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公开(公告)号:US08574985B2
公开(公告)日:2013-11-05
申请号:US13039819
申请日:2011-03-03
申请人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
发明人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
IPC分类号: H01L21/8242
CPC分类号: H01L21/3141 , C23C16/02 , C23C16/405 , H01L21/02186 , H01L21/02271 , H01L21/02315 , H01L21/31604 , H01L28/91
摘要: Methods for depositing high-K dielectrics are described, including depositing a first electrode on a substrate, wherein the first electrode is chosen from the group consisting of platinum and ruthenium, applying an oxygen plasma treatment to the exposed metal to reduce the contact angle of a surface of the metal, and depositing a titanium oxide layer on the exposed metal using at least one of a chemical vapor deposition process and an atomic layer deposition process, wherein the titanium oxide layer comprises at least a portion rutile titanium oxide.
摘要翻译: 描述了沉积高K电介质的方法,包括在衬底上沉积第一电极,其中第一电极选自铂和钌,对暴露的金属施加氧等离子体处理以减小接触角 并且使用化学气相沉积工艺和原子层沉积工艺中的至少一种将氧化钛层沉积在暴露的金属上,其中所述氧化钛层包含至少一部分金红石型氧化钛。
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公开(公告)号:US20110151136A1
公开(公告)日:2011-06-23
申请号:US13039819
申请日:2011-03-03
申请人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
发明人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
CPC分类号: H01L21/3141 , C23C16/02 , C23C16/405 , H01L21/02186 , H01L21/02271 , H01L21/02315 , H01L21/31604 , H01L28/91
摘要: Methods for depositing high-K dielectrics are described, including depositing a first electrode on a substrate, wherein the first electrode is chosen from the group consisting of platinum and ruthenium, applying an oxygen plasma treatment to the exposed metal to reduce the contact angle of a surface of the metal, and depositing a titanium oxide layer on the exposed metal using at least one of a chemical vapor deposition process and an atomic layer deposition process, wherein the titanium oxide layer comprises at least a portion rutile titanium oxide.
摘要翻译: 描述了用于沉积高K电介质的方法,包括在衬底上沉积第一电极,其中第一电极选自铂和钌,对暴露的金属施加氧等离子体处理以减小接触角 并且使用化学气相沉积工艺和原子层沉积工艺中的至少一种在暴露的金属上沉积氧化钛层,其中所述氧化钛层包含至少一部分金红石型氧化钛。
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公开(公告)号:US07927947B2
公开(公告)日:2011-04-19
申请号:US12495558
申请日:2009-06-30
申请人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
发明人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
IPC分类号: H01L21/20
CPC分类号: H01L21/3141 , C23C16/02 , C23C16/405 , H01L21/02186 , H01L21/02271 , H01L21/02315 , H01L21/31604 , H01L28/91
摘要: Methods for depositing high-K dielectrics are described, including depositing a first electrode on a substrate, wherein the first electrode is chosen from the group consisting of platinum and ruthenium, applying an oxygen plasma treatment to the exposed metal to reduce the contact angle of a surface of the metal, and depositing a titanium oxide layer on the exposed metal using at least one of a chemical vapor deposition process and an atomic layer deposition process, wherein the titanium oxide layer comprises at least a portion rutile titanium oxide.
摘要翻译: 描述了用于沉积高K电介质的方法,包括在衬底上沉积第一电极,其中第一电极选自铂和钌,对暴露的金属施加氧等离子体处理以减小接触角 并且使用化学气相沉积工艺和原子层沉积工艺中的至少一种在暴露的金属上沉积氧化钛层,其中所述氧化钛层包含至少一部分金红石型氧化钛。
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公开(公告)号:US20100330772A1
公开(公告)日:2010-12-30
申请号:US12495558
申请日:2009-06-30
申请人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
发明人: Xiangxin Rui , Sunil Shanker , Sandra Malhotra , Imran Hashim , Edward Haywood
IPC分类号: H01L21/02
CPC分类号: H01L21/3141 , C23C16/02 , C23C16/405 , H01L21/02186 , H01L21/02271 , H01L21/02315 , H01L21/31604 , H01L28/91
摘要: Methods for depositing high-K dielectrics are described, including depositing a first electrode on a substrate, wherein the first electrode is chosen from the group consisting of platinum and ruthenium, applying an oxygen plasma treatment to the exposed metal to reduce the contact angle of a surface of the metal, and depositing a titanium oxide layer on the exposed metal using at least one of a chemical vapor deposition process and an atomic layer deposition process, wherein the titanium oxide layer comprises at least a portion rutile titanium oxide.
摘要翻译: 描述了用于沉积高K电介质的方法,包括在衬底上沉积第一电极,其中第一电极选自铂和钌,对暴露的金属施加氧等离子体处理以减小接触角 并且使用化学气相沉积工艺和原子层沉积工艺中的至少一种在暴露的金属上沉积氧化钛层,其中所述氧化钛层包含至少一部分金红石型氧化钛。
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公开(公告)号:US20110027617A1
公开(公告)日:2011-02-03
申请号:US12793614
申请日:2010-06-03
申请人: Laura M. Matz , Xiangxin Rui , Xinjian Lei , Sunil Shanker , Moo-Sung Kim , Nobi Fuchigami , Iain Buchanan , Duong Anh , Sandra Malhotra , Imran Hashim
发明人: Laura M. Matz , Xiangxin Rui , Xinjian Lei , Sunil Shanker , Moo-Sung Kim , Nobi Fuchigami , Iain Buchanan , Duong Anh , Sandra Malhotra , Imran Hashim
IPC分类号: B32B9/00
CPC分类号: C23C16/45531 , C23C16/409 , H01L21/02197 , H01L21/0228 , H01L21/02356 , H01L21/3142 , H01L21/31691 , H01L28/56
摘要: Embodiments of the current invention include methods of forming a strontium titanate (SrTiO3) film using atomic layer deposition (ALD). More particularly, the method includes forming a plurality of titanium oxide (TiO2) unit films using ALD and forming a plurality of strontium oxide (SrO) unit films using ALD. The combined thickness of the TiO2 and SrO unit films is less than approximately 5 angstroms. The TiO2 and SrO units films are then annealed to form a strontium titanate layer.
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公开(公告)号:US20110027960A1
公开(公告)日:2011-02-03
申请号:US12793611
申请日:2010-06-03
申请人: Laura M. Matz , Xiangxin Rui , Xinjian Lei , Sunil Shanker , Moo-Sung Kim , Nobi Fuchigami , Iain Buchanan , Anh Duong , Sandra Malhotra , Imran Hashim
发明人: Laura M. Matz , Xiangxin Rui , Xinjian Lei , Sunil Shanker , Moo-Sung Kim , Nobi Fuchigami , Iain Buchanan , Anh Duong , Sandra Malhotra , Imran Hashim
IPC分类号: H01L21/285 , H01L21/02
CPC分类号: C23C16/45531 , C23C16/409 , H01L21/02197 , H01L21/0228 , H01L21/02356 , H01L21/3142 , H01L21/31691 , H01L28/56
摘要: Embodiments of the current invention include methods of forming a strontium titanate (SrTiO3) film using atomic layer deposition (ALD). More particularly, the method includes forming a plurality of titanium oxide (TiO2) unit films using ALD and forming a plurality of strontium oxide (SrO) unit films using ALD. The combined thickness of the TiO2 and SrO unit films is less than approximately 5 angstroms. The TiO2 and SrO units films are then annealed to form a strontium titanate layer.
摘要翻译: 本发明的实施方案包括使用原子层沉积(ALD)形成钛酸锶(SrTiO 3)膜的方法。 更具体地说,该方法包括使用ALD形成多个氧化钛(TiO 2)单元膜并使用ALD形成多个氧化锶(SrO)单元膜。 TiO 2和SrO单元膜的组合厚度小于约5埃。 然后将TiO 2和SrO单元膜退火以形成钛酸锶层。
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公开(公告)号:US20120235276A1
公开(公告)日:2012-09-20
申请号:US13051531
申请日:2011-03-18
申请人: Xiangxin Rui , Hanhong Chen , Edward Haywood , Sandra Malhotra , Takashi Arao , Naonori Fujiwara , Toshiyuki Hirota , Takakazu Kiyomura , Kenichi Koyanagi
发明人: Xiangxin Rui , Hanhong Chen , Edward Haywood , Sandra Malhotra , Takashi Arao , Naonori Fujiwara , Toshiyuki Hirota , Takakazu Kiyomura , Kenichi Koyanagi
CPC分类号: H01L28/60 , H01L21/02 , H01L27/1085 , H01L28/40
摘要: A method for fabricating a dynamic random access memory capacitor is disclosed. The method may comprise depositing a first titanium nitride (TiN) electrode; creating a first layer of titanium dioxide (TiO2) on the first TiN electrode; depositing a dielectric material on the first layer of titanium dioxide; and depositing a second TiN electrode on the dielectric material.
摘要翻译: 公开了一种用于制造动态随机存取存储器电容器的方法。 该方法可以包括沉积第一氮化钛(TiN)电极; 在第一TiN电极上形成第一层二氧化钛(TiO 2); 在第一层二氧化钛上沉积电介质材料; 以及在所述电介质材料上沉积第二TiN电极。
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公开(公告)号:US20120156889A1
公开(公告)日:2012-06-21
申请号:US13334618
申请日:2011-12-22
申请人: Hanhong Chen , Edward Haywood , Pragati Kumar , Sandra Malhotra , Xiangxin Rui
发明人: Hanhong Chen , Edward Haywood , Pragati Kumar , Sandra Malhotra , Xiangxin Rui
IPC分类号: H01L21/316
CPC分类号: H01L28/40 , H01L21/02186 , H01L21/02189 , H01L21/0228 , H01L28/56 , H01L28/60
摘要: This disclosure provides a method of fabricating a semiconductor stack and associated device, such as a capacitor or DRAM cell. In such a device, a high-K zirconia-based layer may be used as the primary dielectric together with a relatively inexpensive metal electrode based on titanium nitride. To prevent corruption of the electrode during device formation, a thin barrier layer can be used seal the electrode prior to the use of a high temperature process and a (high-concentration or dosage) ozone reagent (i.e., to create a high-K zirconia-based layer). In some embodiments, the barrier layer can also be zirconia-based, for example, a thin layer of doped or un-doped amorphous zirconia. Fabrication of a device in this manner facilitates formation of a device with dielectric constant of greater than 40 based on zirconia and titanium nitride, and generally helps produce less costly, increasingly dense DRAM cells and other semiconductor structures.
摘要翻译: 本公开提供了制造半导体堆叠和相关联的器件(诸如电容器或DRAM单元)的方法。 在这种器件中,高K氧化锆基层可以与基于氮化钛的相对廉价的金属电极一起用作主要电介质。 为了防止在器件形成期间电极的损坏,可以使用薄的阻挡层,在使用高温工艺和(高浓度或剂量)的臭氧试剂之前密封电极(即,产生高K氧化锆 基层)。 在一些实施例中,阻挡层也可以是基于氧化锆的,例如掺杂或未掺杂的无定形氧化锆的薄层。 以这种方式制造器件有助于基于氧化锆和氮化钛形成具有大于40的介电常数的器件,并且通常有助于产生更便宜的,越来越致密的DRAM电池和其它半导体结构。
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公开(公告)号:US08530322B2
公开(公告)日:2013-09-10
申请号:US12970835
申请日:2010-12-16
申请人: Hanhong Chen , Edward Haywood , Pragati Kumar , Sandra Malhotra , Xiangxin Rui
发明人: Hanhong Chen , Edward Haywood , Pragati Kumar , Sandra Malhotra , Xiangxin Rui
IPC分类号: H01L21/20
CPC分类号: H01L28/40 , H01L21/02186 , H01L21/02189 , H01L21/0228 , H01L28/56 , H01L28/60
摘要: This disclosure provides a method of fabricating a semiconductor stack and associated device, such as a capacitor or DRAM cell. In such a device, a high-K zirconia-based layer may be used as the primary dielectric together with a relatively inexpensive metal electrode based on titanium nitride. To prevent corruption of the electrode during device formation, a thin barrier layer can be used seal the electrode prior to the use of a high temperature process and a (high-concentration or dosage) ozone reagent (i.e., to create a high-K zirconia-based layer). In some embodiments, the barrier layer can also be zirconia-based, for example, a thin layer of doped or un-doped amorphous zirconia. Fabrication of a device in this manner facilitates formation of a device with dielectric constant of greater than 40 based on zirconia and titanium nitride, and generally helps produce less costly, increasingly dense DRAM cells and other semiconductor structures.
摘要翻译: 本公开提供了制造半导体堆叠和相关联的器件(诸如电容器或DRAM单元)的方法。 在这种器件中,高K氧化锆基层可以与基于氮化钛的相对廉价的金属电极一起用作主要电介质。 为了防止在器件形成期间电极的损坏,可以使用薄的阻挡层,在使用高温工艺和(高浓度或剂量)的臭氧试剂之前密封电极(即,产生高K氧化锆 基层)。 在一些实施例中,阻挡层也可以是基于氧化锆的,例如掺杂或未掺杂的无定形氧化锆的薄层。 以这种方式制造器件有助于基于氧化锆和氮化钛形成具有大于40的介电常数的器件,并且通常有助于产生更便宜的,越来越致密的DRAM电池和其它半导体结构。
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公开(公告)号:US20120156854A1
公开(公告)日:2012-06-21
申请号:US12970835
申请日:2010-12-16
申请人: Hanhong Chen , Edward Haywood , Pragati Kumar , Sandra Malhotra , Xiangxin Rui
发明人: Hanhong Chen , Edward Haywood , Pragati Kumar , Sandra Malhotra , Xiangxin Rui
IPC分类号: H01L21/02
CPC分类号: H01L28/40 , H01L21/02186 , H01L21/02189 , H01L21/0228 , H01L28/56 , H01L28/60
摘要: This disclosure provides a method of fabricating a semiconductor stack and associated device, such as a capacitor or DRAM cell. In such a device, a high-K zirconia-based layer may be used as the primary dielectric together with a relatively inexpensive metal electrode based on titanium nitride. To prevent corruption of the electrode during device formation, a thin barrier layer can be used seal the electrode prior to the use of a high temperature process and a (high-concentration or dosage) ozone reagent (i.e., to create a high-K zirconia-based layer). In some embodiments, the barrier layer can also be zirconia-based, for example, a thin layer of doped or un-doped amorphous zirconia. Fabrication of a device in this manner facilitates formation of a device with dielectric constant of greater than 40 based on zirconia and titanium nitride, and generally helps produce less costly, increasingly dense DRAM cells and other semiconductor structures.
摘要翻译: 本公开提供了制造半导体堆叠和相关联的器件(诸如电容器或DRAM单元)的方法。 在这种器件中,高K氧化锆基层可以与基于氮化钛的相对廉价的金属电极一起用作主要电介质。 为了防止在器件形成期间电极的损坏,可以使用薄的阻挡层,在使用高温工艺和(高浓度或剂量)的臭氧试剂之前密封电极(即,产生高K氧化锆 基层)。 在一些实施例中,阻挡层也可以是基于氧化锆的,例如掺杂或未掺杂的无定形氧化锆的薄层。 以这种方式制造器件有助于基于氧化锆和氮化钛形成具有大于40的介电常数的器件,并且通常有助于产生更便宜的,越来越致密的DRAM电池和其它半导体结构。
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