公开(公告)号：US20140038829A1

公开(公告)日：2014-02-06

申请号：US14112086

申请日：2012-05-09

申请人： Kei Hanafusa ,  Genki Honda ,  Kotaro Ohki ,  Tsuyoshi Nakanishi ,  Takahiro Taneda ,  Tatsuoki Nagaishi

发明人： Kei Hanafusa ,  Genki Honda ,  Kotaro Ohki ,  Tsuyoshi Nakanishi ,  Takahiro Taneda ,  Tatsuoki Nagaishi

IPC分类号： H01B12/02

CPC分类号： H01B12/02 ,  H01L39/143 ,  H01L39/2422 ,  H01L39/2425 ,  H01L39/2448 ,  Y10T428/265

摘要： A superconducting thin film material exhibiting excellent superconducting properties and a method of manufacturing the same are provided. A superconducting thin film material includes a substrate, and a superconducting film formed on the substrate. The superconducting film includes an MOD layer formed by an MOD process, and a gas-phase-formed layer formed on the MOD layer by a gas-phase process. Since the MOD layer is formed first and then the gas-phase-formed layer is formed in this manner, degradation of the properties of the gas-phase-formed layer due to heat treatment in the step of forming the MOD layer (heat treatment in the MOD process) can be prevented.

摘要翻译： 提供了具有优异的超导特性的超导薄膜材料及其制造方法。 超导薄膜材料包括衬底和形成在衬底上的超导膜。 超导膜包括通过MOD工艺形成的MOD层和通过气相法在MOD层上形成的气相形成层。 由于首先形成MOD层，于是以这种方式形成气相形成层，所以在形成MOD层的步骤中由于热处理而导致气相形成层的性能降低（热处理 可以防止MOD过程）。

公开(公告)号：US08629087B2

公开(公告)日：2014-01-14

申请号：US13137042

申请日：2011-07-18

申请人： Alexander Usoskin ,  Klaus Schlenga

发明人： Alexander Usoskin ,  Klaus Schlenga

IPC分类号： H01L39/24

CPC分类号： H01L39/128 ,  H01L39/126 ,  H01L39/2448 ,  H01L39/2483

摘要： A high temperature superconductor (=HTS) coated conductor (1), comprising an HTS layer (11) deposited epitaxially on a substrate (2), wherein the HTS layer (11) exhibits a lattice with a specific crystal axis being oriented perpendicular to the substrate plane (SP), in particular wherein the HTS layer material is of ReBCO type and the c-axis (c) is oriented perpendicular to the substrate plane (SP), wherein the HIS layer (11) comprises particle inclusions (4), in particular wherein the particle inclusions (4) may be used to introduce pinning of magnetic flux, is characterized in that at least a part (4a) of the particle inclusions (4) are formed of the same material as the HTS layer (11), and/or of chemical fractions of the material of the HTS layer (11), such that the average stoichiometry of said part (4a) of the particle inclusions (4) corresponds to the stoichiometry of the HTS layer (11), and that the particle inclusions of said part (4a) are discontinuities of the lattice of the HTS layer (11). A more simple method for producing a HTS coated conductor with reduced losses, and with improved critical current and critical magnetic field is thereby provided.

摘要翻译： 一种高温超导体（= HTS）涂覆导体（1），包括在衬底（2）上外延沉积的HTS层（11），其中HTS层（11）呈现出具有垂直于 衬底平面（SP），特别地其中HTS层材料为ReBCO型，c轴（c）垂直于衬底平面（SP）定向，其中HIS层（11）包括颗粒夹杂物（4）， 特别是其中可以使用粒子夹杂物（4）引入磁通的钉扎，其特征在于，粒子夹杂物（4）的至少一部分（4a）由与HTS层（11）相同的材料形成， ，和/或HTS层（11）的材料的化学级分，使得所述颗粒夹杂物（4）的所述部分（4a）的平均化学计量对应于HTS层（11）的化学计量，并且 所述部分（4a）的颗粒夹杂物是不规则的 HTS层（11）。 从而提供了一种用于制造具有降低的损耗并且具有改善的临界电流和临界磁场的HTS涂覆导体的更简单的方法。

公开(公告)号：US07871663B1

公开(公告)日：2011-01-18

申请号：US11543286

申请日：2006-10-03

申请人： Paul N. Barnes ,  Joseph W. Kell ,  Timothy J. Haugan

发明人： Paul N. Barnes ,  Joseph W. Kell ,  Timothy J. Haugan

IPC分类号： B05D5/12 ,  H01L39/24 ,  C23C14/00

CPC分类号： H01L39/2483 ,  C23C14/087 ,  H01L39/2448 ,  Y10S505/741 ,  Y10T29/49014

摘要： A method for enhancing the flux pinning of a YBCO superconductor by substituting minute quantities of rare earth elements (La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) or other deleterious elements (Sc, etc.) for Y in YBCO thin films is described. The method of the present invention enables enhanced flux pinning of the material while not significantly increasing the cost of the HIS material and can be used in all HTS deposition methods since it is not process dependent.

摘要翻译： 通过代替微量稀土元素（La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu）来增强YBCO超导体的磁通钉扎的方法， 或YBCO薄膜中Y的其他有害元素（Sc等）。 本发明的方法能够增强材料的磁通钉扎，同时不会显着增加HIS材料的成本，并可用于所有的HTS沉积方法，因为它不是过程依赖的。

公开(公告)号：US20070129255A1

公开(公告)日：2007-06-07

申请号：US11565888

申请日：2006-12-01

申请人： Chakrapani Varanasi ,  Paul Barnes

发明人： Chakrapani Varanasi ,  Paul Barnes

IPC分类号： H01L39/24

CPC分类号： H01L39/2448 ,  C23C14/087 ,  C23C14/088 ,  C23C14/28 ,  H01L39/2483

摘要： Nanometer-sized non-superconducting particulates in superconductive REBCO films, where RE is a rare earth metal, for flux pinning enhancement and a method of forming are disclosed. A target with a second phase material sector portion and a superconductive material portion is used in a pulse laser deposition process to form films on substrates according to the present invention. The films consist of 10-20 nm-sized precipitates. In a 0.5 μm thick film, a transport critical current density (Jc)>3 MA/cm2 at 77K in self-field was measured. In one embodiment, magnetization Jc at 77 K and 65K showed significant improvements in a composite YBCO films with fine precipitates produced according to the present invention as compared to non-doped (standard) YBCO films (>10 times increase at 9 T, 65 K).

摘要翻译： 公开了超导REBCO膜中的纳米尺寸非超导颗粒，其中RE是稀土金属，用于焊剂钉扎增强和形成方法。 在脉冲激光沉积工艺中使用具有第二相材料部分和超导材料部分的靶以在根据本发明的衬底上形成膜。 膜由10-20nm的沉淀物组成。 在0.5μm厚的膜中，测量在自激光下在77K下的传输临界电流密度（JCC）> 3MA / cm 2。 在一个实施方案中，与非掺杂（标准）YBCO膜（> 10）相比，在77K和65K下的磁化强度显示出与根据本发明制备的细微沉淀物的复合YBCO膜的显着改进 时间增加在9T，65K）。

公开(公告)号：US07220315B2

公开(公告)日：2007-05-22

申请号：US10628459

申请日：2003-07-29

申请人： Yasuhiro Iijima

发明人： Yasuhiro Iijima

IPC分类号： C30B25/12 ,  C30B25/24

CPC分类号： C23C14/3442 ,  C23C14/08 ,  C23C14/087 ,  C23C14/46 ,  H01L39/2448 ,  H01L39/2461

摘要： A production method for a polycrystalline thin film, depositing polycrystalline thin film on a polycrystalline substrate. The temperature of the polycrystalline substrate is set within a range from 150° C. to 250° C., the ion beam energy of the ion beam is adjusted within a range from 175 eV to 225 eV, and the ion beam is irradiated at an angle of incidence from 50° to 60° with respect to the normal for the film forming surface of the polycrystalline substrate. By this production method, the grain boundary inclination angle, formed by identical crystal axes of the crystal grains along a plane parallel to the film forming surface of the polycrystalline substrate, is limited to 20° or less, and a polycrystalline thin film having a strong crystal orientation can be stably produced.

摘要翻译： 一种用于多晶薄膜的制造方法，在多晶基板上沉积多晶薄膜。 将多晶基板的温度设定在150℃〜250℃的范围内，将离子束的离子束能量调整为175eV〜225eV的范围，将离子束照射在 入射角相对于多晶衬底的成膜表面的法线为50°至60°。 通过该制造方法，将晶粒沿着与多晶基板的成膜面平行的平面的晶粒的相同晶轴形成的晶界倾斜角限制在20°以下，具有强的多晶薄膜 可以稳定地制造晶体取向。

公开(公告)号：US20060073974A1

公开(公告)日：2006-04-06

申请号：US10925479

申请日：2004-08-25

申请人： Judith Driscoll ,  Stephen Foltyn

发明人： Judith Driscoll ,  Stephen Foltyn

IPC分类号： H01L39/12

CPC分类号： H01L39/126 ,  H01L39/2448 ,  H01L39/2483 ,  Y10S505/701 ,  Y10S505/779

摘要： An superconductive article and method of forming such an article is disclosed, the article including a substrate and a layer of a rare earth barium cuprate film upon the substrate, the rare earth barium cuprate film including two or more rare earth metals capable of yielding a superconductive composition where ion size variance between the two or more rare earth metals is characterized as greater than zero and less than about 10×10−4, and the rare earth barium cuprate film including two or more rare earth metals is further characterized as having an enhanced critical current density in comparison to a standard YBa2Cu3Oy composition under identical testing conditions.

摘要翻译： 公开了一种形成这种制品的超导制品和方法，该制品包括在基底上的基底和稀土钡铜酸盐膜层，稀土钡铜酸盐膜包括两种或更多种能够产生超导体的稀土金属 两种或更多种稀土金属之间的离子尺寸变化的特征在于大于零且小于约10×10 -4的组成，并且包括两种或更多种稀土金属的稀土钡铜酸盐膜进一步 其特征在于在相同的测试条件下与标准YBa 2 Cu 3 O 3 O 3组合物相比具有增强的临界电流密度。

公开(公告)号：US20040247780A1

公开(公告)日：2004-12-09

申请号：US10456733

申请日：2003-06-05

发明人： Venkat Selvamanickam ,  Hee-Gyoun Lee

IPC分类号： B05D005/12 ,  H01L039/24

CPC分类号： H01L39/2448 ,  C23C14/087 ,  C23C14/22 ,  C23C14/28 ,  C23C16/408 ,  C23C16/486 ,  H01L39/2441

摘要： An ion source impinging on the surface of the substrate to be coated is used to enhance a MOCVD, PVD or other process for the preparation of superconducting materials.

摘要翻译： 用于照射待涂覆的基底表面上的离子源用于增强用于制备超导材料的MOCVD，PVD或其它方法。

公开(公告)号：US20020119893A1

公开(公告)日：2002-08-29

申请号：US09950324

申请日：2001-09-10

发明人： Robert A. Hughes ,  Patrick J. Turner ,  John S. Preston

IPC分类号： C30B023/00 ,  C30B025/00 ,  C30B028/12 ,  C30B028/14 ,  H01L033/00 ,  H01L039/00 ,  H01L039/24

CPC分类号： H01L39/2448 ,  C30B23/02 ,  C30B29/22 ,  C30B29/225 ,  H01L39/2422

摘要： Disclosed herein is a method of forming a superconductor, comprising the steps of: providing a substrate and exposing the substrate to a first atmosphere, including precursors to form a first epitaxial layer segment. The first layer segment is then exposed to a second atmosphere, including precursors to form a second epitaxial layer segment, and the second layer segment is exposed to a third atmosphere including precursors to form a third epitaxial layer segment. Each of the first and third layer segments are each formed from a superconductor material and the second layer segment is formed from a material different from the first and third layer segments and the first, second and third layer segments have a collective thickness, the third layer segment having an outer surface with a roughness which is less than that of a single layer of the superconductor material with a thickness equal to the collective thickness.

摘要翻译： 本文公开了形成超导体的方法，包括以下步骤：提供衬底并将衬底暴露于第一气氛，包括前体以形成第一外延层段。 然后将第一层段暴露于第二气氛，包括形成第二外延层段的前体，并且将第二层段暴露于包含前体的第三气氛以形成第三外延层段。 第一和第三层段中的每一个均由超导体材料形成，第二层段由不同于第一和第三层段的材料形成，并且第一，第二和第三层段具有总体厚度，第三层 其外表面的粗糙度小于具有等于集体厚度的厚度的超导体材料的单层的粗糙度。

公开(公告)号：US5846911A

公开(公告)日：1998-12-08

申请号：US889236

申请日：1997-07-08

申请人： Herbert C. Freyhardt ,  Alexander Usoskin ,  Francisco Garcia-Moreno

发明人： Herbert C. Freyhardt ,  Alexander Usoskin ,  Francisco Garcia-Moreno

IPC分类号： C23C14/02 ,  C23C14/16 ,  C23C14/18 ,  C23C14/24 ,  H01B12/06 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/2454 ,  H01L39/2448 ,  Y10S505/704

摘要： A method of producing a superconductive coating (19) on an elongated substrate (12) is indicated, whereby the substrate (12) is drawn through a deposition chamber (1) in which it is also heated in a heating zone (2) and is coated with a superconducting material. To improve the current carrying capacity, the substrate (12) is coated with the superconducting material in a geometric form which differs from the use of the finished product in a way so that a compressive strain is created in the substrate plane of the superconductive coating (19) for the geometric form of the substrate (12) taking place when it is put to use.

摘要翻译： 指示在细长基板（12）上制造超导涂层（19）的方法，由此基板（12）被吸引通过沉积室（1），其中其也在加热区域（2）中被加热，并且是 涂有超导材料。 为了提高电流承载能力，衬底（12）以几何形式涂覆超导材料，其不同于最终产品的使用，使得在超导涂层的衬底平面中产生压缩应变（ 19），用于在投入使用时发生的基板（12）的几何形状。

公开(公告)号：US5693146A

公开(公告)日：1997-12-02

申请号：US478646

申请日：1995-06-07

申请人： Hidenori Nakanishi ,  Saburo Tanaka ,  Hideo Itozaki ,  Shuji Yazu

发明人： Hidenori Nakanishi ,  Saburo Tanaka ,  Hideo Itozaki ,  Shuji Yazu

IPC分类号： C01B13/14 ,  C01G1/00 ,  C23C14/28 ,  C30B29/22 ,  H01L39/24 ,  C23C14/00

CPC分类号： C23C14/28 ,  H01L39/2448

摘要： There is disclosed a device for forming a thin film on a substrate by irradiating a target of a compound oxide superconducting material with a laser beam and evaporating on the substrate a thin film corresponding to a composition of the target in an oxygen ambient atmosphere by laser evaporation, a scanning optical system for causing the laser beam to scan being disposed in an optical path of the laser beam.

摘要翻译： 公开了一种用于通过用激光束照射复合氧化物超导材料的目标物在基板上形成薄膜的装置，并且通过激光蒸发在基板上在氧气环境气氛中在基板上蒸发对应于靶组成的薄膜 用于使激光束扫描的扫描光学系统设置在激光束的光路中。