Rubber composition containing functionalized polymer nanoparticles
    1.
    发明授权
    Rubber composition containing functionalized polymer nanoparticles 有权
    含有官能化聚合物纳米粒子的橡胶组合物

    公开(公告)号:US07897690B2

    公开(公告)日:2011-03-01

    申请号:US12504255

    申请日:2009-07-16

    IPC分类号: C08F279/00

    摘要: A polymer nanoparticle is provided. The nanoparticle includes an inner layer having alkenylbenzene monomer units. The nanoparticle further includes an outer layer having monomer units selected from conjugated dienes, alkylenes, alkenylbenzenes, and mixtures thereof. The nanoparticle has at least one functional group associated with the outer layer. Applications of use as additives for rubber, including the rubber compositions, are also provided.

    摘要翻译: 提供聚合物纳米颗粒。 纳米颗粒包括具有烯基苯单体单元的内层。 纳米颗粒还包括具有选自共轭二烯,亚烷基,链烯基苯及其混合物的单体单元的外层。 纳米颗粒具有与外层相关联的至少一个官能团。 还提供了用作橡胶添加剂的应用,包括橡胶组合物。

    Rubber composition containing functionalized polymer nanoparticles
    3.
    发明授权
    Rubber composition containing functionalized polymer nanoparticles 有权
    含有官能化聚合物纳米粒子的橡胶组合物

    公开(公告)号:US07718737B2

    公开(公告)日:2010-05-18

    申请号:US10791177

    申请日:2004-03-02

    IPC分类号: C08F279/00

    摘要: A polymer nanoparticle is provided. The nanoparticle includes an inner layer having alkenylbenzene monomer units. The nanoparticle further includes an outer layer having monomer units selected from conjugated dienes, alkylenes, alkenylbenzenes, and mixtures thereof. The nanoparticle has at least one functional group associated with the outer layer. Applications of use as additives for rubber, including the rubber compositions, are also provided.

    摘要翻译: 提供聚合物纳米颗粒。 纳米颗粒包括具有烯基苯单体单元的内层。 纳米颗粒还包括具有选自共轭二烯,亚烷基,链烯基苯及其混合物的单体单元的外层。 纳米颗粒具有与外层相关联的至少一个官能团。 还提供了用作橡胶添加剂的应用,包括橡胶组合物。

    Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
    4.
    发明授权
    Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties 失效
    纳米尺寸的无机金属颗粒,其制备及其在改进橡胶性能中的应用

    公开(公告)号:US07560510B2

    公开(公告)日:2009-07-14

    申请号:US11642124

    申请日:2006-12-20

    IPC分类号: C08L53/00

    摘要: Provided are enophile functionalized polymer particles, nano-sized inorganic metal particles such as Al(OH)3 particles, and preparations thereof. Also provided is a method of improving the properties of a rubber composition, such as a tire, by formulating the rubber to incorporate nano-sized inorganic metal particles such as Al(OH)3. The composition exhibits improved properties including bonding rubber, tensile strength, tear strength, and wet traction, among others. A novel rubber composition comprising nano-sized inorganic metal particles is also disclosed.

    摘要翻译: 提供亲本官能化聚合物颗粒,诸如Al(OH)3颗粒的纳米尺寸无机金属颗粒及其制剂。 还提供了通过配制橡胶来改善橡胶组合物如轮胎的性能的方法,以纳入纳米尺寸的无机金属颗粒如Al(OH)3。 组合物表现出改善的性能,包括粘合橡胶,拉伸强度,撕裂强度和湿牵引等。 还公开了一种包含纳米尺寸无机金属颗粒的新型橡胶组合物。

    Nano-sized polymer-metal composites
    5.
    发明授权
    Nano-sized polymer-metal composites 失效
    纳米级聚合物 - 金属复合材料

    公开(公告)号:US07112369B2

    公开(公告)日:2006-09-26

    申请号:US10791491

    申请日:2004-03-02

    IPC分类号: B32B5/16

    摘要: A polymer nanoparticle is provided. The nanoparticle includes an inner layer having alkenylbenzene monomer units. The nanoparticle further includes an outer layer having monomer units selected from conjugated dienes, alkylenes, alkenylbenzenes, and mixtures thereof. The nanoparticle has at least one functional group associated with the outer layer. The nanoparticle further has at least one metal complexed with said functional group. The nanoparticles can be used as a templates for preparation of nano-sized metal crystals and polymer-metal nanocomposite.

    摘要翻译: 提供聚合物纳米颗粒。 纳米颗粒包括具有烯基苯单体单元的内层。 纳米颗粒还包括具有选自共轭二烯,亚烷基,链烯基苯及其混合物的单体单元的外层。 纳米颗粒具有与外层相关联的至少一个官能团。 纳米颗粒还具有与所述官能团络合的至少一种金属。 纳米颗粒可用作制备纳米尺寸金属晶体和聚合物金属纳米复合材料的模板。

    Anionic polymerization initiators for preparing macro-branched diene rubbers
    7.
    发明授权
    Anionic polymerization initiators for preparing macro-branched diene rubbers 有权
    用于制备大分子量二烯橡胶的阴离子聚合引发剂

    公开(公告)号:US06271314B1

    公开(公告)日:2001-08-07

    申请号:US09569253

    申请日:2000-05-11

    IPC分类号: C08F29702

    摘要: Novel solid supported anionic polymerization initiators that are multiply metalated with Group IA alkali metal atoms are provided and employed to produce extremely high molecular weight branched diene polymers. The initiators are prepared by metalating a particle comprising a thermoplastic polymer or a cured elastomer in the presence of a polar coordinator. The polymers obtained by anionic polymerization employing the initiators are multiply branched, with a polymer chain covalently attached to the particle at virtually every metalation site. The macro-branched polymers exhibit desirable properties, such as an extremely high molecular weight, a controlled molecular weight distribution, Tg and vinyl content, and the ability to readily absorb hydrocarbon solvents and oils. The polymers are easily compounded to form vulcanizable elastomeric compounds and articles that have excellent resistance to wear and tear and exhibit reduced hysteresis properties.

    摘要翻译: 提供和使用与IA族碱金属原子多金属化的新型固体负载型阴离子聚合引发剂,用于生产极高分子量支链二烯聚合物。 引发剂通过在极性配位体的存在下金属化包含热塑性聚合物或固化的弹性体的颗粒来制备。 通过使用引发剂的阴离子聚合获得的聚合物是多支化的,聚合物链几乎在每个金属化位点共价连接到颗粒上。 大分支聚合物显示出所需的性能,例如极高的分子量,受控的分子量分布,Tg和乙烯基含量,以及容易吸收烃溶剂和油的能力。 聚合物易于复合以形成具有优异的耐磨性和耐撕裂性并且具有降低的滞后性能的可硫化弹性体化合物和制品。

    Solution masterbatch process using finely ground fillers for low hysteresis rubber
    10.
    发明授权
    Solution masterbatch process using finely ground fillers for low hysteresis rubber 有权
    使用精细研磨填料的低磁滞橡胶的溶液母料处理

    公开(公告)号:US07790798B2

    公开(公告)日:2010-09-07

    申请号:US11321496

    申请日:2005-12-29

    IPC分类号: C08K3/34

    摘要: Methods are provided for making solution masterbatches containing a diene elastomer in an organic solvent and a silica filler, having a first average particle size, that is ground in an organic solvent to form a silica having a reduced second average particle size. Grinding of the silica in the organic solvent, with or without other ingredients including the elastomer, produces a solution masterbatch in which the silica is mixed with and well dispersed in the elastomer. The use of such desolventized solution masterbatches in vulcanizable rubber compounds results in excellent processing characteristics allowing for the reduced use of processing aids such as oil. The compound also demonstrates improved properties, including reduced hysteresis.

    摘要翻译: 提供了用于在有机溶剂中制备含有二烯弹性体的溶液母料和具有第一平均粒径的二氧化硅填料的方法,其在有机溶剂中研磨以形成具有降低的第二平均粒径的二氧化硅。 在有机溶剂中研磨二氧化硅,包括或不含弹性体的其它成分,产生溶液母料,其中二氧化硅与弹性体混合并充分分散在其中。 在可硫化橡胶化合物中使用这种脱溶剂溶液母料导致优异的加工特性,可以减少使用加工助剂如油。 该化合物还表现出改进的性能,包括减少滞后。