POROUS RESIN USED TO SOLID PHASE SYNTHESSIS AND PREPARATION METHOD THEREFOR

    公开(公告)号:US20230312859A1

    公开(公告)日:2023-10-05

    申请号:US18043786

    申请日:2021-02-24

    IPC分类号: C08J9/28 C08F222/34 C08F2/18

    摘要: A porous resin used to solid phase synthesis and a preparation method therefor, specifically being a porous resin having functional groups being an amino group or a hydroxyl group and a preparation method therefor. Using an olefin compound containing two cyano groups as a modified monomer, using a high internal phase emulsion as a pore-foaming agent, and performing suspension polymerization to prepare the porous resin. And then functionalizing the porous resin to obtain the porous resin having functional groups being an amino group or a hydroxyl group. Different from the existing preparation method, the modified monomer can make the distribution of the functional groups more uniform, and make the swelling degrees of the porous resin in different solvents close. The high internal phase emulsion pore-foaming agent can make the pore size distribution of the carrier narrower. The porous resin can be used as a solid phase synthesis carrier to prepare an oligonucleotide, and the use of the carrier is beneficial for improving the yield and purity of the oligonucleotide.

    Piezoelectric or pyroelectric material
    6.
    发明授权
    Piezoelectric or pyroelectric material 失效
    压电或热电材料

    公开(公告)号:US4990584A

    公开(公告)日:1991-02-05

    申请号:US275628

    申请日:1988-11-16

    摘要: A vinylidene cyanide copolymer obtained by copolymerizing vinyldene cyanide represented by formula (I) ##STR1## and a vinyl compound represented by formula (II) ##STR2## wherein Z represents a hydrogen atom or a saturated hydrocarbon group having from 1 to 6 carbon atoms; when Z is a hydrogen atom, R represents C.sub.n H.sub.2n+1 COO--, wherein n represents 0 or an integer of from 4 to 9; and when Z is a saturated hydrocarbon group, R represents CH.sub.3 COO-- or a group having a benzene ring. The copolymer is excellent in transparency and provides an electret exhibiting excellent pyroelectricity or piezoelectricity upon polarization.

    摘要翻译: 通过将由式(I)表示的乙烯基氰化物(I)和由式(II)表示的乙烯基化合物(II)得到的亚乙烯基氰共聚物,其中Z表示氢原子或饱和烃基, 1至6个碳原子; 当Z是氢原子时,R表示C n H 2n + 1 COO-,其中n表示0或4至9的整数; 当Z为饱和烃基时,R表示CH 3 COO-或具有苯环的基团。 共聚物的透明度优异,并且提供了极化时显示优异的热电性或压电性的驻极体。

    Alkyl vinylidene cyanide polymers exhibiting nonlinear optical and
piezoelectric properties
    8.
    发明授权
    Alkyl vinylidene cyanide polymers exhibiting nonlinear optical and piezoelectric properties 失效
    显示非线性光学和压电性能的亚烷基亚乙烯基氰化物聚合物

    公开(公告)号:US5210165A

    公开(公告)日:1993-05-11

    申请号:US718885

    申请日:1991-06-21

    IPC分类号: C08F222/34 G02F1/361

    CPC分类号: C08F222/34 G02F1/3616

    摘要: This invention provides novel polymers containing alkyl vinylidene cyanide moieties that exhibit nonlinear optical and piezoelectric properties. The polymers have utility as media in optical devices.An invention polymer is illustrated by the copolymer of the following structure: ##STR1##

    摘要翻译: 本发明提供了含有显示非线性光学和压电性质的烷基亚乙烯基氰化物部分的新型聚合物。 聚合物在光学器件中具有作为介质的功能。 发明聚合物由以下结构的共聚物说明: