公开(公告)号：US5447802A

公开(公告)日：1995-09-05

申请号：US157069

申请日：1994-04-12

申请人： Yoichi Tobiyama ,  Chiaki Kato ,  Nobuyuki Morito ,  Shigeru Umino

发明人： Yoichi Tobiyama ,  Chiaki Kato ,  Nobuyuki Morito ,  Shigeru Umino

IPC分类号： C23C2/02 ,  C25D3/20 ,  C25D5/10 ,  B32B15/18 ,  C23C2/06 ,  C23C28/02

CPC分类号： B32B15/013 ,  C22C38/002 ,  C22C38/004 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/12 ,  C22C38/14 ,  C23C2/02 ,  C25D3/20 ,  C25D5/10 ,  Y10S428/935 ,  Y10S428/939 ,  Y10T428/12458 ,  Y10T428/1266 ,  Y10T428/12799 ,  Y10T428/12958

摘要： In connection with a process of implementing galvanizing and galvannealing on steel strips containing highly oxidizable elements such as Si, Mn, P, Ti, Nb, Al, Ni, Cu, Mo, V, Cr, and B, after annealing in a continuous line or implementing electroplating after annealing, the present invention provides a method for restraining non-plating at low cost in a stable manner and a surface treated steel strip having minimal non-plating. By applying on at least one surface of a steel strip a Fe plating having a coating weight of 0.1-10 g/m.sup.2 and an oxygen content of 0.1-10 wt %, followed by annealing and then zinc or zinc alloy plating, there is obtained a surface treated steel strip having minimal plating defects which includes a Fe plating layer immediately below a zinc or zinc alloy plating layer and a steel alloying element concentrated stratum immediately below the Fe plating layer. The Fe plating may be formed using an electroplating bath which contains 0.1-10 g/l of Fe.sup.3+ and a carboxylic acid or an alkali metal salt thereof.

摘要翻译： PCT No.PCT / JP93 / 00394 Sec。 371日期1994年04月12日 102（e）日期1994年4月12日PCT 1993年3月30日PCT公布。 公开号WO93 / 20254 日期：1993年10月14日。关于在含有高度可氧化元素如Si，Mn，P，Ti，Nb，Al，Ni，Cu，Mo，V，Cr和B的钢带上实施镀锌和镀锌合金的过程 在退火后连续退火或实施电镀后，本发明提供了一种以低成本稳定地抑制非电镀的方法和具有最小非电镀的表面处理钢带的方法。 通过在钢带的至少一个表面上涂布涂布重量为0.1-10g / m 2，氧含量为0.1-10wt％的Fe镀层，然后进行退火，然后进行锌或锌合金镀覆 具有最小电镀缺陷的表面处理钢带，其包括在锌或锌合金镀层正下方的Fe镀层和紧邻Fe镀层下方的钢合金元素浓缩层。 可以使用含有0.1-10g / l Fe 3+和羧酸或其碱金属盐的电镀浴形成Fe镀层。

公开(公告)号：US5487919A

公开(公告)日：1996-01-30

申请号：US175682

申请日：1993-12-29

申请人： Yoichi Tobiyama ,  Chiaki Kato ,  Nobuyuki Morito ,  Hajime Kimura

发明人： Yoichi Tobiyama ,  Chiaki Kato ,  Nobuyuki Morito ,  Hajime Kimura

IPC分类号： C10M103/06 ,  C10M173/02 ,  B05D3/00

CPC分类号： C10M103/06 ,  C10M173/02 ,  C10M2201/02 ,  C10M2201/0603 ,  C10M2201/0613 ,  C10M2201/062 ,  C10M2201/0623 ,  C10M2201/063 ,  C10M2201/0653 ,  C10M2201/0663 ,  C10M2201/08 ,  C10M2201/0803 ,  C10M2201/081 ,  C10M2201/082 ,  C10M2201/084 ,  C10M2201/085 ,  C10M2201/0853 ,  C10M2201/0863 ,  C10M2201/087 ,  C10M2201/0873 ,  C10M2201/10 ,  C10M2201/1006 ,  C10M2201/1023 ,  C10M2201/1033 ,  C10M2201/105 ,  C10M2201/1053 ,  C10M2201/123 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2250/121

摘要： A method of manufacturing a galvanized steel sheet with high press formability, the sheet having an inorganic compound on a metallic galvanized-layer thereof. The method includes the step of effecting a galvanization on a steel sheet followed by an alloying treatment. The sheet of galvanized steel is immersed in a bath of an aqueous solution containing 0.1 wt % or more of borate of an alkali metal, and then taking the steel sheet out of the bath and effecting such control as to make the amount of deposition of the water-containing borate film on the steel sheet surface to range from 10 to 1,000 mg/m.sup.2, and then heating the steel sheet at a temperature ranging from 60.degree. to 400.degree. C. Thereafter, the steel sheet is cooled to a normal temperature.

摘要翻译： 一种制造具有高压制成形性的镀锌钢板的方法，该片材在其金属镀锌层上具有无机化合物。 该方法包括在钢板上实施镀锌，然后进行合金化处理的步骤。 将该镀锌钢板浸渍在含有0.1重量％以上的碱金属硼酸盐的水溶液浴中，然后将钢板从镀液中取出，进行这样的控制，使得 含水硼酸盐膜在钢板表面上的范围为10〜1000mg / m 2，然后在60〜400℃的温度范围内加热钢板。然后将钢板冷却至常温。

公开(公告)号：US5322741A

公开(公告)日：1994-06-21

申请号：US30412

申请日：1993-04-16

申请人： Yasuji Uesugi ,  Koichi Hashiguchi ,  Yoshihiro Matsumoto ,  Makoto Imanaka ,  Takaaki Hira ,  Nobuyuki Morito ,  Yoichi Tobiyama ,  Nobuo Totsuka ,  Motohiro Nabae

发明人： Yasuji Uesugi ,  Koichi Hashiguchi ,  Yoshihiro Matsumoto ,  Makoto Imanaka ,  Takaaki Hira ,  Nobuyuki Morito ,  Yoichi Tobiyama ,  Nobuo Totsuka ,  Motohiro Nabae

IPC分类号： C23C2/02 ,  C23C2/28 ,  C23C28/00 ,  C23C30/00 ,  C25D5/44 ,  B32B15/20 ,  C22F1/04

CPC分类号： C23C30/00 ,  C23C2/02 ,  C23C2/28 ,  C23C28/00 ,  C25D5/44 ,  Y10T428/12736 ,  Y10T428/12757

摘要： The invention provides an aluminum alloy sheet having improved formability, an elongation of at least 30%, a sliding frictional resistance of up to 0.13 and minimized surface pressure dependency of sliding frictional resistance, comprising an aluminum alloy substrate containing at least 4 wt % of Mg and a Fe rich plating layer on a surface thereof in a coating weight of 1 to 50 g/m.sup.2. Also provided is a bake hardenable, surface treated aluminum alloy sheet having improved formability, an elongation of at least 25%, a sliding frictional resistance of up to 0.13 and minimized surface pressure dependency of sliding frictional resistance, comprising a bake hardenable aluminum alloy substrate containing Mg and Si in an amount of at least 0.4 wt % calculated as Mg.sub.2 Si and a Fe rich plating layer on a surface thereof in coating weight of 1 to 50 g/m.sup.2. By forming a zincate layer as an undercoat below the Fe rich plating layer, the plating adhesion is further improved. The preferred Fe rich plating layer is a Fe-Zn alloy plating layer containing 20 to 80 wt % of Zn for corrosion resistance improvement. A Fe-Zn alloy plating layer containing 30 to 40 wt % of Zn meets both formability and corrosion resistance.

摘要翻译： PCT No.PCT / JP92 / 00931 Sec。 371日期：1993年04月16日 102（e）日期1993年4月16日PCT提交1992年7月22日PCT公布。 第WO93 / 02225号公报 日本公开1993年2月4日。本发明提供一种铝合金板，其具有改进的成形性，伸长率至少为30％，滑动摩擦阻力高达0.13，并且滑动摩擦阻力的表面压力依赖性最小化，包括含有 表面上含有至少4重量％的Mg和富Fe镀层，涂层重量为1〜50g / m 2。 还提供了具有改进的成型性，至少25％的伸长率，至多0.13的滑动摩擦阻力和最小化的滑动摩擦阻力的表面压力依赖性的烘烤可硬化的表面处理的铝合金板，其包括含有 Mg和Si的量为至少0.4重量％，其表面上的Mg 2 Si和Fe富镀层的涂层重量为1至50g / m 2。 通过在富Fe镀层下形成作为底涂层的锌酸盐层，进一步提高镀层附着力。 优选的富Fe镀层是含有20〜80重量％的Zn以提高耐腐蚀性的Fe-Zn合金镀层。 含有30〜40重量％Zn的Fe-Zn合金镀层满足成型性和耐腐蚀性。

公开(公告)号：US06368728B1

公开(公告)日：2002-04-09

申请号：US09437671

申请日：1999-11-10

申请人： Yoichi Tobiyama ,  Chiaki Kato

发明人： Yoichi Tobiyama ,  Chiaki Kato

IPC分类号： B32B1501

CPC分类号： C23C2/28 ,  Y10T428/12799 ,  Y10T428/12993

摘要： Galvannealed steel sheet and method, made by applying hot-dip galvanizing to a steel sheet, heating at a heating rate of at least about 10° C./second to a maximum sheet temperature within a range of from about 470 to 550° C., and applying an alloying treatment; the Al content XAl% in the hot-dip galvannealing layer and the coating weight W g/m2 satisfy the following equation (1); thereby producing a Zn—Fe galvannealing layer having an iron content of from about 7 to 12%; the galvannealed steel sheet has intensities of &zgr;-phase, &dgr;1-phase and &Ggr;-phase that satisfy the following equations (4) and (5) as observed through X-ray diffraction with the galvannealing layer peeled off the galvannealed steel sheet at the galvannealing/steel sheet interface, and the galvannealed steel sheet having excellent press workability, having a whiteness and a glossiness within prescribed ranges: 5≦W×(XAl−0.12)≦15  (1) I(&zgr;:1.26)/I(&dgr;1:2.13)≦0.02  (4) I(&Ggr;:2.59)/I(&dgr;1:2.13)≦0.1  (5).

摘要翻译： 通过对钢板进行热浸镀锌而制成的热浸镀锌钢板和方法，以至少约10℃/秒的加热速度加热到最大板温度在约470〜550℃的范围内。 ，并进行合金化处理; 热浸镀锌层中的Al含量XAl％和涂布重量W g / m2满足下式（1）。 从而制造铁含量为约7-12％的Zn-Fe合金化合金层; 合金化热镀锌钢板具有如下的等式（4）和（5）的强度：z相，δ1相和Ggr相，如通过X射线衍射所观察到的，合金化退火层从合金化热镀锌钢板上剥离 合金化退火/钢板界面以及具有优异的压制加工性的合金化热浸镀锌钢板，其白度和光泽度在规定范围内：

公开(公告)号：US07160631B2

公开(公告)日：2007-01-09

申请号：US10492311

申请日：2002-10-23

申请人： Seiji Nakajima ,  Tomokatsu Katagiri ,  Yoichi Tobiyama ,  Chiaki Kato

发明人： Seiji Nakajima ,  Tomokatsu Katagiri ,  Yoichi Tobiyama ,  Chiaki Kato

IPC分类号： B32B7/04 ,  B32B5/16 ,  B32B15/18 ,  C23C22/05 ,  C23C22/68

CPC分类号： C23C2/26 ,  C23C28/00 ,  Y10T428/12535 ,  Y10T428/12583 ,  Y10T428/12611 ,  Y10T428/12799 ,  Y10T428/25 ,  Y10T428/273

摘要： The present invention provides for a zinc-based coated steel sheet having a zinc-based coating layer and a lubricant film, which is formed on the zinc-based coating layer, containing zinc phosphate particles in an amount of 50 wt. % or more, and having substantially no reaction layer formed by reaction between the zinc-based coating and the zinc phosphate particles, and a method for the manufacture thereof. The zinc-based coated steel sheet according to the present invention has an excellent anti-peeling property, excellent frictional property, even in the non-lubricated condition which occurs at areas where the press oil film is broken, and excellent anti-galling property.

摘要翻译： 本发明提供了一种锌基涂层钢板，其具有锌基涂层和润滑剂膜，其形成在锌基涂层上，其含有50重量％的磷酸锌颗粒。 ％以上，并且基本上没有通过锌基涂层和磷酸锌颗粒之间的反应形成的反应层及其制造方法。 本发明的锌系被覆钢板，即使在压榨油膜破裂的区域发生非润滑状态，也具有优异的抗磨损性，因此具有优异的抗剥离性，优异的摩擦性。

公开(公告)号：US06410163B1

公开(公告)日：2002-06-25

申请号：US09555339

申请日：2000-05-30

申请人： Yoshitsugu Suzuki ,  Kazunori Osawa ,  Chiaki Kato ,  Yoichi Tobiyama ,  Kei Sakata ,  Osamu Furukimi ,  Akio Shinohara

发明人： Yoshitsugu Suzuki ,  Kazunori Osawa ,  Chiaki Kato ,  Yoichi Tobiyama ,  Kei Sakata ,  Osamu Furukimi ,  Akio Shinohara

IPC分类号： B32B1501

CPC分类号： C23C2/28 ,  C22C38/001 ,  C22C38/04 ,  C22C38/12 ,  C22C38/38 ,  C23C2/02 ,  C23C2/06 ,  Y10S428/939 ,  Y10T428/12799

摘要： The present invention provides a high strength thin excellent workability and galvanizability, having a composition comprising from 0.01 to 0.20 wt. % C, up to 1.0 wt. % Si, from 1.0 to 3.0 wt. % Mn, up to 0.10 wt. % P, up to 0.05 wt. % S, up to 0.10 wt. % Al, up to 0.010 wt. % N, up to 1.0 wt. % Cr, from 0.001 to 1.00 wt. % Mo, and the balance Fe and incidental impurities, wherein a band structure comprising a secondary phase has a thickness satisfying the relation Tb/T≦0.005 (where, Tb: average thickness of the band structure in the thickness direction of steel sheet; T: steel sheet thickness), and a manufacturing method thereof, and a manufacturing method of a high strength hot-dip galvanized steel sheet or a high strength galvannealed steel sheet applying hot-dip galvanizing or further galvannealing, and giving an excellent workability, a high tensile strength, and excellent galvanizability, coating adhesion and corrosion resistance.

摘要翻译： 本发明提供高强度的优异的加工性和镀锌性，其组成包含0.01至0.20wt。 ％C，高达1.0wt。 ％Si，1.0〜3.0wt。 ％Mn，至多0.10wt。 ％P，高达0.05wt。 ％S，高达0.10wt。 ％Al，最高0.010wt。 ％N，至多1.0wt。 ％Cr，0.001〜1.00wt。 ％Mo，余量为Fe和附带杂质，其中包含二次相的带结构的厚度满足Tb / T <= 0.005（其中，Tb：钢带厚度方向上带状结构的平均厚度） T：钢板厚度）及其制造方法，以及采用热浸镀锌或进一步合金化处理的高强度热浸镀锌钢板或高强度合金化热浸镀锌钢板的制造方法，赋予优异的加工性， 高拉伸强度，优异的镀锌性，涂层附着力和耐腐蚀性。

公开(公告)号：US20140034195A1

公开(公告)日：2014-02-06

申请号：US14112717

申请日：2012-04-19

申请人： Mikito Suto ,  Katsumi Kojima ,  Masaki Tada ,  Takumi Tanaka ,  Yoichi Tobiyama

发明人： Mikito Suto ,  Katsumi Kojima ,  Masaki Tada ,  Takumi Tanaka ,  Yoichi Tobiyama

IPC分类号： C21D8/02 ,  C22C38/00 ,  C22C38/02 ,  C22C38/06 ,  C22C38/04

CPC分类号： C21D8/0263 ,  C21D8/02 ,  C21D9/46 ,  C22C38/001 ,  C22C38/002 ,  C22C38/004 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06

摘要： A steel sheet containing C: 0.0005% or more and 0.0035% or less, Si: 0.05% or less, Mn: 0.1% or more and 0.6% or less, P: 0.02% or less, S: less than 0.02%, Al: 0.01% or more and less than 0.10%, N: 0.0030% or less, B: 0.0010% or more, in which the relationship B/N≦3.0 is satisfied and the balance being Fe and inevitable impurities, and a microstructure in which the average integrated intensity f in the (111)[1-10] to (111)[-1-12] orientations on a plane parallel to a sheet surface at a position located at ¼ of the thickness of the steel sheet is 7.0 or more, in which an average ferrite grain size is 6.0 μm or more and 10.0 μm or less, and the relationships EAVE≧215 GPa, E0≧210 GPa, E45≧210 GPa, E90≧210 GPa, and −0.4≦Δr≦0.4 are satisfied.

摘要翻译： 含有C：0.0005％以上且0.0035％以下，Si：0.05％以下，Mn：0.1％以上0.6％以下的钢板，P：0.02％以下，S：0.02％以下，Al ：0.01％以上且小于0.10％，N：0.0030％以下，B：0.0010％以上，其中满足B/N@3.0的关系，余量为Fe和不可避免的杂质，以及其中 在位于钢板厚度¼的位置处平行于片材表面的平面上的（111）[1-10]至（111）[ - 1-12]取向中的平均积分强度f为7.0或 平均铁素体晶粒尺寸为6.0μm以上10.0μm以下，EAVE> = 215GPa，E0> = 210GPa，E45> = 210GPa，E90> = 210GPa，-0.4 @ Deltar @ 0.4满意。

公开(公告)号：US20130327116A1

公开(公告)日：2013-12-12

申请号：US13994103

申请日：2011-12-13

申请人： Mikito Suto ,  Katsumi Kojima ,  Yusuke Nakagawa ,  Masaki Tada ,  Yoichi Tobiyama

发明人： Mikito Suto ,  Katsumi Kojima ,  Yusuke Nakagawa ,  Masaki Tada ,  Yoichi Tobiyama

IPC分类号： B21C37/06

CPC分类号： B21C37/06 ,  B21D5/00 ,  B21D5/015 ,  B21D51/10

摘要： An object of the present invention is to provide a method for designing a metal material having mechanical properties with which a specified spring back angle can be achieved after any one of metal materials having a wide variety of mechanical properties and thicknesses has been formed by performing cylinder forming and a product formed by using the method. A method for designing a material to be subjected to cylinder forming, the method including, in the design of a metal material to be subjected to cylinder forming in which the metal material is formed by performing bending forming, calculating the yield strength YP, the Young's modulus E and the thickness t of the metal material so that a spring back angle Δθ becomes a specified value when cylinder forming is performed under conditions of a radius of curvature of bending r of 5 mm or more and a bending angle θ of 90 degrees or more and 180 degrees or less and designing the metal material so that the metal material has the calculated yield strength YP and Young's modulus E.

摘要翻译： 本发明的目的是提供一种用于设计具有机械特性的金属材料的方法，在具有各种各样的机械性能和厚度的金属材料中的任何一种之后，通过执行圆柱体 形成和使用该方法形成的产品。 一种用于设计要进行圆筒形成的材料的方法，所述方法包括在设计要进行成形的金属材料，其中通过弯曲成形形成金属材料，计算屈服强度YP，杨氏 模量E和金属材料的厚度t，使得当在弯曲曲率半径为5mm以上且弯曲角度θ为90度的条件下进行气缸成形时，弹簧后视角Deltatheta变为规定值，或 多于180度或更小，并且设计金属材料，使得金属材料具有计算的屈服强度YP和杨氏模量E.

公开(公告)号：US20130209827A1

公开(公告)日：2013-08-15

申请号：US13823409

申请日：2011-09-14

申请人： Takeshi Suzuki ,  Norihiko Nakamura ,  Yuka Miyamoto ,  Yoichi Tobiyama

发明人： Takeshi Suzuki ,  Norihiko Nakamura ,  Yuka Miyamoto ,  Yoichi Tobiyama

IPC分类号： C23C28/00 ,  C25D11/00 ,  C23C22/05

CPC分类号： C23C28/00 ,  B32B1/08 ,  B32B15/09 ,  B32B15/18 ,  B32B2250/03 ,  B32B2250/40 ,  B32B2255/06 ,  B32B2255/205 ,  B32B2255/26 ,  B32B2255/28 ,  B32B2439/66 ,  C23C22/00 ,  C23C22/05 ,  C23C22/34 ,  C23C22/36 ,  C23C22/83 ,  C23C28/32 ,  C23C28/321 ,  C23C28/322 ,  C23C28/34 ,  C23C28/3455 ,  C23C30/00 ,  C23C30/005 ,  C25D5/12 ,  C25D5/505 ,  C25D9/08 ,  C25D11/00 ,  C25D11/36 ,  Y10T428/12535 ,  Y10T428/12556 ,  Y10T428/12569 ,  Y10T428/12597 ,  Y10T428/12604 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12708 ,  Y10T428/12722 ,  Y10T428/12944 ,  Y10T428/12958 ,  Y10T428/12972 ,  Y10T428/12979 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/27 ,  Y10T428/31678

摘要： A steel sheet for containers that has excellent film adhesion qualities, and has; a chemical conversion coating formed by immersing or subjecting to electrolytic treatment a steel sheet in a solution containing Zr ions, F ions, with adhesion amount of 0.1 to 100 mg/m2 for metal Zr and no more than 0.1 mg/m2 for F; and a hydroxyl acid treatment layer formed on the chemical conversion coating, the layer having a C adhesion amount of 0.05 to 50 mg/m2.

摘要翻译： 具有优异的膜粘合性的容器用钢板，具有： 通过在包含Zr离子的溶液中对钢板进行电解处理而形成的化学转化膜，F离子，金属Zr的附着量为0.1〜100mg / m 2，F为0.1mg / m 2以下; 以及形成在化学转化涂层上的羟基酸处理层，该层的C附着量为0.05〜50mg / m 2。

公开(公告)号：US10174393B2

公开(公告)日：2019-01-08

申请号：US14112717

申请日：2012-04-19

申请人： Mikito Suto ,  Katsumi Kojima ,  Masaki Tada ,  Takumi Tanaka ,  Yoichi Tobiyama

发明人： Mikito Suto ,  Katsumi Kojima ,  Masaki Tada ,  Takumi Tanaka ,  Yoichi Tobiyama

IPC分类号： C22C38/06 ,  C22C38/04 ,  C21D8/02 ,  C22C38/00 ,  C22C38/02 ,  C21D9/46

摘要： A steel sheet containing C: 0.0005% or more and 0.0035% or less, Si: 0.05% or less, Mn: 0.1% or more and 0.6% or less, P: 0.02% or less, S: less than 0.02%, Al: 0.01% or more and less than 0.10%, N: 0.0030% or less, B: 0.0010% or more, in which the relationship B/N≤3.0 is satisfied and the balance being Fe and inevitable impurities, and a microstructure in which the average integrated intensity f in the (111)[1-10] to (111)[-1-12] orientations on a plane parallel to a sheet surface at a position located at ¼ of the thickness of the steel sheet is 7.0 or more, in which an average ferrite grain size is 6.0 μm or more and 10.0 μm or less, and the relationships EAVE≥215 GPa, E0≥210 GPa, E45≥210 GPa, E90≥210 GPa, and −0.4≤Δr≤0.4 are satisfied.