Asymmetrical tin-coupled rubbery polymers
    6.
    发明授权
    Asymmetrical tin-coupled rubbery polymers 失效
    不对称锡偶联橡胶聚合物

    公开(公告)号:US6043321A

    公开(公告)日:2000-03-28

    申请号:US8716

    申请日:1998-01-19

    摘要: Tire rubbers which are prepared by anionic polymerization are frequently coupled with a suitable coupling agent, such as a tin halide, to improve desired properties. It has been unexpectedly found that greatly improved properties for tire rubbers, such as lower hysteresis, can be attained by asymmetrically coupling the rubber. This invention more specifically discloses an asymmetrical tin-coupled rubbery polymer which is particularly valuable for use in manufacturing tire tread compounds, said asymmetrical tin-coupled rubbery polymer being comprised of a tin atom having at least three polydiene arms covalently bonded thereto, wherein at least one of said polydiene arms has a number average molecular weight of less than about 40,000, wherein at least one of said polydiene arms has a number average molecular weight of at least about 80,000, and wherein the ratio of the weight average molecular weight to the number average molecular weight of the asymmetrical tin-coupled rubbery polymer is within the range of about 2 to about 2.5.

    摘要翻译: 通过阴离子聚合制备的轮胎橡胶通常与合适的偶合剂如卤化锡偶联,以改善所需的性能。 已经意外地发现,通过不对称地连接橡胶,可以获得轮胎橡胶的较大改善的性能,例如较低的滞后。 本发明更具体地公开了一种非对称锡 - 偶联橡胶状聚合物,其特别有价值地用于制造轮胎胎面胶料,所述不对称锡 - 偶联橡胶状聚合物由具有至少三个与其共价结合的聚二烯臂的锡原子组成,其中至少 所述聚二烯臂之一具有小于约40,000的数均分子量,其中所述聚二烯臂中的至少一个具有至少约80,000的数均分子量,并且其中重均分子量与数 不对称锡 - 偶联橡胶状聚合物的平均分子量在约2至约2.5的范围内。

    Asymmetrical tin-coupled rubbery polymers
    8.
    发明授权
    Asymmetrical tin-coupled rubbery polymers 失效
    不对称锡偶联橡胶聚合物

    公开(公告)号:US06420484B1

    公开(公告)日:2002-07-16

    申请号:US09968464

    申请日:2001-10-01

    IPC分类号: C08F842

    CPC分类号: C08C19/44

    摘要: Tire rubbers which are prepared by anionic polymerization are frequently coupled with a suitable coupling agent, such as a tin halide, to improve desired properties. It has been unexpectedly found that greatly improved properties for tire rubbers, such as lower hysteresis, can be attained by asymmetrically coupling the rubber. This invention more specifically discloses an asymmetrical tin-coupled rubbery polymer which is particularly valuable for use in manufacturing tire tread compounds, said asymmetrical tin-coupled rubbery polymer being comprised of a tin atom having at least three polydiene arms covalently bonded thereto, wherein said polydiene arms have a weight average molecular weight which is within the range of about 80,000 to about 300,000, wherein the polydiene arms do not contain blocks of more than about 4 repeat units of vinyl aromatic monomers, and wherein the ratio of the weight average molecular weight to the number average molecular weight of the asymmetrical tin-coupled rubbery polymer is within the range of about 1.4 to about 2.0.

    摘要翻译: 通过阴离子聚合制备的轮胎橡胶通常与合适的偶合剂如卤化锡偶联,以改善所需的性能。 已经意外地发现,通过不对称地连接橡胶,可以获得轮胎橡胶的较大改善的性能,例如较低的滞后。 本发明更具体地公开了一种非对称锡 - 偶联橡胶状聚合物,其特别有价值地用于制造轮胎胎面胶料,所述不对称锡 - 偶联橡胶状聚合物由具有共价键合至少三个聚二烯臂的锡原子组成,其中所述聚二烯 臂的重均分子量在约80,000至约300,000的范围内,其中聚二烯臂不含有大于约4个重复单元的乙烯基芳族单体的嵌段,并且其中重均分子量与 不对称锡偶联橡胶状聚合物的数均分子量在约1.4至约2.0的范围内。