METHOD FOR PRODUCING VINYL ETHER POLYMER CONTAINING HYDROCARBON GROUP BY RADICAL POLYMERIZATION

    公开(公告)号:US20210122847A1

    公开(公告)日:2021-04-29

    申请号:US17257664

    申请日:2019-06-14

    摘要: [Object] To provide a method for producing a vinyl ether polymer containing a hydrocarbon group in a stable and efficient manner, wherein decomposition of the monomer and generation of polyacetal are suppressed.
    [Means for solving problem] The method for producing a vinyl ether polymer containing a hydrocarbon group according to the present invention comprises the step of polymerizing vinyl ether represented by the following formula (1): wherein R1 represents an aliphatic hydrocarbon group having 1 to 10 carbons or an alicyclic hydrocarbon group having 3 to 10 carbons, in the presence of water as a polymerization solvent and an organic azo-based compound as a radical polymerization initiator, under pH of 6 or more.

    Radiation curable compositions
    3.
    发明授权
    Radiation curable compositions 失效
    辐射固化组合物

    公开(公告)号:US6028124A

    公开(公告)日:2000-02-22

    申请号:US199645

    申请日:1998-11-25

    CPC分类号: C09D4/00

    摘要: This invention relates to a radiation curable compositions. More particularly this invention relates to radiation curable compositions comprising a vinyl ether compound which is free of silicon atoms, a cationic photoinitiator, a free radical photoinitiator, and dodecylphenol. The radiation curable compositions of this invention are useful for coating a thin layer film that has potential for many applications in the coating industry.

    摘要翻译: 本发明涉及可辐射固化的组合物。 更具体地说,本发明涉及包含不含硅原子的乙烯基醚化合物,阳离子光引发剂,自由基光引发剂和十二烷基苯酚的可辐射固化组合物。 本发明的可辐射固化组合物可用于涂覆在涂料工业中具有许多应用潜力的薄层膜。

    Cationically polymerizable mixtures containing selected metallocene
complex salts as curing agents
    5.
    发明授权
    Cationically polymerizable mixtures containing selected metallocene complex salts as curing agents 失效
    含有选择的茂金属络合盐作为固化剂的阳离子可聚合混合物

    公开(公告)号:US5565500A

    公开(公告)日:1996-10-15

    申请号:US310452

    申请日:1994-09-22

    CPC分类号: G03F7/029 Y10S430/115

    摘要: The invention relates to mixtures containing:a) a cationically polymerizable compound andb) a compound of the formula I[R.sup.1 (Fe.sup.II R.sup.2).sub.a ].sub.q.sup..sym.an anX.sup..crclbar.q (I)in which a is 1 or 2, n is 1 or 2, R.sup.1 is a substituted or unsubstituted .pi.-arene, R.sup.2 is a substituted or unsubstituted .pi.-arene or cyclopentadienyl anion or indenyl anion, q is an integer from 1 to 3 and X is FSO.sub.3.sup.- or a q-valent anion of an organic sulfonic acid or of a carboxylic acid; R.sup.1 can also be a polymeric, aromatic ligand. The invention also relates to the novel compounds of the formula I. The curable mixtures can be processed in particular for the production of coatings having a good resistance to heat.

    摘要翻译: 本发明涉及含有:a)阳离子可聚合化合物和b)式I [R1(FeIIR2)a] q(+)ananX( - )q(I)的化合物,其中a为1或2,n 是1或2,R1是取代或未取代的对 - 芳基,R2是取代或未取代的对 - 芳基或环戊二烯基阴离子或茚基阴离子,q是1至3的整数,X是FSO 3 - 或q-价阴离子 的有机磺酸或羧酸; R1也可以是聚合的芳族配体。 本发明还涉及式I的新型化合物。可固化混合物可特别用于制备具有良好耐热性的涂料。

    Linear addition polymer with hyperpolarizable side groups

    公开(公告)号:US4999401A

    公开(公告)日:1991-03-12

    申请号:US171550

    申请日:1988-03-22

    摘要: A linear addition polymer having sidegroups which may be coupled to it or not through a spacer and have a molecular hyperpolarizability .beta. of at least 10.sup.-38 m.sup.4 /V, characterized in that the recurring units of the polymer correspond to the formula ##STR1## wherein X represents a hydrogen atom or a lower alkyl group and m=1 or optionally 0, wherewhen m-1Y represents a ##STR2## group and R has the meaning of (a) a hyperpolarizable group having a molecular hyperpolarizability .beta. of at least 10.sup.-38 m.sup.4 /V, in the presence or not of a spacer, and optionally along with(b) a mesogenic group in the presence or not of a spacer, and/or(c) a hydrogen atom or a substituted or unsubstituted organic group having not more than 30 carbon atoms, andwhen m=0Y represents a --CN, a substituted or unsubstituted phenyl group or a group of the formula --OR.sub.1 or --CH.sub.2 OR.sub.1, wherein R.sub.1 has the meaning of a hydrogen atom or a substituted or unsubstituted aliphatic group having not more than 20 carbon atoms, provided thatat least 10% of the recurring units in the polymer contain a hyperpolarizable group having a molecular hperpolarizability .beta. of at least 10.sup.-38 m.sup.4 /V,at the most 40% of the recurring units in the polymer contain a mesogenic group, andthat the quotient of the degree of substitution of the recurring units with a group having a molecular hyperpolarizability .beta. of at least 10.sup.-38 m.sup.4 /V and the average molecular weight of R with the meaning given under b and c amounts to at least 5.times.10.sup.-4, a non-linear optical medium thereof oriented in an electric field and electro-optical laminates comprising such a non-linear optical medium.

    Liquid phase and aqueous solutions of poly(vinyl methyl ether) from
highly purified vinyl methyl ether monomer
    10.
    发明授权
    Liquid phase and aqueous solutions of poly(vinyl methyl ether) from highly purified vinyl methyl ether monomer 失效
    来自高纯度乙烯基甲基醚单体的聚(乙烯基甲基醚)的液相和水溶液

    公开(公告)号:US5393856A

    公开(公告)日:1995-02-28

    申请号:US105889

    申请日:1993-08-11

    CPC分类号: C07C41/42 C07C41/36 C08F16/18

    摘要: A process is disclosed for the preparation of liquid and aqueous solutions of amorphous colorless poly (vinyl methyl ether) polymer with low level of impurities from purified vinyl methyl ether. The polymer has relatively high molecular weight, narrow molecular weight distribution and does not degrade readily due to the presence of impurities. The purification of the monomer uses a procedure selected from the group consisting of a vapor-liquid separation, a solid-liquid separation and combinations thereof to remove the impurities at a temperature within the range of from -20.degree. C. to +30.degree. C. The aqueous solution is prepared by devolitilization of solvent solutions of the polymerized purified vinyl methyl ether monomer. The solid polymer is prepared by heating the aqueous solution of the poly(vinyl methyl ether). The amorphous polymers of poly(vinyl methyl ether) are particularly suited for adhesive applications.

    摘要翻译: 公开了一种用于从纯化的乙烯基甲基醚制备具有低水平杂质的无定形无色聚(乙烯基甲基醚)聚合物的液体和水溶液的方法。 该聚合物具有相对高的分子量,窄的分子量分布,并且由于杂质的存在而不会容易地降解。 单体的纯化使用选自气液分离,固液分离及其组合的方法,以在-20℃至+ 30℃的温度下除去杂质 该水溶液是通过将聚合的纯化的乙烯基甲基醚单体的溶剂溶液脱挥发制备的。 通过加热聚(乙烯基甲基醚)的水溶液制备固体聚合物。 聚(乙烯基甲基醚)的无定形聚合物特别适用于粘合剂应用。