PHOSPHORUS-CONTAINING COMPOUND, AND CURABLE EPOXY RESIN COMPOSITION CONTAINING SAME
    1.
    发明申请
    PHOSPHORUS-CONTAINING COMPOUND, AND CURABLE EPOXY RESIN COMPOSITION CONTAINING SAME 审中-公开
    含有含磷的化合物和可固化的环氧树脂组合物

    公开(公告)号:US20160152643A1

    公开(公告)日:2016-06-02

    申请号:US14900844

    申请日:2014-08-21

    申请人: ADEKA CORPORATION

    IPC分类号: C07F9/32

    摘要: The purpose of the present invention is to provide a phosphorus-containing compound having reactivity with a glycidyl group, specifically a phosphorus-containing compound represented by general formula (I). (In the formula, m represents a numerical value of 1 to 10; R1 and R2 independently represent a hydrogen atom, an alkyl group or an aryl group; R3 represents an alkyl group, an alkanediyl group, an alkanetriyl group, an alkanetetrayl group or an aromatic group; X represents an oxygen atom or a sulfur atom; Y represents an oxygen atom, a sulfur atom or —NR4—; and R4 represents a hydrogen atom, an alkyl group or an aryl group.)

    摘要翻译: 本发明的目的是提供一种与缩水甘油基具有反应性的含磷化合物,特别是由通式(I)表示的含磷化合物。 (式中,m表示1〜10的数值,R 1和R 2分别表示氢原子,烷基或芳基,R 3表示烷基,烷二基,烷三甲酰基,烷基四氟乙基, 芳基; X表示氧原子或硫原子; Y表示氧原子,硫原子或-NR4-,R4表示氢原子,烷基或芳基)。

    Methoxy-substituted cyanophenyl ester derivatives of phosphorus acids as
insecticidal agents
    5.
    发明授权
    Methoxy-substituted cyanophenyl ester derivatives of phosphorus acids as insecticidal agents 失效
    作为杀虫剂的磷酸的甲氧基取代的氰基苯酯衍生物

    公开(公告)号:US4046885A

    公开(公告)日:1977-09-06

    申请号:US688506

    申请日:1976-05-20

    申请人: Edward N. Walsh

    发明人: Edward N. Walsh

    摘要: Methoxy-substituted cyanophenyl ester derivatives of phosphinic, phosphonic, phosphoric, thiophosphinic, thiophosphonic, and thiophosphoric acids having the general formula: ##STR1## wherein R and R.sup.1 are independently selected from the group consisting of lower alkyl, chloro-substituted lower alkyl, lower alkoxy, phenyl, phenoxy and lower dialkylamide, and X is oxygen or sulfur. The compounds are effective pesticides especially in the control of houseflies, American cockroach, milkweed bug and two-spotted mite. Representative compounds are O-ethyl-O-(2-methoxy-4-cyanophenyl) ethyl phosphonothioate and O,O-dimethyl-O-(2-methoxy-4-cyanophenyl) phosphorothioate.

    摘要翻译: 具有以下通式的次膦酸,膦酸,磷酸,硫代亚膦酸,硫代膦酸和硫代磷酸的甲氧基取代的氰基苯酯衍生物,其中R和R 1独立地选自低级烷基,氯取代的低级烷基,低级 烷氧基,苯基,苯氧基和低级二烷基酰胺,X是氧或硫。 这些化合物是有效的农药,特别是控制家蝇,美国蟑螂,奶草虫和双斑螨。 代表性的化合物是O-乙基-O-(2-甲氧基-4-氰基苯基)乙基硫代磷酸酯和O,O-二甲基-O-(2-甲氧基-4-氰基苯基)硫代磷酸酯。

    Multi-element Standard for Nuclear Magnetic Resonance Spectroscopy
    7.
    发明申请
    Multi-element Standard for Nuclear Magnetic Resonance Spectroscopy 审中-公开
    核磁共振光谱多元素标准

    公开(公告)号:US20150077104A1

    公开(公告)日:2015-03-19

    申请号:US14387520

    申请日:2013-03-15

    IPC分类号: C07F9/36 G01N24/08 C07F9/12

    摘要: Organic compounds which contain nitrogen, fluorine, and phosphorus atoms together with carbon atoms and hydrogen atoms and which can be used as a multi-element standard for 1H—, 13C—, 15N—, 19F—, and 31P nuclear magnetic resonance spectroscopy. Also, a nuclear magnetic resonance spectroscopy method, preferably a quantitative nuclear magnetic resonance spectroscopy method, using said compounds and a method for qualitatively and/or quantitatively determining an analyte using such a nuclear magnetic resonance spectroscopy method.

    摘要翻译: 含有氮,氟和磷原子以及碳原子和氢原子的有机化合物,可用作1H-,13C-,15N-,19F-和31P核磁共振光谱的多元素标准。 此外,使用所述化合物的核磁共振光谱法,优选定量核磁共振光谱法和使用这种核磁共振光谱法定性和/或定量测定分析物的方法。

    Preparation of alkane phosphonic and phosphinic acid aryl esters
    9.
    发明授权
    Preparation of alkane phosphonic and phosphinic acid aryl esters 失效
    烷烃膦酸和次膦酸芳酯的制备

    公开(公告)号:US4377537A

    公开(公告)日:1983-03-22

    申请号:US222221

    申请日:1981-01-02

    CPC分类号: C07F9/4084 C07F9/3282

    摘要: A process for the preparation of an alkane phosphonic acid diaryl ester or an alkane phosphinic acid aryl ester of the formula ##STR1## wherein R.sup.1 is C.sub.1 -C.sub.20 alkyl or alkenyl group,R.sup.2 is a C.sub.1 -C.sub.20 alkyl or alkenyl group or a C.sub.6 -C.sub.10 aryl or aryloxy group,R.sup.3 is C.sub.6 -C.sub.10 aryl group,k is 0 or 1,p is 1 or 2,k+p=2,plus an alkane phosphonic acid diaryl ester, alkane phosphinic acid aryl ester or phosphine oxide of the formula ##STR2## R.sup.4 and R.sup.5 each independently is C.sub.1 -C.sub.20 alkyl group, a C.sub.6 -C.sub.10 aryl group or a C.sub.6 -C.sub.10 aryloxy group,R.sup.6 is C.sub.1 -C.sub.20 alkyl or alkenyl group,n and m each is 0, 1 or 2, andn+m=2,comprising reacting an aryloxy compound of trivalent phosphorus of the formula ##STR3## (a) with an alkyl phosphite or alkyl phosphonite of the formula ##STR4## in the presence of an Arbusow catalyst, or (b) a rearrangement product formed in the presence of an Arbusow catalyst and of the formula ##STR5##

    摘要翻译: 制备下式的烷烃膦酸二芳基酯或烷烃次膦酸芳基酯的方法,其中R 1是C 1 -C 20烷基或烯基,R 2是C 1 -C 20烷基或链烯基或C 6 -C 20烷基, C10芳基或芳氧基,R3为C6-C10芳基,k为0或1,p为1或2,k + p = 2,加上烷烃膦酸二芳基酯,烷烃次膦酸芳酯或氧化膦 其中R4和R5各自独立地为C1-C20烷基,C6-C10芳基或C6-C10芳氧基,R6是C1-C20烷基或烯基,n和m各自为0 ,1或2和n + m = 2,包括在Arbusow催化剂的存在下使式(a)的三价磷的芳氧基化合物与式IMAMA的烷基亚磷酸酯或烷基亚膦酸酯反应, 或(b)在Arbusow催化剂存在下形成并具有式(IMAGE)的重排产物