Abstract:
The present invention is a low firing temperature, composite thick film dielectric layer for an electroluminescent display. The composite thick film dielectric layer comprises; (a) a lower zone layer of a thick film composition comprising; one or more of lead magnesium niobate (PMN), lead magnesium niobate-titanate (PMN-PT), lead titanate, barium titanate and lead oxide; and a glass frit composition comprising lead oxide, boron oxide and silicon dioxide; (b) an upper zone comprising at least one layer of lead zirconate titanate (PZT) and/or barium titanate; and (c) an intermediate composite zone comprising a composite of (a) and (b).
Abstract:
The invention relates to a laser ablation method for patterning thin film layers for thick dielectric electroluminescent displays without substantial ablation of or damage to any other layers. Typically, the thin film layers are phosphor layers. The laser ablation method for patterning a thin film phosphor layer of a thick dielectric electroluminescent display includes selecting a wavelength of laser radiation, a laser pulse length, a laser energy density and a sufficient number of laser pulses to pattern the thin film phosphor layer without substantial ablation of or damage to other layers, whereby the wavelength of laser radiation is such that the laser radiation is substantially absorbed by the thin film phosphor layer with minimal absorption by other layers, the laser pulse length is sufficiently short that during the duration of the laser pulse there is minimal heat flow from the thin film phosphor layer to other layers, and the laser energy density and the sufficient number of laser pulses is sufficiently high that energy is deposited in the thin film phosphor layer, whereby the entire thickness of at least a portion of the thin film phosphor layer is ablated.
Abstract:
A method of deposition of a phosphor in a single-source sputtering process, in which the phosphor is selected from the group consisting of ternary, quaternary or higher thioaluminate, thiogallate and thioindate phosphors, and composites thereof, synthesized with cations selected from Groups IIA and IIB of the Periodic Table of Elements. The phosphor is of a pre-determined composition of elements. The method comprising sputtering in a hydrogen sulphide atmosphere from a single source composition so as to deposit a composition on a substrate. The composition of the targets of the single source has a relative increase in concentration of elements of the phosphor that have a lower atomic weight compared to other elements in said phosphor. The relative increase is controlled such that deposition of the pre-determined composition is effected on the substrate. Preferred phosphors are barium thioaluminate (BaAl2S4:Eu), and barium magnesium thioaluminates.
Abstract:
An electroluminescent display and driving method is provided wherein the rows of pixels are divided into sub-pixel sets and several different sets of sub-pixels are then addressed from within a larger superset of adjacent sub-pixels. The image data for the addressed sub-pixels is averaged with that for adjacent sub-pixels and is applied to the reduced number of larger sub-pixels in sequence. Consequently, for a given sequence of input frame data sets the time average over one frame for a portion of the sub-pixels at any location of the panel is substantially the same as that for a conventionally addressed sub-pixel in a prior art panel.
Abstract:
A circuit and method of driving a display panel requiring gray scale control wherein the voltage applied to a row of pixels is equal to the sum of voltages of opposite sign with respect to ground applied respectively to the row electrode and column electrodes whose intersection with the row defines the pixels. Gray scale is realized through modulation of the voltage applied to the column electrodes. Typically for video application, 256 individual gray levels are required corresponding to luminance levels ranging from zero (no emissive luminance) to full luminance. The required luminance for each gray level is not a linear function of the gray level number but rather corresponds to an approximate quadratic function of this number. The present invention facilitates generation of luminance values for each gray level that approximates this functional dependence ( i.e. Gamma corrected) with a non-linear voltage ramp terminated by a digital clock having 256 (8 bit) resolution. The voltage at the ramp termination is held at a constant value and fed to the output buffer of the gray scale drivers for the display columns.
Abstract:
A thin film phosphor for an electroluminescent device, the phosphor being selected from the group consisting of thioaluminates, thiogallates and thioindates having at least one cation selected from elements of Groups IIA and IIB of the Periodic Table of Elements. The phosphor being activated by a rare earth metal and containing oxygen as a partial substitute for a portion of the sulphur in the crystal lattice of the thiogallate, thioindate or thioaluminate. The phosphor is a single phase homogeneous compound and provides improved luminance stability. An electroluminescent device comprising the thin film phosphor is also described and methods of making the phosphor of the invention.
Abstract:
A patterned phosphor structure, and EL laminate containing same, forming red, green and blue sub-pixel phosphor elements for an AC electroluminescent display. The patterned phosphor structure includes at least a first and a second phosphor emitting light in different ranges of the visible spectrum, but with combined emission spectra contains red, green and blue light, the first and second phosphors being in a layer, arranged in adjacent, repeating relationship to each other to provide a plurality of repeating first and second phosphor deposits. The phosphor structure also includes one or more means associated with one or more of the first and second phosphor deposits, and which together with the first and second phosphor deposits, form the red, green and blue sub-pixel phosphor elements, for setting and equalizing the threshold voltages of the red, green and blue sub-pixel phosphor elements, and for setting the relative luminosities of the red, green and blue sub-pixel phosphor elements so that they bear set ratios to one another at each operating modulation voltage used to generate the desired luminosities for red, green and blue. Photolithographic methods for producing the patterned phosphor structure are also provided. Also provided is an improved dielectric layer for use in an EL laminate, including a pressed, sintered ceramic material having, compared to an unpressed, sintered dielectric layer of the same composition, improved dielectric strength, reduced porosity and uniform luminosity in an EL laminate. Also provided are combined substrate and dielectric layer components or EL laminates containing the pressed thick film dielectric layer, and methods of forming the pressed thick film dielectric layer. A process is also provided for synthesizing strontium sulfide phosphors by providing a source of high purity strontium carbonate in a dispersed form, heating the strontium carbonate in a reactor with gradual heating up to a maximum temperature in the range of 800 to 1200° C., contacting the heated strontium carbonate with a flow of sulfur vapours formed by heating elemental sulfur in the reactor to at least 300° C. in an inert atmosphere; and terminating the reaction by stopping the flow of sulfur at a point when sulfur dioxide or carbon dioxide in the reaction gas reaches an amount which correlates with an amount of oxygen in oxygen-containing strontium compounds in the reaction product which is in the range of 1 to 10 atomic percent.
Abstract:
A phosphor and a method of deposition. The phosphor comprises a composition of the formula M′aBa1-aM″2M′″4′; RE, whereM′ is at least one element selected from magnesium and calcium, M″ is at least one element selected from aluminum, gallium and indium, M′″ is at least one element selected from sulphur, selenium and tellurium, RE is at least one rare earth element, especially europium or cerium, and 0
Abstract:
An electroluminescent display and driving method is provided wherein the rows of pixels are divided into sub-pixel sets and several different sets of sub-pixels are then addressed from within a larger superset of adjacent sub-pixels. The image data for the addressed sub-pixels is averaged with that for adjacent sub-pixels and is applied to the reduced number of larger sub-pixels in sequence. Consequently, for a given sequence of input frame data sets the time average over one frame for a portion of the sub-pixels at any location of the panel is substantially the same as that for a conventionally addressed sub-pixel in a prior art panel.
Abstract:
A novel structure is provided to improve the operating stability of thioaluminate based phosphors used in ac thick film dielectric electroluminescent displays. The novel structure comprises a rare earth activated alkaline earth thioaluminate phosphor thin film layer and a silicon oxynitride layer provided directly adjacent the top and/or bottom of the phosphor thin film layer, wherein said silicon oxynitride layer comprises a composition of Si3NxOyHz where 2≦x≦4, 0
Abstract translation:提供了一种新颖的结构来改善在ac厚膜电介质电致发光显示器中使用的硫铝酸盐基磷光体的操作稳定性。 该新型结构包括稀土活化的碱土金属硫铝酸盐荧光体薄膜层和直接邻近荧光体薄膜层的顶部和/或底部设置的氧氮化硅层,其中所述氧氮化硅层包含Si 3 其中2 <= x <= 4,0