METHOD OF MAKING IONIC LIQUID MEDIATED SOL-GEL SORBENTS
    9.
    发明申请
    METHOD OF MAKING IONIC LIQUID MEDIATED SOL-GEL SORBENTS 有权
    制造离子液体介质溶胶凝胶的方法

    公开(公告)号:US20140057048A1

    公开(公告)日:2014-02-27

    申请号:US14046302

    申请日:2013-10-04

    IPC分类号: B01J20/291

    摘要: Ionic liquid (IL)-mediated sol-gel hybrid organic-inorganic materials present enormous potential for effective use in analytical microextraction. One obstacle to materializing this prospect arises from high viscosity of ILs significantly slowing down sol-gel reactions. A method was developed which provides phosphonium-based, pyridinium-based, and imidazolium-based IL-mediated advanced sol-gel organic-inorganic hybrid materials for capillary microextraction. Scanning electron microscopy results demonstrate that ILs can serve as porogenic agents in sol-gel reactions. IL-mediated sol-gel coatings prepared with silanol-terminated polymers provided up to 28 times higher extractions compared to analogous sol-gel coatings prepared without any IL in the sol solution. This study shows that IL-generated porous morphology alone is not enough to provide effective extraction media: careful choice of the organic polymer and the precursor with close sol-gel reactivity must be made to ensure effective chemical bonding of the organic polymer to the created sol-gel material to be able to provide the desired sorbent characteristics.

    摘要翻译: 离子液体(IL)介导的溶胶 - 凝胶杂化有机 - 无机材料在分析微萃取中有巨大的潜力。 实现这一前景的一个障碍来自于高粘度的ILs显着减慢溶胶 - 凝胶反应。 开发了一种提供用于毛细管微萃取的基于鏻,吡啶鎓和咪唑鎓的IL介导的高级溶胶 - 凝胶有机 - 无机杂化材料的方法。 扫描电子显微镜结果表明,ILs可作为溶胶 - 凝胶反应中的致孔剂。 与溶胶溶液中没有任何IL制备的类似溶胶 - 凝胶涂层相比,用硅烷醇封端的聚合物制备的IL介导的溶胶 - 凝胶涂层提供高达28倍的提取量。 这项研究表明,单独的IL产生的多孔形态不足以提供有效的提取介质:必须仔细选择有机聚合物和具有近似溶胶 - 凝胶反应性的前体,以确保有机聚合物与所形成的溶胶的有效化学键合 凝胶材料能够提供所需的吸附剂特性。

    Ionic liquid mediated sol-gel sorbents
    10.
    发明授权
    Ionic liquid mediated sol-gel sorbents 有权
    离子液体介导的溶胶 - 凝胶吸附剂

    公开(公告)号:US08623279B2

    公开(公告)日:2014-01-07

    申请号:US13300943

    申请日:2011-11-21

    IPC分类号: G01N30/60

    摘要: Ionic liquid (IL)-mediated sol-gel hybrid organic-inorganic materials present enormous potential for effective use in analytical microextraction. One obstacle to materializing this prospect arises from high viscosity of ILs significantly slowing down sol-gel reactions. A method was developed which provides phosphonium-based, pyridinium-based, and imidazolium-based IL-mediated advanced sol-gel organic-inorganic hybrid materials for capillary microextraction. Scanning electron microscopy results demonstrate that ILs can serve as porogenic agents in sol-gel reactions. IL-mediated sol-gel coatings prepared with silanol-terminated polymers provided up to 28 times higher extractions compared to analogous sol-gel coatings prepared without any IL in the sol solution. This study shows that IL-generated porous morphology alone is not enough to provide effective extraction media: careful choice of the organic polymer and the precursor with close sol-gel reactivity must be made to ensure effective chemical bonding of the organic polymer to the created sol-gel material to be able to provide the desired sorbent characteristics.

    摘要翻译: 离子液体(IL)介导的溶胶 - 凝胶杂化有机 - 无机材料在分析微萃取中有巨大的潜力。 实现这一前景的一个障碍来自于高粘度的ILs显着减慢溶胶 - 凝胶反应。 开发了一种提供用于毛细管微萃取的基于鏻,吡啶鎓和咪唑鎓的IL介导的高级溶胶 - 凝胶有机 - 无机杂化材料的方法。 扫描电子显微镜结果表明,ILs可作为溶胶 - 凝胶反应中的致孔剂。 与溶胶溶液中没有任何IL制备的类似溶胶 - 凝胶涂层相比,用硅烷醇封端的聚合物制备的IL介导的溶胶 - 凝胶涂层提供高达28倍的提取量。 这项研究表明,单独的IL产生的多孔形态不足以提供有效的提取介质:必须仔细选择有机聚合物和具有近似溶胶 - 凝胶反应性的前体,以确保有机聚合物与所形成的溶胶的有效化学键合 凝胶材料能够提供所需的吸附剂特性。