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公开(公告)号:US5114563A
公开(公告)日:1992-05-19
申请号:US618761
申请日:1990-11-27
申请人: Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
发明人: Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
IPC分类号: B01J20/18 , B01J29/85 , C01B37/08 , C07C2/54 , C07C2/58 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号: C07C5/41 , B01J20/18 , B01J29/85 , C01B37/08 , C07C2/54 , C07C2/58 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/85
摘要: The catalytic conversion of hydrocarbon feedstocks is affected under effective conversion process conditions in the presence of silicoaluminophosphate-based catalyst compositions.
摘要翻译: 在基于硅铝磷酸盐的催化剂组合物存在下,烃原料的催化转化在有效的转化工艺条件下受到影响。
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公开(公告)号:US4440871A
公开(公告)日:1984-04-03
申请号:US400438
申请日:1982-07-26
申请人: Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
发明人: Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
IPC分类号: C01B33/26 , B01J20/18 , B01J21/00 , B01J29/04 , B01J29/85 , C01B37/08 , C01B39/04 , C01B39/10 , C01B39/14 , C01B39/28 , C01B39/32 , C07B61/00 , C07C2/54 , C07C2/70 , C07C2/86 , C07C4/08 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/32 , C07C5/41 , C10G11/05 , C10G35/095 , C10G45/12 , C10G45/34 , C10G45/54 , C10G45/64 , C10G47/16 , C10G49/08 , B01J27/14
CPC分类号: C07C5/41 , B01J20/18 , B01J29/85 , C01B37/08 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/85
摘要: A novel class of crystalline microporous silicoaluminophosphates is synthesized by hydrothermal crystallization of silicoaluminophosphate gels containing a molecular structure-forming templating agent. The class comprises a number of distinct species, each with a unique crystal structure. The compositions exhibit properties somewhat analogous to zeolitic molecular sieves which render them useful as adsorbent or catalysts in chemical reactions such as hydrocarbon conversions.
摘要翻译: 通过含有分子结构形成模板剂的硅铝磷酸凝胶的水热结晶合成了一类新型的结晶微孔硅铝磷酸盐。 该类包括许多不同的物种,每个具有独特的晶体结构。 该组合物显示出类似于沸石分子筛的性质,其使得它们可用作化学反应如烃转化中的吸附剂或催化剂。
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公开(公告)号:US4744885A
公开(公告)日:1988-05-17
申请号:US766961
申请日:1985-08-19
IPC分类号: B01J27/185 , B01J29/84 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/02 , C01G11/02 , C01G25/00 , C01G45/04
CPC分类号: C07C5/41 , B01J27/1853 , B01J29/84 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2529/84
摘要: Novel class of crystalline microporous ferroaluminophosphate compositions containing as lattice constituents in addition to AlO.sub.2 and PO.sub.2 structural units, ferric and/or ferrous iron in tetrahedral coordination with oxygen atoms. These compositions are prepared hydrothermally using organic templating agents and are suitably employed as catalysts or adsorbents.
摘要翻译: 除AlO 2和PO 2结构单元之外还含有作为晶格组分的结晶微孔铁铝磷酸盐组合物的新型,与氧原子四面体配位的铁和/或亚铁。 这些组合物是使用有机模板剂水热制备的,并且适合用作催化剂或吸附剂。
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公开(公告)号:US4554143A
公开(公告)日:1985-11-19
申请号:US514335
申请日:1983-07-15
IPC分类号: B01J20/02 , B01J27/185 , B01J29/84 , C01B25/45 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C11/09 , B01J27/18
CPC分类号: C07C5/41 , B01J20/0292 , B01J27/1853 , B01J29/84 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2529/84
摘要: Novel class of crystalline microporous ferroaluminophosphate compositions containing as lattice constituents in addition to AlO.sub.2 and PO.sub.2 structural units, ferric and/or ferrous iron in tetrahedral coordination with oxygen atoms. These compositions are prepared hydrothermally using organic templating agents and are suitably employed as catalysts or adsorbents.
摘要翻译: 除AlO 2和PO 2结构单元之外还含有作为晶格组分的结晶微孔铁铝磷酸盐组合物的新型,与氧原子四面体配位的铁和/或亚铁。 这些组合物是使用有机模板剂水热制备的,并且适合用作催化剂或吸附剂。
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公开(公告)号:US4842836A
公开(公告)日:1989-06-27
申请号:US843295
申请日:1986-03-24
CPC分类号: C01B39/48 , B01J29/70 , C07C4/06 , C07C2529/70 , Y10S423/37
摘要: A novel crystalline aluminosilicate composition denominated "zeolite LZ-133" or simply "LZ-133" and having uniform pore dimensions of approximately 4.3 Angstroms is prepared hydrothermally from a reaction mixture containing as essential reagents, water, alkali or alkaline earth metal oxide, alumina, silica and a quaternary ammonium compound.
摘要翻译: 以含有作为必需试剂,水,碱金属或碱土金属氧化物的反应混合物,氧化铝,氧化铝,水合氧化铝,水热法制备了名为“沸石LZ-133”或简称为“LZ-133”并具有约4.3埃的均匀孔径的新型结晶硅铝酸盐组合物 ,二氧化硅和季铵化合物。
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6.
公开(公告)号:US5057295A
公开(公告)日:1991-10-15
申请号:US845255
申请日:1986-03-28
IPC分类号: B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号: C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要: Molecular sieve compositions having three-dimensional microporous framework structures of BO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(B.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline port system; "m" represents the molar amount of "R" present per mole of (B.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fraction of boron, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译: 公开了具有BO2,AlO2,PO2和SiO2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成:mR:(BwAlxPySiz)O 2,其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔(BwAlxPySiz)O 2存在的“R”摩尔量; 和“w”,“x”,“y”和“z”分别表示作为四面体氧化物存在的硼,铝,磷和硅的摩尔分数。 还公开了它们作为吸附剂,催化剂等的用途。
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公开(公告)号:US4952383A
公开(公告)日:1990-08-28
申请号:US029540
申请日:1987-03-24
IPC分类号: B01J20/18 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号: C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要: Molecular sieves having three-dimensional microporous framework structures of BO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (B.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (B.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of boron, aluminum and phosphorus, respectively, present as tetrahedral oxides. The use of these molecular sieves as adsorbents, catalysts etc. is also disclosed.
摘要翻译: 公开了具有BO2,AlO2和PO2四面体单元的三维微孔骨架结构的分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成:mR:(BxAlyPz)O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔(BxAlyPz)O 2存在的“R”摩尔量; 和“x”,“y”和“z”分别表示作为四面体氧化物存在的硼,铝和磷的摩尔分数。 还公开了使用这些分子筛作为吸附剂,催化剂等。
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公开(公告)号:US4940570A
公开(公告)日:1990-07-10
申请号:US835293
申请日:1986-03-03
IPC分类号: B01J29/84 , C01B25/45 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号: C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要: Molecular sieve compositions having three-dimensional microporous framework structures of BeO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Be.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Be.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of beryllium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译: 公开了具有BeO 2,AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成:mR:(BexAlyPz)O 2,其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔(BexAlyPz)O 2存在的“R”摩尔量; 和“x”,“y”和“z”分别表示作为四面体氧化物存在的铍,铝和磷的摩尔分数。 还公开了它们作为吸附剂,催化剂等的用途。
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9.
公开(公告)号:US4781814A
公开(公告)日:1988-11-01
申请号:US46396
申请日:1987-05-06
IPC分类号: B01J29/84 , C01B37/06 , C01B39/54 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/05 , C10G47/02 , C10G11/04 , C10G45/12 , C10G47/04
CPC分类号: C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要: Crystalline molecular sieves having three-dimensional microporous framework structure of MO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis are expressed by the formula:mR: (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; "M" represents at least two elements capable of forming framework tetrahedral oxides and selected from the group consisting of arsenic, beryllium, boron, chromium, gallium, germanium, lithium and vanadium; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed. The catalyst is useful in the cracking and hydrocracking of various hydrocarbonaceous feeds.
摘要翻译: 公开了具有MO2,AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基的经验化学组成由下式表示:mR:(MxAlyPz)O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔(M×AlyPz)O 2存在的“R”摩尔量; “M”表示能够形成骨架四面体氧化物并选自砷,铍,硼,铬,镓,锗,锂和钒的至少两种元素; 和“x”,“y”和“z”分别表示作为四面体氧化物存在的“M”,铝和磷的摩尔分数。 公开了它们作为吸附剂,催化剂等的用途。 该催化剂可用于各种烃类进料的裂化和加氢裂化。
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公开(公告)号:US4793984A
公开(公告)日:1988-12-27
申请号:US600312
申请日:1984-04-13
申请人: Brent M. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人: Brent M. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号: B01J20/18 , B01J29/04 , B01J29/85 , C01B37/06 , C01B37/08 , C01B39/04 , C01B39/10 , C01B39/12 , C07B61/00 , C07C2/12 , C07C2/54 , C07C2/70 , C07C2/86 , C07C4/06 , C07C4/08 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C01B25/26 , B01J27/182
CPC分类号: C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (El.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译: 公开了具有ELO2,AlO2,SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有由下式表示的无水基础上的经验化学组成:mR:(ELwAlxPySiz)O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂:“m”表示“ 每摩尔(ElwAlxPySiz)O2存在R“ “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”,“x”,“y”和“z”分别表示作为骨架氧化物存在的元素“EL”,铝,磷和硅的摩尔分数。 还公开了它们作为吸附剂,催化剂等的用途。
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