摘要:
In connection with a process of implementing galvanizing and galvannealing on steel strips containing highly oxidizable elements such as Si, Mn, P, Ti, Nb, Al, Ni, Cu, Mo, V, Cr, and B, after annealing in a continuous line or implementing electroplating after annealing, the present invention provides a method for restraining non-plating at low cost in a stable manner and a surface treated steel strip having minimal non-plating. By applying on at least one surface of a steel strip a Fe plating having a coating weight of 0.1-10 g/m.sup.2 and an oxygen content of 0.1-10 wt %, followed by annealing and then zinc or zinc alloy plating, there is obtained a surface treated steel strip having minimal plating defects which includes a Fe plating layer immediately below a zinc or zinc alloy plating layer and a steel alloying element concentrated stratum immediately below the Fe plating layer. The Fe plating may be formed using an electroplating bath which contains 0.1-10 g/l of Fe.sup.3+ and a carboxylic acid or an alkali metal salt thereof.
摘要翻译:PCT No.PCT / JP93 / 00394 Sec。 371日期1994年04月12日 102(e)日期1994年4月12日PCT 1993年3月30日PCT公布。 公开号WO93 / 20254 日期:1993年10月14日。关于在含有高度可氧化元素如Si,Mn,P,Ti,Nb,Al,Ni,Cu,Mo,V,Cr和B的钢带上实施镀锌和镀锌合金的过程 在退火后连续退火或实施电镀后,本发明提供了一种以低成本稳定地抑制非电镀的方法和具有最小非电镀的表面处理钢带的方法。 通过在钢带的至少一个表面上涂布涂布重量为0.1-10g / m 2,氧含量为0.1-10wt%的Fe镀层,然后进行退火,然后进行锌或锌合金镀覆 具有最小电镀缺陷的表面处理钢带,其包括在锌或锌合金镀层正下方的Fe镀层和紧邻Fe镀层下方的钢合金元素浓缩层。 可以使用含有0.1-10g / l Fe 3+和羧酸或其碱金属盐的电镀浴形成Fe镀层。
摘要:
A method of manufacturing a galvanized steel sheet with high press formability, the sheet having an inorganic compound on a metallic galvanized-layer thereof. The method includes the step of effecting a galvanization on a steel sheet followed by an alloying treatment. The sheet of galvanized steel is immersed in a bath of an aqueous solution containing 0.1 wt % or more of borate of an alkali metal, and then taking the steel sheet out of the bath and effecting such control as to make the amount of deposition of the water-containing borate film on the steel sheet surface to range from 10 to 1,000 mg/m.sup.2, and then heating the steel sheet at a temperature ranging from 60.degree. to 400.degree. C. Thereafter, the steel sheet is cooled to a normal temperature.
摘要翻译:一种制造具有高压制成形性的镀锌钢板的方法,该片材在其金属镀锌层上具有无机化合物。 该方法包括在钢板上实施镀锌,然后进行合金化处理的步骤。 将该镀锌钢板浸渍在含有0.1重量%以上的碱金属硼酸盐的水溶液浴中,然后将钢板从镀液中取出,进行这样的控制,使得 含水硼酸盐膜在钢板表面上的范围为10〜1000mg / m 2,然后在60〜400℃的温度范围内加热钢板。然后将钢板冷却至常温。
摘要:
The invention provides an aluminum alloy sheet having improved formability, an elongation of at least 30%, a sliding frictional resistance of up to 0.13 and minimized surface pressure dependency of sliding frictional resistance, comprising an aluminum alloy substrate containing at least 4 wt % of Mg and a Fe rich plating layer on a surface thereof in a coating weight of 1 to 50 g/m.sup.2. Also provided is a bake hardenable, surface treated aluminum alloy sheet having improved formability, an elongation of at least 25%, a sliding frictional resistance of up to 0.13 and minimized surface pressure dependency of sliding frictional resistance, comprising a bake hardenable aluminum alloy substrate containing Mg and Si in an amount of at least 0.4 wt % calculated as Mg.sub.2 Si and a Fe rich plating layer on a surface thereof in coating weight of 1 to 50 g/m.sup.2. By forming a zincate layer as an undercoat below the Fe rich plating layer, the plating adhesion is further improved. The preferred Fe rich plating layer is a Fe-Zn alloy plating layer containing 20 to 80 wt % of Zn for corrosion resistance improvement. A Fe-Zn alloy plating layer containing 30 to 40 wt % of Zn meets both formability and corrosion resistance.
摘要:
A zinc or zinc-alloy plated steel sheet having an improved weldability and plating properties, as well as a method for making the same is provided. Even when the substrate steel sheet is the one which is difficult to deposit a zinc or zinc-alloy layer by conventional methods, such as an extra low carbon steel sheet, the present invention enable a reliable production of a galvanized steel sheet suffering from no plating failure or insufficient adhesion as well as a reliable production of a galvannealed steel sheet suffering from no plating failure or streaking of the alloyed layer.The zinc or zinc-alloy plated steel sheet having improved weldability comprises an extra low carbon steel sheet, an iron-carbon plated layer or a carbon-rich layer generated by diffusion of the iron-carbon plated layer on at least one major surface of the extra low carbon steel sheet, and a zinc or zinc-alloy plated layer on the iron-carbon plated layer or the carbon-rich layer.The zinc or zinc-alloy plated steel sheet having improved weldability and/or plating properties is produced by depositing on the steel sheet an iron-carbon plated layer having a carbon content of from 0.01% by weight to 10% by weight to a coating weight of from 0 01 g/m.sup.2 to 10 g/m.sup.2, optionally annealing the iron-carbon plated steel sheet, and depositing a zinc or zinc-alloy plated layer, preferably by galvanizing or galvannealing, on the annealed steel sheet.
摘要翻译:提供具有改进的焊接性和电镀性能的锌或锌合金镀覆钢板及其制造方法。 即使基板钢板是通过常规方法难以沉积锌或锌合金层的钢板,例如超低碳钢板,本发明能够可靠地生产没有电镀的镀锌钢板 失效或不充分的粘合性,以及可靠地生产没有电镀失效或合金化层的条纹的合金化热镀锌钢板。 具有改善的焊接性的锌或锌合金镀覆钢板包括通过铁碳镀层在至少一个主表面上扩散而产生的超低碳钢板,铁碳镀层或富碳层 铁碳镀层或富碳层上的锌或锌合金镀层。 通过在碳钢板上沉积碳含量为0.01重量%〜10重量%的铁碳镀层,涂布量为1重量%以上,制成具有改善的焊接性和/或电镀性能的锌或锌合金镀覆钢板 为0.01g / m 2至10g / m 2,可选择地对含铁碳素钢板进行退火,并且优选通过镀锌或合金化退火将锌或锌合金镀层沉积在退火钢板上。
摘要:
A zinc or zinc-alloy plated steel sheet having an improved weldability and plating properties, as well as a method for making the same is provided. Even when the substrate steel sheet is the one which is difficult to deposit a zinc or zinc-alloy layer by conventional methods, such as an extra low carbon steel sheet, the present invention enables a reliable production of a galvanized steel sheet suffering from no plating failure of insufficient adhesion as well as a reliable production of a galvanized steel sheet suffering from no plating failure or streaking of the alloyed layer. The zinc or zinc-alloy plated steel sheet having improved weldability comprises an extra low carbon steel sheet, an iron-carbon plated layer or a carbon-rich layer generated by diffusion of the iron-carbon plated layer on at least one major surface of the extra low carbon steel sheet, and a zinc or zinc-alloy plated layer on the iron-carbon plated layer or the carbon-rich layer. The zinc or zinc-alloy plated steel sheet having improved weldability and/or plating properties is produced by depositing on the steel sheet an iron-carbon plated layer having a carbon content of from 0.01% by weight to 10% by weight to a coating weight of from 0.01 g/m.sup.2 to 10 g/m.sup.2, optionally annealing the iron-carbon plated steel sheet, and depositing a zinc or zinc-alloy plated layer, preferably by galvanizing or galvannealing, on the annealed steel sheet.
摘要翻译:提供具有改进的焊接性和电镀性能的锌或锌合金镀覆钢板及其制造方法。 即使基板钢板是通过常规方法难以沉积锌或锌合金层的钢板,例如超低碳钢板,本发明能够可靠地生产没有电镀的镀锌钢板 无法实现不良的附着力,可靠地生产没有电镀不良或合金化层的条纹的镀锌钢板。 具有改善的焊接性的锌或锌合金镀覆钢板包括通过铁碳镀层在至少一个主表面上扩散而产生的超低碳钢板,铁碳镀层或富碳层 铁碳镀层或富碳层上的锌或锌合金镀层。 通过在碳钢板上沉积碳含量为0.01重量%〜10重量%的铁碳镀层,涂布量为1重量%以上,制成具有改善的焊接性和/或电镀性能的锌或锌合金镀覆钢板 为0.01g / m 2至10g / m 2,可选择地对该铁碳钢进行退火,并且优选通过镀锌或合金化退火将锌或锌合金镀层沉积在退火钢板上。
摘要:
A process for the manufacture of tinplates comprising electroplating a substrate in a fused-chloride tin plating bath at a temperature of about 150.degree. to 350.degree. C., a current density of about 100 to 500 A/dm.sup.2 in an atmosphere of a non-oxidizing gas. This process may be converted to a process for the manufacture of reflow type tinplates by only changing the bath temperature, and vice versa. For the manufacture of no-reflow type tinplates, the bath is kept at 150.degree. to 232.degree. C., while for the manufacture of reflow type tinplates, the bath is kept at 233.degree. to 350.degree. C. In these cases, the bath includes SnCl.sub.2 and at least one member selected from the group consisting of KCl, NaCl, LiCl and AlCl.sub.3, and may preferably be operated while flowing the bath at a flow rate of about 0.1 m/sec higher. There is provided equipment for the manufacture of tin-plated steel strip comprising a pretreating apparatus for cold rolling steel strip, an annealing apparatus, a skin pass rolling apparatus, a fused-salt tin-electroplating apparatus with the above bath including chlorides, and an aftertreating apparatus, these apparatus being continuously integrated into the equipment by use of a fused-salt bath.
摘要:
A method of guiding and transferring a rapidly quenched metallic tape includes steps of peeling the rapidly quenched metallic tape produced by solidification through rapid quenching on a circumferential surface of a single cooling roll rotating at a high speed, introducing the metallic tape into a cylindrical transfer guide to a pinch roll unit arranged at a terminal end of the transfer guide to catch the metallic tape by the pinch roll unit, and moving the pinch roll unit to a winder for the metal tape. The metallic tape is fed in the transfer guide substantially without being in contact with the transfer guide. An apparatus for guiding and transferring a rapidly quenched metallic tape includes a cylindrical transfer guide arranged on a normal line of a single cooling roll for introducing and guiding the metallic tape, a pinch roll unit arranged at a terminal end of the transfer guide for catching the metallic tape, and a transfer trolley for transferring the pinch roll unit to a winder for the metallic tape.
摘要:
Zn--Cr alloy plated steel sheets have excellent corrosion resistance. It has now been found that the phase structures of Zn--Cr alloy platings are such that they comprise yet to be known phases .eta.x, .delta.x and .GAMMA.x. Furthermore, these phases when taken either singly or with two or more phases being mixed together, exhibit the following characteristics (1)-(6). The characteristics of the respective phases are also identified below.______________________________________(1) .eta.x Resistance to cosmetic corrosion(2) .GAMMA.x Formability(3) .eta.x + .delta.x Chipping resistance(4) .eta.x + .GAMMA.x Corrosion resistance in the as-formed state(5) .delta.x + .GAMMA.x Water resistant secondary adherence of coating(6) .eta.x + .delta.x + .GAMMA.x Perforation corrosion resistance.eta.x: Hexagonal crystal a = 2.66-2.74 .ANG. c = 4.61-4.95 .ANG..delta.x: Hexagonal crystal a = 2.72-2.78 .ANG. c = 4.43-4.60 .ANG..GAMMA.x: Cubic crystal a = 3.00-3.06 .ANG.______________________________________
摘要:
The present invention provides a method of producing a zinc-chromium alloy-plated steel sheet having excellent properties such as bare corrosion resistance, corrosion resistance after coating, plating adhesiveness and weldability.The method is characterized by plating the surface of the steel sheet using an acid plating bath containing zinc ion (Zn.sup.2+) and chromium ion (Cr.sup.3+) at a molar concentration ratio of about 0.1.ltoreq.Cr.sup.3+ /(Zn.sup.3+ +Cr.sup.3+).ltoreq.0.9 in a total amount of at least about 0.5 mol/1 within the dissolution range, and about 0.1 to 30 g/1 of at least one nonionic organic additive having at least a triple bond, at a bath temperature of about 25.degree. to 70.degree. C. and a pH of about 1.0 to 4.0 with a current density of about 50 to 200 A/dm.sup.2.
摘要:
The improved organic composite coated steel plate includes a zinc or zinc alloy plated steel plate as a substrate that has on its surface a chromate film the Cr.sup.6+ content of which is no more than 70% of the total Cr content and which is deposited in an amount of 5-500 mg/m.sup.2 in terms of metallic chromium, the chromate film being overlaid with a resin layer that is deposited in an amount of 0.1-3 g/m.sup.2 on a dry weight basis and which is formed primarily of water-dispersed silica and one organic resin member as selected from the group consisting of an anionic aqueous resin, a nonionic aqueous resin and an anionic aqueous urethane resin. This steel plate is adapted for not contaminating the environment of the earth in the process of its manufacture.
摘要翻译:改进的有机复合涂层钢板包括锌或锌合金镀覆钢板作为基材,其表面上具有Cr6 +含量不超过总Cr含量的70%并以一定量沉积的铬酸盐膜 以金属铬计为5-500mg / m 2,铬酸盐膜覆盖有以干重计为0.1-3g / m 2的量沉积的树脂层,主要由水分散二氧化硅 和一种选自阴离子水性树脂,非离子水性树脂和阴离子水性聚氨酯树脂的有机树脂构件。 该钢板适用于在制造过程中不污染地球的环境。