Polymer alloy of polyarylene thioether and a process for producing the
same
    1.
    发明授权
    Polymer alloy of polyarylene thioether and a process for producing the same 失效
    聚亚芳基硫醚的聚合物合金及其制备方法

    公开(公告)号:US5134206A

    公开(公告)日:1992-07-28

    申请号:US668146

    申请日:1991-03-11

    IPC分类号: C08F283/00

    CPC分类号: C08F283/00

    摘要: Disclosed herein are a polymer alloy prepared by polymerizing 0.1 to 100 parts by weight of at least one radically polymerizable monomer to 100 parts by weight of polyarylene thioether having a repeating unit of ##STR1## as a main constituent and at least a part of said radically polymerizable monomers is polymerized within inner pores of the polyarylene thioether particles and a process for producing the polymer alloy.The polymer alloy of polyarylene thioether according to the present invention has the fine particles of the radically polymerized monomer uniformly dispersed in the said polymer alloy, and accordingly, the polymer alloy of polyarylene thioether according to the present invention is excellent in various physical properties, such as, good impact strength and improved anti-flash property.

    摘要翻译: 本文公开了一种聚合物合金,其通过将0.1至100重量份的至少一个可自由基聚合的单体聚合至100重量份的具有作为主要成分的重复单元的聚亚芳基硫醚和至少一部分所述基本上 可聚合单体在聚亚芳基硫醚颗粒的内孔内聚合,以及聚合物合金的制造方法。 根据本发明的聚芳硫醚的聚合物合金具有在所述聚合物合金中均匀分散的自由基聚合单体的细颗粒,因此本发明的聚亚芳基硫醚的聚合物合金具有优异的各种物理性能,例如 冲击强度好,抗闪光性能好。

    Heat-resistant stretched film and production process thereof
    7.
    发明授权
    Heat-resistant stretched film and production process thereof 失效
    耐热拉伸膜及其制造方法

    公开(公告)号:US5286814A

    公开(公告)日:1994-02-15

    申请号:US690318

    申请日:1991-04-26

    摘要: A heat-resistant stretched film is obtained by stretching a resin composition comprising 100 parts by weight of a poly(arylene sulfide) of a substantially linear structure and 5 to less than 100 parts by weight of a melt-stable poly(arylene thioether-ketone). The poly(arylene sulfide) has a melt viscosity of at least 1,000 poises as measured at 310.degree. C. and a shear rate of 200 sec.sup.-1. The poly(arylene thioether-ketone) has predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- groups are bonded in the para position to each other through the benzene ring, and has the following physical properties (a)-(c):(a) a melting point, Tm being 310.degree.-380.degree. C.;(b) a melt crystallization temperature, Tmc (420.degree. C./10 min) being at least 210.degree. C. and a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) being at least 10 J/g; and(c) a reduced viscosity being 0.3-2 dl/g at 25.degree. C. and a polymer concentration of 0.5 g/dl in 98% sulfuric acid.

    摘要翻译: 通过拉伸含有100重量份基本上线性结构的聚(亚芳基硫醚)和5至小于100重量份熔体稳定的聚(亚芳基硫醚 - 酮)的树脂组合物来获得耐热拉伸膜 )。 聚(亚芳基硫醚)在310℃下测得的熔体粘度至少为1,000泊,剪切速率为200秒-1。 聚(亚芳基硫醚酮)具有主要的式(*化学结构*)的重复单元,其中-CO-和-S-基通过苯环彼此键合在对位,并且具有以下物理 性质(a) - (c):(a)熔点,Tm为310-380℃。 (b)熔融结晶温度Tmc(420℃/分钟)至少为210℃,残余熔融结晶焓(ΔH)为420℃至10℃ /G; 和(c)在25℃下的比浓粘度为0.3-2dl / g,在98%硫酸中的浓度为0.5g / dl。