METHOD FOR SYNTHESIS OF ORGANIC IODIDES, A PEROVSKITE-FORMING COMPOSITION COMPRISING AN ORGANIC IODIDE AND A PHOTOVOLTAIC CELL WITH A PEROVSKITE LAYER OBTAINED THEREFROM

    公开(公告)号:US20220185765A1

    公开(公告)日:2022-06-16

    申请号:US17601065

    申请日:2020-06-01

    申请人: SAULE S.A

    摘要: A method for obtaining a salt with a general formula: RxNI, wherein: RxN is an organic cation (RxN+), R represents substituents (R−) independently selected from a group consisting of organic substituents: R1−, R2—, R3— and hydrogen (H—), x is a number of the substituents R— directly linked with the nitrogen (N) atom in the organic cation RxN+, wherein x is 3 or 4, I is an iodide anion (I−). The method comprises: preparing a reaction mixture comprising the steps of: synthesizing hydrogen iodide (HI) in situ by mixing molecular iodine (I2) with formic acid (COOH) in a molar ratio of molecular iodine (I2): formic acid (COOH) of no less than 1.01:1, in a solvent medium, introducing into the solvent medium a compound being a donor of organic cation RxN+ in an amount providing the molar ratio of the donor of organic cation RxN+: molecular iodine (I2) of no less than 1.01:1, and maintaining the reaction mixture at a temperature of not less than 20° C. for the time necessary to obtain the reaction product being the salt with the general formula RxNI. The obtained product is a substrate for synthesis of perovskites.

    Amidine compound and use thereof
    6.
    发明授权
    Amidine compound and use thereof 有权
    脒化合物及其用途

    公开(公告)号:US09309191B2

    公开(公告)日:2016-04-12

    申请号:US14779095

    申请日:2014-03-20

    发明人: Hiroto Tamashima

    摘要: An amidine compound represented by formula (1) wherein R1, R2, R3, R4 and R5 are the same or different and represent a C1 to C5 alkyl group optionally having one or more halogen atoms or the like; R6 and R7 are a hydrogen atom or the like; R8 and R9 are the same or different and represent a C1 to C3 alkyl group optionally having one or more halogen atoms or the like; and R10 and R11 are the same or different and represent a C1 to C6 alkyl group optionally having one or more halogen atoms or the like, has an excellent control effect on plant diseases.

    摘要翻译: 由式(1)表示的脒化合物,其中R 1,R 2,R 3,R 4和R 5相同或不同,表示任选具有一个或多个卤素原子等的C 1 -C 5烷基; R6和R7是氢原子等; R8和R9相同或不同,表示任选具有一个或多个卤素原子等的C 1至C 3烷基; R10和R11相同或不同,表示任选具有一个或多个卤素原子等的C 1〜C 6烷基,对植物病害具有优异的防治效果。