also be used in the process.
摘要翻译： 本发明涉及使用具有MA2单元的三维微孔结构的结晶组合物，基于分子大小（动力学直径）或分子物质的极性的程度来分离分子种类的混合物的方法，其中A是硫 或硒，并具有以摩尔比表示的经验式：xR：MA2 +/- 0.2：zH2O其中R表示晶体内孔体系中存在的至少一种有机模板剂，x是R的摩尔数，z是水的摩尔数， M是锗或锡。 具有以摩尔比表示的经验式的组合物：xR：M1-yM'yA2 +/- 0.2：zH2O，其中M'是诸如钴，锌，锰，铁，镍，铜，镉和镓的金属也可以是 在过程中使用。
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4.发明授权
公开(公告)号：US4973460A
公开(公告)日：1990-11-27
申请号：US218494
申请日：1988-07-06
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of LiO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of lithium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有LiO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（LiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（LiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锂，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4940570A
公开(公告)日：1990-07-10
申请号：US835293
申请日：1986-03-03
IPC分类号： B01J29/84 , C01B25/45 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of BeO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Be.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Be.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of beryllium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有BeO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（BexAlyPz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（BexAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的铍，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4759919A
公开(公告)日：1988-07-26
申请号：US830756
申请日：1986-02-19
CPC分类号： B01J29/84 , C01B39/00 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of CrO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Cr.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Cr.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of chromium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CrO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（CrxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CrxAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的铬，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4310440A
公开(公告)日：1982-01-12
申请号：US166333
申请日：1980-07-07
IPC分类号： B01D53/28 , B01J20/02 , B01J20/08 , B01J29/04 , B01J29/83 , B01J29/84 , C01B25/36 , C01B37/04 , C07B61/00 , C07C1/00 , C07C2/54 , C07C2/66 , C07C4/18 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C6/12 , C07C15/08 , C07C67/00 , C10G11/02 , C10G35/06 , C10G45/04 , C10G47/02 , B01J27/14 , B01J31/02 , C01B15/16
CPC分类号： C07C5/224 , B01J20/0292 , B01J29/84 , C01B37/04 , C07C2/54 , C07C5/02 , C07C5/2716 , C07C2529/83 , Y10S502/51 , Y10S502/511
摘要： A novel family of crystalline, microporous aluminophosphate compositions is synthesized by hydrothermal crystallization at elevated temperatures of aluminophosphate gels containing a molecular structure-forming template. The family comprises a number of distinct species, each with a unique crystal structure. Calcination removes volatile extraneous matter from the intracrystalline void space and yields microporous crystalline adsorbents with uniform pores, the dimensions of which vary, among the individual species, from about 3A to 10A in diameter. The compositions represent a new class of adsorbents of the molecular sieve type, and also exhibit properties somewhat analogous to zeolitic molecular sieves which render them useful as catalysts or catalyst bases in chemical reactions such as hydrocarbon conversions.
摘要翻译： 通过在含有分子结构形成模板的磷酸铝凝胶的升高温度下水热结晶合成了一系列结晶的微孔磷酸铝组合物。 家庭包括许多不同的物种，每个都有独特的晶体结构。 焙烧从晶体间隙空间中除去挥发性的外来物质，并产生具有均匀孔隙的微孔结晶吸附剂，其尺寸在各个物种之间变化，直径为约3A至10A。 该组合物代表了一类新型的分子筛型吸附剂，并且还表现出与沸石分子筛有些类似的特性，使得它们可用作化学反应如烃转化中的催化剂或催化剂。
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公开(公告)号：US4952384A
公开(公告)日：1990-08-28
申请号：US197407
申请日：1988-05-20
申请人： Brent M. T. Lok , Bonita K. Marcus , Celeste A. Messina , Stephen T. Wilson , Edith M. Flanigen
发明人： Brent M. T. Lok , Bonita K. Marcus , Celeste A. Messina , Stephen T. Wilson , Edith M. Flanigen
IPC分类号： B01J29/84 , B01J29/85 , C01B25/45 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , B01J29/85 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MO.sub.2.sup.n, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR : (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and/or titanium, and at least one of cobalt, magnesium, manganese and zinc; "n" is O, -1 or -2; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有MO2n，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和/或钛，以及钴，镁，锰和锌中的至少一种; “n”为O，-1或-2; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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9.发明授权Hydrocarbon conversion process using crystalline microporous metal sulfide compositions 失效使用结晶微孔金属硫化物组合物的烃转化方法
公开(公告)号：US4933068A
公开(公告)日：1990-06-12
申请号：US416170
申请日：1989-10-02
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82
摘要： This invention relates to a hydrocarbon conversion process using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2+0.2 :ZH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. This invention also relates to a composition having the empirical formula expressed in molar ratios: XR:M.sub.1-y M.sup.'y A.sub.2+0.2 :ZH.sub.2 O where M' is a metal such as cobalt, zinc, manganese, iron, nickel, cooper, cadmium and gallium.
摘要翻译： 本发明涉及使用具有MA2单元的三维微孔结构的结晶组合物的烃转化方法，其中A是硫或硒，并且具有以摩尔比表示的经验式：xR：MA2 + 0.2：ZH2O其中R表示至少 存在于晶体内孔体系中的一种有机模板剂，x是R的摩尔数，z是水的摩尔数，M是锗或锡。 本发明还涉及具有以摩尔比表示的经验式的组合物：XR：M1-yM'yA2 + 0.2：ZH2O其中M'是金属如钴，锌，锰，铁，镍，铜，镉和镓 。
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公开(公告)号：US4880761A
公开(公告)日：1989-11-14
申请号：US280757
申请日：1988-12-06
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82
摘要： This invention relates to a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. This invention also relates to a composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium. This invention further relates to a method of preparing the crystalline composition.
摘要翻译： 本发明涉及一种具有MA2单元的三维微孔结构的结晶组合物，其中A是硫或硒并具有以摩尔比表示的经验式：xR：MA2 +/- 0.2：zH2O其中R表示至少一种有机模板剂 存在于晶体内孔体系中，x是R的摩尔数，z是水的摩尔数，M是锗或锡。 本发明还涉及具有以摩尔比表示的经验式的组合物：xR：M1-yM'yA2 +/- 0.2：zH2O，其中M'是诸如钴，锌，锰，铁，镍，铜，镉的金属 和镓。 本发明还涉及一种制备该结晶组合物的方法。
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