摘要:
The present invention generally relates to composition and methods for downconverting light. In some embodiments, the composition and methods comprise an organic material, a nanocrystal, and a ligand capable of facilitating energy transfer between the organic material and the nanocrystal. In certain embodiments, the nanocrystal has a first excited energy state with an energy less than a triplet energy state of the organic material. The organic material, in some embodiments, may be aromatic and/or include one or more pi-conjugated carbon-carbon double bonds. In some cases, incident light may be absorbed by the organic material to produce two triplet excitons. The triplet excitons may then transfer to the nanocrystal via the ligand, where they can undergo recombination, resulting in the formation low energy photons.
摘要:
Disclosed herein are magic size nanoclusters comprising lead and one or more chalcogens. The disclosed magic size nanoclusters have both spectrally narrow fluorescence and ultra-high quantum efficiencies. Further disclosed herein is a method for preparing PbS, PbSe, and PbTe magic size nanoclusters. The yield of magic size nanoclusters can be increased by using anion sources enriched for secondary phosphines. The use of enriched secondary phosphine anion sources also increases the yield of quantum nanostructures.
摘要:
A semiconductor nanocrystal complex that is stable and has high luminescent quantum yield. The semiconductor nanocrystal complex has a semiconductor nanocrystal core of a III-V semiconductor nanocrystal material. A method of making a semiconductor nanocrystal complex is also provided. The method includes synthesizing a semiconductor nanocrystal core of a III-V semiconductor nanocrystal material, and forming a metal layer on the semiconductor nanocrystal core after synthesis of the semiconductor nanocrystal core.
摘要:
Sulphides and selenides are prepared by dissolving sulphur or selenium in an aqueous or non-aqueous solution of hydrazine hydrate. The solution is combined with a solution of an appropriate cation to precipitate the corresponding sulphide or selenide. Solutions of two or more cations may be used to produce ternary compounds of sulphur and selenium, for example thio-gallates. Likewise both sulphur and selenium can be used together to produce sulpho-selenides. The method is particularly applicable to the production of doped phosphors by the inclusion of solutions containing the appropriate dopant.
摘要:
Described are ZnxCd1-xSySe1-y/ZnSzSe1-z core/shell nanocrystals, CdTe/CdS/ZnS core/shell/shell nanocrystals, optionally doped Zn(S,Se,Te) nano- and quantum wires, and SnS quantum sheets or ribbons, methods for making the same, and their use in biomedical and photonic applications, such as sensors for analytes in cells and preparation of field effect transistors.
摘要:
Photovoltaic cells are fabricated in which the compositions of the light-absorbing layer and the electron-accepting layer are selected such that at least one side of the junction between these two layers is substantially depleted of charge carriers, i.e., both free electrons and free holes, in the absence of solar illumination. In further aspects of the invention, the light-absorbing layer is comprised of dual-shell passivated quantum dots, each having a quantum dot core with surface anions, an inner shell containing cations to passivate the core surface anions, and an outer shell to passivate the inner shell anions and anions on the core surface.
摘要:
A micronized semiconductor nanocrystal complex including a plurality of semiconductor nanocrystals embedded in a first matrix material wherein the first matrix material is a micronized polymer. The micronized semiconductor nanocrystal complex can be used in or include inks, paints, dyes, LEDs, taggants, tracers and cosmetics. The present application further provides methods of making micronized semiconductor nanocrystal complexes.
摘要:
A shaped article comprising a plurality of semiconductor nanocrystals. Devices incorporating shaped articles are also provided. Methods of manufacturing shaped articles by various molding processes are also provided.