公开(公告)号：US09908103B2

公开(公告)日：2018-03-06

申请号：US14037100

申请日：2013-09-25

申请人： UNIVERSITY OF CONNECTICUT

发明人： Steven L. Suib ,  Altug Suleyman Poyraz

IPC分类号： B01J23/755 ,  C01F17/00 ,  C01B37/02 ,  C01B35/10 ,  C01B33/12 ,  C01B13/18 ,  B82Y30/00 ,  C01B13/32 ,  B01J23/34 ,  B01J23/06 ,  B01J21/06 ,  B01J23/75 ,  B01J23/10 ,  B01J23/745 ,  B01J21/08 ,  B01J21/12 ,  B01J23/72 ,  C01G1/02

CPC分类号： B01J23/755 ,  B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/06 ,  B01J23/10 ,  B01J23/34 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B82Y30/00 ,  C01B13/18 ,  C01B13/326 ,  C01B33/124 ,  C01B35/1027 ,  C01B37/02 ,  C01F17/0043 ,  C01G1/02 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/13 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

摘要： A process for preparing a mesoporous metal oxide, i.e., transition metal oxide. Lanthanide metal oxide, a post-transition metal oxide and metalloid oxide. The process comprises providing an acidic mixture comprising a metal precursor, an interface modifier, a hydrotropic ion precursor, and a surfactant; and heating the acidic mixture at a temperature and for a period of time sufficient to form the mesoporous metal oxide. A mesoporous metal oxide prepared by the above process. A method of controlling nano-sized wall crystallinity and mesoporosity in mesoporous metal oxides. The method comprises providing an acidic mixture comprising a metal precursor, an interface modifier, a hydrotropic ion precursor, and a surfactant; and heating the acidic mixture at a temperature and for a period of time sufficient to control nano-sized wall crystallinity and mesoporosity in the mesoporous metal oxides. Mesoporous metal oxides and a method of tuning structural properties of mesoporous metal oxides.

公开(公告)号：US20140227158A1

公开(公告)日：2014-08-14

申请号：US13767358

申请日：2013-02-14

申请人： U.S. ARMY RESEARCH LABORATORY ATTN: RDRL-LOC-I

发明人： Robert J. Pavlacka ,  Gary A. Gilde

IPC分类号： C01B35/10

CPC分类号： C01B35/1027

摘要： Methods of preparing boron suboxide are provided herein. In some embodiments, a method for preparing boron suboxide may include loading elemental boron powder into a furnace; purging the furnace by flowing a first gas comprising one of nitrogen or an inert gas into the furnace; heating the boron powder in a reactive atmosphere comprising a mixture of argon and a non-reducing oxygen-containing gas to convert elemental boron powder into boron suboxide powder, wherein the amount of oxygen in the reactive atmosphere is no greater than about 1%.

摘要翻译： 本文提供了制备低氧化硼的方法。 在一些实施方案中，制备低氧化硼的方法可包括将元素硼粉末加入炉中; 通过将包括氮气或惰性气体中的一种的第一气体流入炉中来吹扫炉; 在包含氩和非还原性含氧气体的混合物的反应气氛中加热硼粉末，以将元素硼粉末转化成低氧化硼粉末，其中反应气氛中的氧气量不大于约1％。

公开(公告)号：US20120219862A1

公开(公告)日：2012-08-30

申请号：US13505123

申请日：2010-10-27

申请人： Yukiko Fujino ,  Yoshinobu Yasunaga ,  Toru Tabuchi ,  Tokuo Inamasu ,  Toshiyuki Nukuda

发明人： Yukiko Fujino ,  Yoshinobu Yasunaga ,  Toru Tabuchi ,  Tokuo Inamasu ,  Toshiyuki Nukuda

IPC分类号： H01M4/485 ,  H01B1/04 ,  H01M4/58

CPC分类号： C01B35/1027 ,  C01B35/121 ,  C01B35/143 ,  C01P2004/51 ,  C01P2006/12 ,  H01M4/136 ,  H01M4/366 ,  H01M4/381 ,  H01M4/382 ,  H01M4/40 ,  H01M4/405 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M2004/021 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides a Li3V2(PO4)3-based positive active material for a lithium secondary battery, which has high discharge capacity and excellent storage performance, particularly high-temperature storage performance; and a lithium secondary battery made using the positive active material. The positive active material for a lithium secondary battery has general formula Li3V2(PO4)3-x(BO3)x (0

摘要翻译： 本发明提供一种锂二次电池用Li3V2（PO4）3系正极活性物质，其放电容量大，储存性能优异，特别是高温保存性能; 以及使用正极活性物质制造的锂二次电池。 锂二次电池用正极活性物质具有通式Li 3 V 2（PO 4）3-x（BO 3）x（0

公开(公告)号：US20240088444A1

公开(公告)日：2024-03-14

申请号：US18381688

申请日：2023-10-19

申请人： TOMIYAMA PURE CHEMICAL INDUSTRIES, LTD.

发明人： Tailu NING ,  Kazuyuki SHIMIZU ,  Hiroo NITTA

IPC分类号： H01M10/0568 ,  C01B33/32 ,  C01B35/10 ,  C01B35/14 ,  H01G11/60 ,  H01G11/62 ,  H01G11/64 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569

CPC分类号： H01M10/0568 ,  C01B33/32 ,  C01B35/1027 ,  C01B35/14 ,  C01B35/146 ,  H01G11/60 ,  H01G11/62 ,  H01G11/64 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  C01P2006/40 ,  H01M2300/004

摘要： To provide an electrolyte for a storage device capable of lowering the electric resistance and maintaining a high capacity even after charging and discharging are repeatedly carried out, and a storage device.
An electrolyte for a storage device, which comprises a lithium-containing complex compound represented by the following formula (1), (2), (3), (4) or (5):


(Li)m(A)n(UFx)y  (1)



(Li)m(Si)n(O)q(UFx)y  (2)

wherein A is O, S, P or N; U is a boron atom or a phosphorus atom; m and n are each independently from 1 to 6; q is from 1 to 12; x is 3 or 5; and y is from 1 to 6;


(Li)m(O)n(B)p(OWFq)x  (3)

wherein W is a boron atom or a phosphorus atom; m, p and x are each independently from 1 to 15; n is from 0 to 15; and q is 3 or 5;


(Li)m(B)p(O)n(OR)y(OWFq)x  (4)

wherein W is a boron atom or a phosphorus atom; n is from 0 to 15; p, m, x and y are each independently from 1 to 12; q is 3 or 5; and R is hydrogen, an alkyl group, an alkenyl group, an aryl group, a carbonyl group, a sulfonyl group or a silyl group, and such a group may have a fluorine atom, an oxygen atom or other substituent;


(Li)m(O)n(B)p(OOC-(A)z-COO)y(OWFq)x  (5)

wherein W is a boron atom or a phosphorus atom, A is a C1-6 allylene group, alkenylene group or alkynylene group, a phenylene group, or an alkylene group having an oxygen atom or a sulfur atom in its main chain; m, p, x and y are each independently from 1 to 20; n is from 0 to 15; z is 0 or 1; and q is 3 or 5.

公开(公告)号：US09452933B2

公开(公告)日：2016-09-27

申请号：US14037107

申请日：2013-09-25

申请人： UNIVERSITY OF CONNECTICUT

发明人： Steven L. Suib ,  Altug Suleyman Poyraz

IPC分类号： C01B13/32 ,  B01J21/06 ,  B82Y30/00 ,  C01G1/02 ,  C01B19/00 ,  C01B33/113 ,  C01B35/10 ,  C01B33/12 ,  C01B37/02 ,  C01G23/053 ,  C01G25/02 ,  C01G45/02 ,  C01G49/06 ,  C01G51/04 ,  C01G3/02

CPC分类号： C01B13/328 ,  B82Y30/00 ,  C01B19/004 ,  C01B33/113 ,  C01B33/124 ,  C01B35/1027 ,  C01B37/02 ,  C01G1/02 ,  C01G3/02 ,  C01G23/053 ,  C01G25/02 ,  C01G45/02 ,  C01G49/06 ,  C01G51/04 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

摘要： A process for preparing a mesoporous metal oxide, i.e., transition metal oxide, Lanthanide metal oxide, a post-transition metal oxide and metalloid oxide. The process comprises providing a micellar solution comprising a metal precursor, an interface modifier, a hydrotropic ion precursor, and a surfactant; and heating the micellar solution at a temperature and for a period of time sufficient to form the mesoporous metal oxide. A mesoporous metal oxide prepared by the above process. A method of controlling nano-sized wall crystallinity and mesoporosity in mesoporous metal oxides. The method comprises providing a micellar solution comprising a metal precursor, an interface modifier, a hydrotropic ion precursor, and a surfactant; and heating the micellar solution at a temperature and for a period of time sufficient to control nano-sized wall crystallinity and mesoporosity in the mesoporous metal oxides. Mesoporous metal oxides and a method of tuning structural properties of mesoporous metal oxides.

摘要翻译： 一种制备介孔金属氧化物，即过渡金属氧化物，镧系元素金属氧化物，后过渡金属氧化物和准金属氧化物的方法。 该方法包括提供包含金属前体，界面改性剂，水溶助离子前体和表面活性剂的胶束溶液; 并在足以形成介孔金属氧化物的温度和一段时间内加热胶束溶液。 通过上述方法制备的介孔金属氧化物。 控制介孔金属氧化物中纳米尺寸壁结晶度和介孔度的方法。 该方法包括提供包含金属前体，界面改性剂，水溶助离子前体和表面活性剂的胶束溶液; 并在足以控制介孔金属氧化物中的纳米尺寸壁结晶度和介孔度的温度下加热胶束溶液。 介孔金属氧化物和调节中孔金属氧化物的结构特性的方法。

公开(公告)号：US08552189B2

公开(公告)日：2013-10-08

申请号：US12853460

申请日：2010-08-10

申请人： Kyo-sung Park ,  Seon-ah Jin ,  Hyun-chul Lee

发明人： Kyo-sung Park ,  Seon-ah Jin ,  Hyun-chul Lee

IPC分类号： C07F15/00 ,  C07F7/18 ,  C07F3/00 ,  C07F5/06

CPC分类号： C07F3/003 ,  C01B13/363 ,  C01B33/12 ,  C01B33/18 ,  C01B35/1009 ,  C01B35/1027 ,  C01P2002/72 ,  C01P2004/03

摘要： A hybrid porous material including at least a first and a second porous material portion which are chemically bonded to each other and are each a different type of material.

摘要翻译： 一种混合多孔材料，其包括至少第一和第二多孔材料部分，其彼此化学键合并且各自是不同类型的材料。

公开(公告)号：US07897135B2

公开(公告)日：2011-03-01

申请号：US11231450

申请日：2005-09-21

申请人： Karen S. Martirosyan ,  Dan Luss

发明人： Karen S. Martirosyan ,  Dan Luss

IPC分类号： C01G1/00 ,  C01G9/00 ,  C01G19/00 ,  C01G23/00 ,  C01G49/00 ,  C01G51/00

CPC分类号： C01G1/02 ,  C01B13/324 ,  C01B33/181 ,  C01B35/1027 ,  C01F17/0025 ,  C01G9/00 ,  C01G19/00 ,  C01G23/006 ,  C01G45/006 ,  C01G45/1264 ,  C01G49/0018 ,  C01G49/0027 ,  C01G49/0036 ,  C01G49/0054 ,  C01G49/009 ,  C01G51/00 ,  C01G53/006 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2006/42 ,  C09C1/0009

摘要： The present invention is generally directed to a novel, economic synthesis of oxide ceramic composites. Methods of the present invention, referred to as carbon combustion synthesis of oxides (CCSO), are a modification of self-propagating high-temperature synthesis (SHS) methods in which the heat needed for the synthesis is generated by combustion of carbon in oxygen rather than that of a pure metal. This enables a more economic production of the ceramic material and minimizes the presence of intermediate metal oxides in the product. The reactant mixture generally comprises at least one oxide precursor (e.g., a metal or non metal oxide, or super oxide, or nitride, or carbonate, or chloride, or oxalate, or halides) as a reactant, but no pure metal. Pure carbon in the form of graphite or soot is added to the reactant mixture to generate the desired heat (upon ignition). The mixture is placed in a reactor and exposed to gaseous oxygen. The high-temperature exothermic reaction between the carbon and oxygen generates a self-sustaining reaction in the form of a propagating temperature wave that causes a reaction among the reactants. The reaction proceeds rapidly following ignition, and the final product comprises simple and/or complex oxides of elements present in the oxide precursor(s). CCSO also enables synthesis of oxides that cannot be produced by conventional SHS, such as when the pure metal is pyrophoric (such as Li or La) or such as when it melts at room temperature (e.g., Ga) or such as the combustion heat of the metal is relatively low.

摘要翻译： 本发明一般涉及氧化物陶瓷复合材料的新型经济合成。 本发明的方法，称为碳燃烧合成氧化物（CCSO），是自蔓延高温合成（SHS）方法的改进，其中合成所需的热量是通过在氧气中燃烧碳而产生的 比纯金属。 这使得能够更经济地生产陶瓷材料并最小化产品中中间体金属氧化物的存在。 反应物混合物通常包含作为反应物的至少一种氧化物前体（例如，金属或非金属氧化物，或超氧化物，或氮化物，或碳酸盐，或氯化物，或草酸盐或卤化物），但不包括纯金属。 将石墨或烟灰形式的纯碳加入到反应混合物中以产生所需的热量（点火时）。 将混合物置于反应器中并暴露于气态氧气中。 碳和氧之间的高温放热反应以引起反应物之间的反应的传播温度波的形式产生自维持反应。 该反应在点燃之后迅速进行，并且最终产物包含存在于氧化物前体中的元素的简单和/或复合氧化物。 CCSO还能够合成不能通过常规SHS生产的氧化物，例如当纯金属是自燃的（例如Li或La）时，或者当其在室温下熔化时（例如Ga）或诸如燃烧热 金属相对较低。

公开(公告)号：US20180230015A1

公开(公告)日：2018-08-16

申请号：US15949726

申请日：2018-04-10

申请人： Saudi Arabian Oil Company

发明人： Michele Louisa Ostraat

IPC分类号： C01B33/18 ,  C04B35/626 ,  C01G25/02 ,  B01J2/00 ,  C01G23/047 ,  C01G17/02 ,  C01G41/02 ,  C01F17/00

CPC分类号： C01B33/18 ,  B01J2/00 ,  B01J2/04 ,  B01J2/18 ,  C01B13/14 ,  C01B35/1027 ,  C01F7/02 ,  C01F7/025 ,  C01F17/0043 ,  C01G1/02 ,  C01G17/02 ,  C01G23/047 ,  C01G25/02 ,  C01G33/00 ,  C01G41/02 ,  C01P2004/50 ,  C01P2004/82 ,  C01P2006/10 ,  C01P2006/12 ,  C04B35/626 ,  C04B35/62695

摘要： Novel methods for processing fumed metallic oxides into globular metallic oxide agglomerates are provided. The methodology may allow for fumed metallic oxide particles, such as fumed silica and fumed alumina particles, to be processed into a globular morphology to improve handling while retaining a desirable surface area. The processes may include providing fumed metallic oxide particles, combining the particles with a liquid carrier to form a suspension, atomizing the solution of suspended particles, and subjecting the atomized droplets to a temperature range sufficient to remove the liquid carrier from the droplets, to produce metallic oxide-containing agglomerations.

公开(公告)号：US09969621B2

公开(公告)日：2018-05-15

申请号：US15146037

申请日：2016-05-04

申请人： Saudi Arabian Oil Company

发明人： Michele Louisa Ostraat

IPC分类号： B01J2/04 ,  B01J2/18 ,  C01B13/14 ,  C01B33/18 ,  C01B35/10 ,  C04B35/626 ,  C01F7/04 ,  C01F17/00 ,  C01G1/02 ,  C01G17/02 ,  C01G23/04 ,  C01G25/02 ,  C01G33/00 ,  C01G41/02 ,  B01J2/00 ,  C01F7/02 ,  C01G23/047

CPC分类号： C01B33/18 ,  B01J2/00 ,  B01J2/04 ,  B01J2/18 ,  C01B13/14 ,  C01B35/1027 ,  C01F7/02 ,  C01F7/025 ,  C01F17/0043 ,  C01G1/02 ,  C01G17/02 ,  C01G23/047 ,  C01G25/02 ,  C01G33/00 ,  C01G41/02 ,  C01P2004/50 ,  C01P2004/82 ,  C01P2006/10 ,  C01P2006/12 ,  C04B35/626 ,  C04B35/62695

摘要： Novel methods for processing fumed metallic oxides into globular metallic oxide agglomerates are provided. The methodology may allow for fumed metallic oxide particles, such as fumed silica and fumed alumina particles, to be processed into a globular morphology to improve handling while retaining a desirable surface area. The processes may include providing fumed metallic oxide particles, combining the particles with a liquid carrier to form a suspension, atomizing the solution of suspended particles, and subjecting the atomized droplets to a temperature range sufficient to remove the liquid carrier from the droplets, to produce metallic oxide-containing agglomerations.

公开(公告)号：US09416016B2

公开(公告)日：2016-08-16

申请号：US13820574

申请日：2011-09-08

申请人： Puru Jena ,  Gerd Gantefoer

发明人： Puru Jena ,  Gerd Gantefoer

IPC分类号： A01N59/16 ,  A01N59/20 ,  A61K33/34 ,  C01B35/10 ,  C01B35/12 ,  A61K33/24 ,  C09K3/00

CPC分类号： C01B35/1027 ,  A01N59/16 ,  A01N59/20 ,  A61K33/24 ,  A61K33/34 ,  C01B35/127 ,  C09K3/00

摘要： Hyperhalogens, a new class of highly electronegative species, are now invented. A hyperhalogen is a superhalogen-containing composition in which the electron affinity (EA) of the hyperhalogen is even larger than that of the superhalogens they are composed of. Novel production methods are provided in which highly electronegative species are produced by surrounding a central metal atom by superhalogen moieties.

摘要翻译： 目前，已经发明了一类高度负电荷物种的超卤素。 高卤素是含有超卤素的组合物，其中超卤素的电子亲和力（EA）甚至比它们组成的超级卤素的电子亲和力（EA）更大。 提供了新的制备方法，其中通过用超卤素部分包围中心金属原子来产生高度负电荷的物质。