COPPER-PALLADIUM-LOADED MESOPOROUS SILICON CARBIDE-BASED CATALYST, PREPARATION METHOD AND APPLICATION THEREOF

    公开(公告)号:US20210404077A1

    公开(公告)日:2021-12-30

    申请号:US17126052

    申请日:2020-12-18

    申请人: Tongji University

    摘要: A copper-palladium-loaded mesoporous silicon carbide-based catalyst, a preparation method, and an application thereof are provided. First, a mesoporous silicon carbide material is prepared by using mesoporous silica as a hard template; subsequently, the mesoporous silicon carbide material is mixed with a copper-palladium precursor mixed solution, and dried after the solvent is completely volatilized. The dried powder is successively subjected to calcination with N2 and reduction with H2 to finally obtain the copper-palladium-loaded mesoporous silicon carbide-based catalyst. The catalyst is made into an electrode, and the nitrate in water body is catalytically reduced by electrochemical method. The preparation method of the catalyst of the present invention is simple. The catalyst can realize high-efficiency catalytic denitrification at a low metal loading amount, with high selectivity of nitrogen. Moreover, the catalyst has the advantages of high activity, good stability, wide application range and low cost.

    ELECTRODE FOR GENERATING CHLORINE
    5.
    发明公开

    公开(公告)号:US20240209531A1

    公开(公告)日:2024-06-27

    申请号:US18390714

    申请日:2023-12-20

    摘要: Disclosed herein are an electrode for generating chlorine comprising in sequence a substrate consisting of titanium or titanium-based alloy, an intermediate layer, and a catalyst layer, and a method for generating chlorine by electrolyzing dilute salt water in an electrolytic cell comprising at least a pair of said electrodes with an anode and a cathode. The intermediate layer comprises a porous platinum coating and titanium oxide provided on the substrate, the catalyst layer, in particular, consists of 2 mol % to 24 mol % platinum, 41 mol % to 49 mol % iridium oxide, and 35 mol % to 49 mol % tantalum oxide in metal equivalent. The electrode and the method with high chlorine generation efficiency and longer life time are provided under the condition of electrolyzing dilute salt water while repeatedly switching the polarity of anode and cathode every 5 to 60 seconds at a current density of 0.05 to 0.25 A·cm−2.

    Electrode for Electrolysis
    7.
    发明公开

    公开(公告)号:US20230295819A1

    公开(公告)日:2023-09-21

    申请号:US18006306

    申请日:2021-11-08

    申请人: LG Chem, Ltd.

    摘要: The present invention relates to an electrode for electrolysis and a method for manufacturing the same, wherein an electrode coating layer for electrolysis is provided in plurality, and the tin content in each coating layer is configured to increase as the distance from a substrate increases, and the titanium content therein is configured to decrease as the distance from the substrate increases, so that excellent performance is maintained, and also delamination and the like does not occur during firing, so that excellent durability may be implemented.

    ELECTROCATALYST SUPPORT MATERIAL
    8.
    发明公开

    公开(公告)号:US20240271298A1

    公开(公告)日:2024-08-15

    申请号:US18162306

    申请日:2023-01-31

    申请人: Robert Bosch GmbH

    摘要: An electrolyzer catalyst support includes a material including one or more transparent conducting oxide (TCO) compositions of formula (I): AxBySbwOz (I), where A is a dopant and is a halogen, alkali metal, transition metal, or metalloid, B is Zn, Cd, Sn, or Ti, x is any number between about 0.0 and 0.2, y is any number between 0.9 and 2, w is 0 or 2, and z is any number between 0.9 and 3, when A is F and B is Sn, the oxide is non-stoichiometric.