公开(公告)号：US4587226A

公开(公告)日：1986-05-06

申请号：US699056

申请日：1985-02-07

申请人： Yutaka Sasaki ,  Toshio Nakamura ,  Hiroshi Yamamoto ,  Hiroshi Murata ,  Yoshimi Nakamura ,  Naohiro Takahashi

发明人： Yutaka Sasaki ,  Toshio Nakamura ,  Hiroshi Yamamoto ,  Hiroshi Murata ,  Yoshimi Nakamura ,  Naohiro Takahashi

IPC分类号： B01J23/18 ,  B01J23/20 ,  B01J23/22 ,  B01J23/24 ,  B01J23/32 ,  B01J23/34 ,  B01J23/64 ,  B01J23/644 ,  B01J23/68 ,  B01J23/84 ,  B01J23/843 ,  B01J23/85 ,  B01J27/057 ,  B01J27/186 ,  B01J27/199 ,  B01J37/34 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08

CPC分类号： B01J23/8435 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/64 ,  B01J27/0573 ,  B01J27/0576 ,  B01J27/186 ,  B01J37/343 ,  Y10S502/522

摘要： A process for producing an antimony-containing oxide catalyst with improved strength is described, by the steps of preparing a slurry containing an antimony compound, a polyvalent metal compound and a silica sol as the essential ingredients, adjusting the pH of the slurry to 7 or less, heat treating the slurry at a temperature of 40.degree. C. or higher, and thereafter drying the slurry and calcining the dried particles, wherein said slurry is irradiated with ultrasonic waves during the pH adjustment, or after the pH adjustment and before completion of the heat treatment.

摘要翻译： 通过制备含有锑化合物，多价金属化合物和二氧化硅溶胶作为必要成分的浆料的步骤，描述了制备具有改善强度的含锑氧化物催化剂的方法，将浆料的pH调节至7或 较少，在40℃以上的温度下对浆料进行热处理，然后干燥浆料并煅烧干燥的颗粒，其中所述浆料在pH调节期间或在pH调节之后或在pH调节完成之前用超声波照射 热处理。

公开(公告)号：US4624800A

公开(公告)日：1986-11-25

申请号：US679719

申请日：1984-12-10

申请人： Yutaka Sasaki ,  Toshio Nakamura ,  Hiroshi Murata ,  Yoshimi Nakamura

发明人： Yutaka Sasaki ,  Toshio Nakamura ,  Hiroshi Murata ,  Yoshimi Nakamura

IPC分类号： B01J21/08 ,  B01J37/34 ,  C01B33/141 ,  B01J13/00

CPC分类号： B01J37/343 ,  B01J21/08 ,  C01B33/1415

摘要： A method for producing an aqueous silica sol is described, comprising admixing a fine silica powder having an ultimate particle size of 5 to 200 millimicrons with an aqueous medium at a pH not higher than 5 while applying ultrasonic vibrations having a frequency within the range of from 10 to 100 kilohertz to the aqueous medium to thereby disperse said silica powder in said aqueous medium and thus convert the mixture into an aqueous sol.

摘要翻译： 本发明描述了一种水溶性二氧化硅溶胶的制造方法，其特征在于，将具有5〜200毫微米的极细粒径的二氧化硅微粉与含水介质在不高于5的pH下混合，同时施加频率范围为 10至100千赫兹，从而将所述二氧化硅粉末分散在所述水性介质中，从而将所述混合物转化为水性溶胶。

公开(公告)号：US4590173A

公开(公告)日：1986-05-20

申请号：US699113

申请日：1985-02-07

申请人： Yutaka Sasaki ,  Toshio Nakamura ,  Hiroshi Utsumi ,  Hiroshi Murata ,  Yoshimi Nakamura

发明人： Yutaka Sasaki ,  Toshio Nakamura ,  Hiroshi Utsumi ,  Hiroshi Murata ,  Yoshimi Nakamura

IPC分类号： B01J23/18 ,  B01J23/20 ,  B01J23/24 ,  B01J23/32 ,  B01J23/644 ,  B01J23/68 ,  B01J23/84 ,  B01J23/843 ,  B01J23/85 ,  B01J27/057 ,  B01J27/182 ,  B01J27/186 ,  B01J27/199 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C51/377 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08 ,  B01J21/08 ,  B01J23/16 ,  B01J27/18

CPC分类号： C07C253/26 ,  B01J23/18 ,  B01J23/84 ,  B01J23/8435 ,  B01J27/0576 ,  B01J27/186 ,  B01J37/02 ,  C07C51/377 ,  B01J2523/00 ,  Y02P20/52

摘要： A process for producing an antimony-containing oxide catalyst supported on silica for use in a fluidized bed reaction is described, by the steps of preparing a slurry containing an antimony compound, a polyvalent metal compound, and silica sol as the essential ingredients, heat treating the slurry at a pH of 7 or less and at a temperature of 40.degree. C. or higher, and thereafter spray-drying the slurry and calcining the dried particles, wherein said silica sol has a multi-peak particle size distribution profile that is derived by using a mixture of silica sol A in an amount corresponding to form 10 to 90 wt % of the total silica in the catalyst and silica sol B in an amount corresponding to 90 to 10 wt % of the total silica in the catalyst, with silica sols A and B having different average particle sizes, provided that the relations 3

摘要翻译： 通过制备含有锑化合物，多价金属化合物和二氧化硅溶胶作为必须成分的浆料的步骤，描述了用于流化床反应的负载在二氧化硅上的含锑氧化物催化剂的制备方法， 该浆液pH为7以下，温度为40℃以上，然后喷雾干燥浆料并煅烧干燥后的颗粒，其中所述二氧化硅溶胶具有衍生出的多峰粒度分布曲线 通过使用相当于催化剂中总二氧化硅的10〜90重量％的量的二氧化硅溶胶A的混合物和二氧化硅溶胶B，其量相当于催化剂中总二氧化硅的90〜10重量％，与二氧化硅 溶胶A和B具有不同的平均粒径，条件是通过da（μm）满足关系3

公开(公告)号：US4757038A

公开(公告)日：1988-07-12

申请号：US52226

申请日：1987-05-15

申请人： Yutaka Sasaki ,  Yutaka Kiyomiya ,  Toshio Nakamura ,  Yoshimi Nakamura ,  Masanori Yamaguchi

发明人： Yutaka Sasaki ,  Yutaka Kiyomiya ,  Toshio Nakamura ,  Yoshimi Nakamura ,  Masanori Yamaguchi

IPC分类号： B01J27/057 ,  B01J23/94 ,  B01J27/28 ,  B01J37/04 ,  B01J38/04 ,  C01C3/02 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08 ,  B01J23/92 ,  C07C121/14 ,  C07C121/32

CPC分类号： B01J27/28 ,  B01J23/94 ,  B01J37/04

摘要： Iron-antimony metallic oxide catalysts which have become deactivated after being used for the production of aldehydes, acids, nitriles, or dienes through oxidation, ammoxidation, or oxidative dehydrogenation of organic compounds in fluidized-bed reactors are regenerated by adding to the catalyst a molybdenum-enriched catalyst formed by supporting a molybdenum component which is volatile or capable of forming a volatile compound under reaction conditions on a metallic oxide catalyst. The metallic oxide catalysts contain as essential components (I) Fe, (II) Sb, (III) at least one element selected from the group consisting of V, Mo and W, and (IV) Te.

摘要翻译： 通过在流化床反应器中通过氧化，氨氧化或有机化合物的氧化脱氢用于生产醛，酸，腈或二烯而失活的铁 - 锑金属氧化物催化剂通过向催化剂中加入钼 通过在金属氧化物催化剂上在反应条件下支持挥发性或能够形成挥发性化合物的钼组分形成的富含催化剂。 金属氧化物催化剂含有作为必要成分（I）Fe，（II）Sb，（III）至少一种选自V，Mo和W的元素和（IV）Te。

公开(公告)号：US4536483A

公开(公告)日：1985-08-20

申请号：US545713

申请日：1983-10-26

申请人： Yutaka Sasaki ,  Yutaka Kiyomiya ,  Toshio Nakamura ,  Yoshimi Nakamura ,  Masanori Yamaguchi

发明人： Yutaka Sasaki ,  Yutaka Kiyomiya ,  Toshio Nakamura ,  Yoshimi Nakamura ,  Masanori Yamaguchi

IPC分类号： B01J27/057 ,  B01J23/94 ,  B01J27/28 ,  B01J27/30 ,  B01J38/04 ,  C01C3/02 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/26 ,  C07C255/08 ,  C07C120/14 ,  C07C121/32

CPC分类号： B01J23/94 ,  B01J27/30

摘要： Iron-antimony metallic oxide catalysts which have become deactivated after being used for the production of aldehydes, acids, nitriles, or dienes through oxidation, ammoxidation, or oxidative dehydrogenation of organic compounds in fluidized-bed reactors are regenerated by adding to the catalyst a solid molybdenum component which is volatile or capable of forming a volatile compound under reaction conditions. The metallic oxide catalysts contain as essential components (I) Fe, (II) Sb, (III) at least one element selected from the group consisting of V, MO, and W, and (IV) Te.

摘要翻译： 通过在流化床反应器中通过氧化，氨氧化或有机化合物的氧化脱氢用于生产醛，酸，腈或二烯而失活的铁 - 锑金属氧化物催化剂通过向催化剂中加入固体而再生 钼组分，其在反应条件下挥发或能够形成挥发性化合物。 金属氧化物催化剂含有作为必要成分（I）Fe，（II）Sb，（III）选自V，MO和W的至少一种元素和（IV）Te。

公开(公告)号：US5877381A

公开(公告)日：1999-03-02

申请号：US673053

申请日：1996-07-01

申请人： Yutaka Sasaki ,  Hiroshi Yamamoto ,  Kiyoshi Moriya ,  Yoshimi Nakamura

发明人： Yutaka Sasaki ,  Hiroshi Yamamoto ,  Kiyoshi Moriya ,  Yoshimi Nakamura

IPC分类号： B01J8/18 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/64 ,  B01J23/68 ,  B01J23/76 ,  B01J23/88 ,  B01J23/89 ,  B01J27/02 ,  B01J27/186 ,  B01J27/192 ,  B01J27/199 ,  B01J35/00 ,  B01J35/02 ,  C01C3/02 ,  C07B61/00 ,  C07C45/00 ,  C07C45/34 ,  C07C45/36 ,  C07C45/41 ,  C07C47/02 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/265 ,  C07C53/00 ,  C07C253/24 ,  C07C255/08 ,  C07C5/327 ,  C07C5/02 ,  C07C47/00 ,  C07C255/00

CPC分类号： B01J23/002 ,  B01J23/18 ,  B01J23/22 ,  B01J27/199 ,  B01J35/0026 ,  B01J35/023 ,  C01C3/0241 ,  C07C253/26 ,  C07C253/28 ,  C07C45/002 ,  C07C45/34 ,  C07C45/36 ,  C07C45/41 ,  C07C51/215 ,  C07C51/252 ,  C07C51/265 ,  B01J2523/00 ,  Y02P20/52 ,  Y10S502/503

摘要： The present invention provides a fluidized bed catalyst for the synthetic reaction of organic compounds which has a reduced catalyst loss. A fluidized bed catalyst for organic compound synthetic reaction, characterized in that 90% or more of the catalyst particles is in the range of 5-500 .mu.m on the weight-based particle size distribution and 90% or more of the 20-75 .mu.m particles has a crushing strength which satisfies the following equation:CS>A.multidot.d.sub..alpha.wherein CS represents a crushing strength �g-weight/particle!,A represents a constant 0.001,d represents a particle diameter �.mu.m!, and.alpha. represents a constant 2.

摘要翻译： 本发明提供了一种催化剂损失减少的有机化合物的合成反应的流化床催化剂。 一种用于有机化合物合成反应的流化床催化剂，其特征在于，基于重量的粒度分布，催化剂颗粒的90％或更多在5-500μm范围内，20-75μm的90％以上 m颗粒具有满足以下等式的破碎强度：CS>Axdα其中CS表示抗碎强度[g-重量/颗粒]，A表示常数0.001，d表示粒径μ，α表示 常数2。

公开(公告)号：US4590175A

公开(公告)日：1986-05-20

申请号：US655612

申请日：1984-09-28

申请人： Yutaka Sasaki ,  Hiroshi Utsumi ,  Kunio Mori ,  Hiroshi Yamamoto ,  Yoshimi Nakamura ,  Kiyoshi Moriya ,  Akimitsu Morii ,  Mikio Noda ,  Miki Kunitani

发明人： Yutaka Sasaki ,  Hiroshi Utsumi ,  Kunio Mori ,  Hiroshi Yamamoto ,  Yoshimi Nakamura ,  Kiyoshi Moriya ,  Akimitsu Morii ,  Mikio Noda ,  Miki Kunitani

IPC分类号： C07B33/00 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/80 ,  B01J23/843 ,  B01J23/85 ,  B01J23/88 ,  B01J27/057 ,  B01J27/188 ,  B01J37/00 ,  B01J37/04 ,  C01G30/00 ,  C07B31/00 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J21/08

CPC分类号： C07C253/26 ,  B01J23/16 ,  B01J23/18 ,  B01J23/8435 ,  B01J23/85 ,  B01J27/0576 ,  C01G30/004 ,  B01J2523/00 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/61 ,  Y02P20/52

摘要： A process for the production of antimony-containing metal oxide catalysts, comprising preparing a slurry containing as essential components an antimony component, a polyvalent metal compound, and silica sol, heating and drying the slurry to form a solid product, and then calcining the solid product, wherein the antimony component is a mixture of (A) at least one of antimonic acid, polyantimonic acid and the salts thereof and (B) antimony trioxide, and is prepared by mixing (A) and (B) in such a manner that the antimony provided by the (B) constitutes from 0.1 to 70 atomic % of the total amount of antimony and further in an aqueous slurry state. These antimony-containing metal oxide catalysts have superior activity and physical properties, and further reproducibility in the preparation thereof. Thus they are useful for production of aldehydes and acids through oxidation, nitriles through ammoxidation, and dienes, unsaturated aldehydes and unsaturated acids through oxidative dehydrogenation.

摘要翻译： 一种制备含锑金属氧化物催化剂的方法，包括制备含有锑组分，多价金属化合物和二氧化硅溶胶作为必要组分的浆料，加热和干燥该浆料以形成固体产物，然后煅烧该固体 产品，其中锑组分是（A）锑酸，聚锑酸及其盐中的至少一种和（B）三氧化锑中的至少一种的混合物，并且通过混合（A）和（B）以下列方式制备： 由（B）提供的锑构成锑总量的0.1〜70原子％，进一步为含水浆状态。 这些含锑金属氧化物催化剂具有优异的活性和物理性能，并且在制备时具有进一步的再现性。 因此，它们可用于通过氧化制备醛和酸，通过氨氧化生成腈，通过氧化脱氢可用于二烯，不饱和醛和不饱和酸。

公开(公告)号：US4826802A

公开(公告)日：1989-05-02

申请号：US159997

申请日：1988-02-24

申请人： Yutaka Sasaki ,  Yoshimi Nakamura ,  Hiroshi Utsumi ,  Kunio Mori

发明人： Yutaka Sasaki ,  Yoshimi Nakamura ,  Hiroshi Utsumi ,  Kunio Mori

IPC分类号： B01J27/057 ,  B01J27/186 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/24 ,  C07C255/08 ,  B01J21/08 ,  B01J23/18

CPC分类号： B01J27/0576

摘要： A process for preparing an antimony/tellurium-containing metal oxide catalyst, comprising preparing a slurry containing an antimony compound, a polyvalent metal compound, and a silica support starting material selected from silica sol and mixtures of silica sol and white carbon, fumed silica or silica hydrogel, heating the slurry at a pH or 7 or less and a temperature of at least 40.degree. C., mixing the above heat treated slurry with a tellurium solution which has been independently prepared by oxidizing metallic tellurium with hydrogen peroxide in the presence of the oxide, oxyacid or oxyacid salt of at least one metal selected from the group consisting of vanadium, molybdenum and tungsten, and then drying and calcining the resulting mixture.

公开(公告)号：US4370279A

公开(公告)日：1983-01-25

申请号：US941351

申请日：1978-09-11

申请人： Yutaka Sasaki ,  Tomio Nakamura ,  Yoshimi Nakamura ,  Kiyoshi Moriya ,  Hiroshi Utsumi ,  Shigeru Saito

发明人： Yutaka Sasaki ,  Tomio Nakamura ,  Yoshimi Nakamura ,  Kiyoshi Moriya ,  Hiroshi Utsumi ,  Shigeru Saito

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/88 ,  B01J27/00 ,  B01J27/057 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C120/14

CPC分类号： B01J23/8873 ,  B01J23/8872 ,  B01J23/8876 ,  B01J23/8877 ,  B01J27/0576 ,  C07C253/26 ,  B01J2523/00 ,  Y02P20/52

摘要： A process for producing acrylonitrile by the vapor-phase catalytic ammoxidation of propylene, which comprises(I) reacting propylene, a molecular oxygen-containing gas and ammonia in the presence of a catalyst expressed by the following empirical formulaFe.sub.a Sb.sub.b Mo.sub.c Me.sub.d Te.sub.e Q.sub.f Na.sub.g O.sub.h. (SIO).sub.iwherein Me is at least one element selected from the group consisting of V and W,Q is at least one element selected from the group consisting of Cu, Mg, Zn and Ni, andthe subscripts a, b, c, d, e, f, g, h and i each represents atomic ratios such that when a=10; b=13 to 28; c=0.1 to 2.5; d=0.05 to 1; e=0.2 to 5; f=0 to 4 (in which case b=13 to 20), or f=2 to 6 (in which case b=20 to 28); g=0 to 3; h=the number of oxygens corresponding to the oxide formed by the combination of the components, and i=25 to 200;in a fluidized bed catalytic reaction zone at a temperature of about 380 to about 500.degree. C. and a pressure of about 0.2 to about 3 kg/cm.sup.2 -G while adjusting the propylene/oxygen/ammonia molar ratio to about 1:about 1:about 0.8 to about 1:about 4:about 3;(II) the catalyst being prepared by(1) intimately mixing starting materials for the Fe, Mo, Me, Te and Q components in a form soluble in water or nitric acid, a starting material for the Sb component, and silica sol which may or may not contain an Na component, thereby to form a slurry containing these components and having a non-volatile solids content of about 10 to about 50% by weight;(2) so that the composition of the final catalyst is within the range expressed by the empirical formula above;(3) spray-drying the resulting slurry, and(4) calcining the resulting spray-dried particles at a temperature of about 600 to about 950.degree. C. thereby to form a catalyst with a composition within the above empirical formula and with all of the Mo, Me, and Te components substantially dissolved in an iron/antimony oxide compound (FeSbO.sub.4) in the form of a solid solution.

公开(公告)号：US6100215A

公开(公告)日：2000-08-08

申请号：US993577

申请日：1997-12-18

申请人： Yutaka Sasaki ,  Kunio Mori ,  Yoshimi Nakamura ,  Koichi Mizutani

发明人： Yutaka Sasaki ,  Kunio Mori ,  Yoshimi Nakamura ,  Koichi Mizutani

IPC分类号： B01J23/843 ,  C01G49/00 ,  H01L21/8238 ,  H01L21/331

CPC分类号： C01G49/0018 ,  B01J23/8435 ,  C01P2004/32 ,  C01P2006/21 ,  C01P2006/60 ,  Y10S502/503

摘要： There is provided a process for producing a particulate iron-antimony containing oxide composition having high compressive strength, comprising the steps of: providing an aqueous slurry containing iron ions, nitrate ions and antimony trioxide; adjusting the slurry to a pH value in the range of 0.5 to 3 as measured at 40.degree. C.; heating the slurry; spray-drying the heated slurry; and calcining the resultant particles.

摘要翻译： 提供了一种制备具有高抗压强度的颗粒状含铁锑氧化物组合物的方法，包括以下步骤：提供含有铁离子，硝酸根离子和三氧化锑的含水浆料; 将浆料调节至在40℃下测量的0.5至3范围内的pH值; 加热浆料; 喷雾干燥加热的浆料; 并煅烧所得颗粒。